氮丙啶固化端羧基液体氟橡胶的性能研究

doi:10.11896/cldb.19060181

材料导报

2020, Vol. 34

Issue (20): 20177-20181 https://doi.org/10.11896/cldb.19060181

高分子与聚合物基复合材料

氮丙啶固化端羧基液体氟橡胶的性能研究

李雪岩, 常云飞, 廖明义

大连海事大学交通运输工程学院,大连 116026

Study on Properties of Carboxyl-terminated Liquid Fluororubber Cured by Aziridine

LI Xueyan, CHANG Yunfei, LIAO Mingyi

Transportation Engineering College, Dalian Maritime University, Dalian 116026, China

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摘要以自制的端羧基液体氟橡胶为原料,氮丙啶为固化剂,丙酮为溶剂,采用一锅法对其进行固化。通过红外光谱(IR)、差示扫描量热仪(DSC)和热失重仪(TGA)分别对固化产物的结构、固化过程及耐热性能进行研究,考察了固化剂用量、固化时间等因素对固化产物耐溶剂性和力学性能的影响。结果表明:氮丙啶与端羧基液体氟橡胶的固化温度为90~100 ℃。随着固化剂添加量的增加,产物的热稳定性逐渐增强,且具有优异的耐溶剂性。当固化剂用量为14%、固化时间为4 h时,固化产物的综合性能最佳。

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关键词: 端羧基液体氟橡胶氮丙啶固化剂固化热性能力学性能

Abstract: The self-made carboxyl-terminated liquid fluororubber was used as raw material, aziridine as curing agent and acetone as solvent to cure it by a one-pot method. The structure, curing process and heat resistance of the cured product were studied by infrared spectroscopy (IR), diffe-rential scanning calorimetry (DSC) and thermogravimetric meter (TGA). At the same time, the effects of curing agent dosage and curing time on the solvent resistance and mechanical properties of the cured product were investigated. The results show that the curing temperature of aziridine and terminal carboxyl liquid fluororubber is between 90 ℃ and 100 ℃. As the amount of the curing agent added increases, the thermal stability of the product gradually increases, and the solvent resistance is excellent. When the curing agent is used in an amount of 14% and the curing time is 4 h, the overall performance of the cured product is optimal.

Key words: carboxyl-terminated liquid fluororubber aziridine curing agent curing thermal performance mechanical property

出版日期: 2020-10-25 发布日期: 2020-11-06

ZTFLH:

TQ333.93

基金资助: 国家自然科学基金(51873026)

通讯作者: liaomy@dlmu.edu.cn

作者简介: 李雪岩,2017年6月毕业于北方民族大学,获得学士学位。现为大连海事大学材料科学与工程专业研究生,主要研究液体氟橡胶的合成及改性。
廖明义,大连海事大学教授,博士研究生导师。1984年本科毕业于大连工学院化工系,1988—1993年公派到俄罗斯莫斯科精细化工学院攻读博士学位。主持国家自然科学基金、国家科技合作专项、科技部政府间合作项目、装备预研以及省部级以上项目15项,以及中国石油化工公司、中国石油天然气公司、中石化燕山石化、中石油抚顺石化、中石油大庆石化等数十项企业课题。发表学术论文170余篇,被 SCI、EI 收录50余篇;出版教材2部,即《高分子合成材料学》和《高聚物的结构与性能》,申请国家发明专利 30 余项。主要研究方向为通用橡胶合成、液体氟橡胶制备和应用、聚合物基纳米复合材料、橡塑材料改性及公路路面材料制备。

引用本文:

李雪岩, 常云飞, 廖明义. 氮丙啶固化端羧基液体氟橡胶的性能研究[J]. 材料导报, 2020, 34(20): 20177-20181.
LI Xueyan, CHANG Yunfei, LIAO Mingyi. Study on Properties of Carboxyl-terminated Liquid Fluororubber Cured by Aziridine. Materials Reports, 2020, 34(20): 20177-20181.

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http://www.mater-rep.com/CN/10.11896/cldb.19060181 或 http://www.mater-rep.com/CN/Y2020/V34/I20/20177

1 Ameduri B.Chemical Reviews, 2009, 109, 6632.
2 Liu L M. Organo-Fluorine Industry, 2001(2), 5(in Chinese).
刘岭梅. 有机氟工业, 2001(2), 5.
3 Qian H Q, Wang C Y. Organo-Fluorine Industry, 2016(1), 48(in Chinese).
钱厚琴,王昌尧. 有机氟工业, 2016(1), 48.
4 Li D H, Liao M Y. Materials Reports B: Research Papers, 2018, 32(5), 1730(in Chinese).
李东翰,廖明义. 材料导报:研究篇, 2018, 32(5), 1730.
5 Li D H, Liao M Y. Materials Reports B: Research Papers, 2018, 32(4), 1338(in Chinese).
李东翰,廖明义. 材料导报:研究篇, 2018, 32(4), 1338.
6 Scheirs J. Modern fluoropolymers: high performance polymers for diverse applications, John Wiley & Sons, USA, 1997.
7 Ross E W, Gary J R, Hoover S. Modern Fluoroelastomers, 1997, 23,422.
8 Ren H F, Jiang J F, Chen W F. Organo-Fluorine Industry, 2017(4), 36(in Chinese).
任慧芳, 蒋杰峰, 陈伟峰. 有机氟工业, 2017(4), 36.
9 Li D H. Preparatio, curing, structures and properties of end-functiona-lized liquid fluoroelastomers. Ph.D. Thesis, Dalian Maritime University, China, 2018(in Chinese).
李东翰. 液体端基官能化氟橡胶的制备、固化及其结构和性能研究. 博士学位论文, 大连海事大学, 2018.
10 Wang Y H, Dong S, Wu J H, et al. China Adhesives, 2018, 27(3), 46(in Chinese).
王亚琴, 董帅, 武建华, 等. 中国胶粘剂, 2018, 27(3), 46.
11 Xie F, Liu Z H, Wei D H. Chinese Journal of Synthetic Chemistry, 2002(2), 120(in Chinese).
谢飞, 刘宗惠, 魏德卿. 合成化学, 2002(2), 120.
12 Jung S, Kang S, Kuwabara J, et al. Polymer Chemistry, 2019, 10(33), 4506.
13 Tong R, Sun J, Pang X Y, et al. Leather and Chemicals, 2011, 28(2), 16(in Chinese).
童蓉, 孙静, 庞晓燕, 等. 皮革与化工, 2011, 28(0), 16.
14 Roesler R R, Danielmeier K. Progress in Organic Coatings, 2004, 50(1),1.
15 De W H, Xie F, Jia L, et al. China Leather, 2002(19), 25(in Chinese).
魏德卿, 谢飞, 贾锂, 等. 中国皮革, 2002(19), 25.
16 Zhang X T, Zhao Q. Chinese Journal of Magnetic Resonance,1990(3), 255(in Chinese).
张喜田, 赵琦. 波谱学杂志, 1990(3), 255.

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