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材料导报  2019, Vol. 33 Issue (Z2): 283-287    
  无机非金属及其复合材料 |
混凝土增粘剂的制备及应用性能研究
汪源1, 汪苏平2, 张亚利2, 纪宪坤1
1 武汉三源特种建材有限责任公司,武汉 430000;
2 武汉源锦建材科技有限公司,武汉 430000
Study on Preparation and Application Properties of Adhesive Agent for Concrete
WANG Yuan1, WANG Suping2, ZHANG Yali2, JI Xiankun1
1 Wuhan Sanyuan Special Building Materials Co., Ltd., Wuhan 430000;
2 Wuhan Ujoin Building Material Technology Co., Ltd., Wuhan 430000
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摘要 以异戊烯醇聚氧乙烯醚、N,N-二甲基丙烯酰胺、丙烯酸为反应单体,通过三元共聚合成混凝土增粘剂M32,研究了反应单体浓度及配比、反应温度、引发剂用量和滴加时间等因素对混凝土增粘剂性能的影响,同时优化了各工艺参数,并通过红外光谱和核磁共振对其分子结构进行了表征,通过凝胶渗透色谱测试了其分子量。实验结果表明:当异戊烯醇聚氧乙烯醚、N,N-二甲基丙烯酰胺、丙烯酸的物质的量比为1∶120∶120、反应单体总浓度为15%、反应温度为65 ℃、引发剂用量和滴加时间分别为1.0%和60 min时,合成的混凝土增粘剂M32增粘作用明显,能够很好地改善混凝土的离析、泌水、扒底等现象,并改善混凝土的和易性和包裹性。与BASF420增粘剂相比,混凝土中M32使用掺量为BASF420的70%~80%,而且混凝土的28 d抗压强度可提高8%左右,产品在实际工程应用中效果显著。
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汪源
汪苏平
张亚利
纪宪坤
关键词:  混凝土增粘剂  分子结构  泌水  性能评价    
Abstract: The concrete tackifier M32 was synthesized by terpolymerization using isoamyl alcohol polyoxyethylene ether, N, N-dimethyl acrylamide and acrylic acid as reaction monomers, and that concentration and proportion of reactive monomer, reaction temperature, initiator dosage and dropping time of reactive monome were studied. The effects of various factors on the properties of concrete viscosifier were studied, and the process parameters were optimized, and the effects of various factors on the properties of concrete viscosifier were investigated by means of IR and NMR. Its molecular structure was characterized and its molecular weight was determined by gel permeation chromatography. The experimental results show that the synthetic concrete tackifier M32 has obvious viscosity-increasing effect, which can improve the phenomena of segregation, bleeding and bottoming of concrete, and improve the workability and encapsulation of concrete,when the isoamyl alcohol polyoxyethylene ether, N, N-dimethyl acrylamide, acrylic acid molar ratio is 1∶120∶120, the total reaction monomer concentration is 15%, the reaction temperature is 65 ℃, the amount of initiator and the dropping time was 1.0% and 60 min, respectively.The M32 content in that concrete is 70%—80% of that of the BASF420 in comparison with the BASF420 tackify, and the 28 d compressive strength of concrete can be increased by about 8%, and the effect of the product is remarkable in practical engineering application.
Key words:  concrete tackifier    molecular structure    bleeding    performance evaluation
               出版日期:  2019-11-25      发布日期:  2019-11-25
ZTFLH:  TU53  
通讯作者:  jxk0907@126.com   
作者简介:  汪源,2012年6 月毕业于华中农业大学,获得硕士学位,工程师,在国内外学术期刊上发表论文10余篇,申请国家发明专利7项,主要从事建筑功能材料及新型建筑材料方向的研究。
纪宪坤,硕士,高级工程师,毕业于重庆大学材料科学与工程专业,中国土木工程学会混凝土质量专业委员会专家委员,中国工程建设标准化协会建筑防水与防护委员会专家委员, 武汉源锦建材科技工程技术部长,研究领域为:混凝土工程技术,裂缝控制技术,混凝土耐久性及测试技术,尾矿资源化利用技术等。获得华夏建设科学技术一等奖1项、二等奖2项、广东省土木建筑学会二等奖1项,完成专著1部(合著),发表学术论文40余篇。参与多项“十二五”、“十一五”国家科技支撑计划课题,参编《普通混凝土长期性能和耐久性能试验方法标准》(GB/T50082-2009)、《混凝土耐久性检验评定标准》(JGJ/T 193-2009)、《普通混凝土配合比设计规程》(JGJ 55-2011)、《混凝土质量控制标准》(GB 50164-2011)、《混凝土用氧化镁膨胀剂》(CBMF19-2017)、《混凝土用氧化镁应用技术规程》等国家标准。
引用本文:    
汪源, 汪苏平, 张亚利, 纪宪坤. 混凝土增粘剂的制备及应用性能研究[J]. 材料导报, 2019, 33(Z2): 283-287.
WANG Yuan, WANG Suping, ZHANG Yali, JI Xiankun. Study on Preparation and Application Properties of Adhesive Agent for Concrete. Materials Reports, 2019, 33(Z2): 283-287.
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