Please wait a minute...
材料导报  2020, Vol. 34 Issue (12): 12040-12044    https://doi.org/10.11896/cldb.19050115
  无机非金属及其复合材料 |
利用离子交换法制备高强载银抗菌玻璃及其性能测试
王海风1,2, 徐桂香1, 董芸谷1, 熊能1, 王若轩1
1 东华大学材料科学与工程学院,上海 201620
2 先进玻璃制造技术教育部工程研究中心,上海 201620
Preparation and Properties of High Strength Ag-carrying Antibacterial Glass by Ion Exchange Method
WANG Haifeng1,2, XU Guixiang1, DONG Yungu1, XIONG Neng1, WANG Ruoxuan1
1 School of Material Science and Engineering, Donghua University, Shanghai 201620, China
2 Advanced Glass Manufacturing Technology Engineering Research Center, Ministry of Education, Shanghai 201620, China
下载:  全 文 ( PDF ) ( 3924KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 将厚度为1.1 mm的高铝硅酸盐玻璃(SiO2-Al2O3-Na2O系)置于KNO3/NaNO3混合熔盐中进行离子交换增强,再将强化后的玻璃置于不同质量比的AgNO3/KNO3混合熔盐中进行二次离子交换,制得高强载银抗菌玻璃。采用万能试验机测试玻璃样品的抗弯强度,利用EDS能谱分析测试离子交换深度及元素分布情况,用活菌计数法评测玻璃的抗菌性。实验结果表明:经过两步离子交换法可获得强度高、透明度好、抑菌效果优良的抗菌玻璃。第一步离子交换混盐质量比m(KNO3)∶m(NaNO3)=9∶1,交换2 h;第二步离子交换混盐质量比m(AgNO3)∶m(KNO3)=1∶9,交换10 min,在此工艺条件下制得的抗菌玻璃综合性能最优。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
王海风
徐桂香
董芸谷
熊能
王若轩
关键词:  化学钢化  载银  抗菌玻璃    
Abstract: The Na2O-Al2O3-SiO2 system glass was ion exchange strengthened by KNO3/NaNO3 mixed molten salts, and then the tempered glasses were put into AgNO3/KNO3 mixed molten salt with different proportions to prepare high-strength Ag-carrying antibacterial glass. The bending strength of glass samples were measured by universal testing machine, the element distribution on the glass surface was measured by EDS and the antimicrobial activity of glass was determined by viable counting method. The results show that the glass with high strength, high transmittance and good antibacterial ability can be produced by two-step ion exchange process. Moreover, ion exchanging for 2 h with mass ratio of mixed salt m(KNO3)∶m(NaNO3)=9∶1 in the first step and 10 minutes with mass ratio of mixed salt m(AgNO3)∶m(KNO3)=1∶9 in the second step making the antibacterial glass obtain optimized comprehensive properties.
Key words:  chemical tempering    Ag-carrying    antibacterial glass
                    发布日期:  2020-05-29
ZTFLH:  TB321  
基金资助: 东华大学材料科学与工程学院拔尖创新人才培养计划
通讯作者:  whf2008@dhu.edu.cn   
作者简介:  王海风,女,博士,东华大学材料科学与工程学院副研究员。长期从事无机非金属材料的研究,在电子玻璃、玻璃深加工与改性技术、复合介质材料等方面具有丰富的研究经验。主持或参与多项省部级、军工配套项目以及企业技术开发项目等,研发材料广泛用于航天、航空器件等。
引用本文:    
王海风, 徐桂香, 董芸谷, 熊能, 王若轩. 利用离子交换法制备高强载银抗菌玻璃及其性能测试[J]. 材料导报, 2020, 34(12): 12040-12044.
WANG Haifeng, XU Guixiang, DONG Yungu, XIONG Neng, WANG Ruoxuan. Preparation and Properties of High Strength Ag-carrying Antibacterial Glass by Ion Exchange Method. Materials Reports, 2020, 34(12): 12040-12044.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.19050115  或          http://www.mater-rep.com/CN/Y2020/V34/I12/12040
1 Nana Fofana, Xu L, Hao Y B, et al. Food Science and Techology,2004(6),7(in Chinese).
Nana Fofana,徐黎,郝云彬,等.食品科技,2004(6),7.
2 Mao H B, Feng J Y, Zhao X J. The World of Building Materials,2011,32(5),1(in Chinese).
茅海波,冯晋阳,赵修建.建材世界,2011,32(5),1.
3 Li Q H.Preparation and antibacterial properties of silver zinc composite SiO2 films. Master's Thesis, Wuhan University of Technology, China,2007(in Chinese).
李全华.银锌复合SiO2薄膜的制备及抗菌性能研究.武汉理工大学,2007.
4 Ma X X, Pei Y Y, Lei Y. Journal of Functional Materials,2017,48(9),38(in Chinese).
麻晓霞,裴阳阳,雷云.功能材料,2017,48(9),38.
5 Jia Z X, Viktor Nadtochenko, Marina A, et al. Mechanics & Industry,2016,17(5),504.
6 Esteban-Tejeda L, Malpartida F, Esteban-Cubillo A, et al. Nanotech-nology,2009,20(8),085103.
7 Zhang B, Fu L, Tang X N, et al. Bulletin of the Chinese Ceramic Sociaty,2013,32(2),313(in Chinese).
张彬,付亮,唐晓宁,等.硅酸盐通报,2013,32(2),313.
8 Wang J, Shui Z H, Ji Z J, et al. Materials Review A: Review Papers,2013,27(9),59(in Chinese).
王静,水中和,冀志江,等.材料导报:综述篇,2013,27(9),59.
9 Xu Y, Cheng J S, Li Q H. Journal of Central China Normal University (Natural Sciences),2005,39(3),355(in Chinese).
徐瑛,程金树,李全华.华中师范大学学报(自然科学版),2005,39(3),355.
10 Hu W, Wang H F, Tan B Q, et al. Glass & Enamel,2018,46(4),10.
胡伟,王海风,谈宝权,等,玻璃与搪瓷,2018,46(4),10.
11 Hamid H, Vincenzo M S. Journal of Non-Crystalline Solids,2019,515(1),143.
12 中华人民共和国国家卫生和计划生育委员会,国家食品药品监督管理总局.中华人民共和国国家标准:食品安全国家标准 食品微生物学检验 菌落总数测定:GB 4789.1-2016.中国标准出版社,2016.
13 Du X O, Yuan J, Peng Z G, et al. Bulletin of the Chinese Ceramic Sociaty,2017,36(S),223(in Chinese).
杜晓欧,袁坚,彭志钢,等.硅酸盐通报,2017,36(S),223.
14 Liu X Q, He F, Liu X Y, et al. Bulletin of the Chinese Ceramic Society,2018,37(11),3592(in Chinese).
刘小青,何峰,刘锡宇,等.硅酸盐通报,2018,37(11),3592.
15 Wang D X, Lei Z Y. In:The 6th China Antibacterial Industry Development Conference. Beijing,2008,pp.135(in Chinese).
王德宪,雷振宇.第六届中国抗菌产业发展大会.北京,2008,pp.135.
16 Lu Y Q, Zhang F, Chen W, et al. Bulletin of the Chinese Ceramic Sociaty,2015,34(S),12(in Chinese).
陆勇祺,张凡,陈玮,等.硅酸盐通报,2015,34(S),12.
17 Su W, Tang J X, Dong L L, et al. Nanoscience and Nanotechnology Letters,2016,8(6),471.
18 Takeda Satoshi, Yamamoto Kiyoshi, Matsumoto Kiyoshiet. Journal of Non-Crystalline Solids,2000,265(1),133.
19 Wang J, Wang X Y, Shui Z H, et al. Materials Review B: Research Papers,2018,32(8),2709(in Chinese).
王静,王晓燕,水中和,等.材料导报:研究篇,2018,32(8),2709.
20 Tejido-Rastrilla Rocío, Ferraris Sara, Goldmann Wolfgang H, et al. Materials,2019,12(3),500.
21 Chou Y J, Lin S H, Shih C J, et al. Journal of Nanoscience and Nanotechnology,2016,16(9),10001.
[1] 王晓燕, 王继梅, 侯国艳. 富锌载银可溶玻璃抗菌材料的性能[J]. 材料导报, 2019, 33(Z2): 92-96.
[2] 李森, 王清涛, 于华芹, 徐会君, 杜庆洋. 固相离子交换法制备高效载银分子筛抗菌剂及其抗菌性能[J]. 《材料导报》期刊社, 2018, 32(4): 539-544.
[3] 张雪荣, 胡银春, 席少晖, 王兆伟, 战岩, 黄棣, 胡超凡, 魏延. 静电纺β-环糊精/石墨烯载银抗菌纤维膜的制备与表征[J]. 《材料导报》期刊社, 2018, 32(4): 545-548.
[4] 王静, 王晓燕, 水中和, 冀志江, 赵春艳, 刘蕊蕊. 玻璃载银抗菌材料的Ag+溶出性质及与大肠杆菌作用机理[J]. 材料导报, 2018, 32(16): 2709-2714.
[1] Dongyong SI, Guangxu HUANG, Chuanxiang ZHANG, Baolin XING, Zehua CHEN, Liwei CHEN, Haoran ZHANG. Preparation and Electrochemical Performance of Humic Acid-based Graphitized Materials[J]. Materials Reports, 2018, 32(3): 368 -372 .
[2] Bingwei LUO,Dabo LIU,Fei LUO,Ye TIAN,Dongsheng CHEN,Haitao ZHOU. Research on the Two Typical Infrared Detection Materials Serving at Low Temperatures: a Review[J]. Materials Reports, 2018, 32(3): 398 -404 .
[3] Ming HE,Yao DOU,Man CHEN,Guoqiang YIN,Yingde CUI,Xunjun CHEN. Preparation and Characterization of Feather Keratin/PVA Composite Nanofibrous Membranes by Electrospinning[J]. Materials Reports, 2018, 32(2): 198 -202 .
[4] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[5] Xu LI,Ziru WANG,Li YANG,Zhendong ZHANG,Youting ZHANG,Yifan DU. Synthesis and Performance of Magnetic Oil Absorption Material with Rice Chaff Support[J]. Materials Reports, 2018, 32(2): 219 -222 .
[6] XU Zhichao, FENG Zhongxue, SHI Qingnan, YANG Yingxiang, WANG Xiaoqi, QI Huarong. Microstructure of the LPSO Phase in Mg98.5Zn0.5Y1 Alloy Prepared by Directional Solidification and Its Effect on Electromagnetic Shielding Performance[J]. Materials Reports, 2018, 32(6): 865 -869 .
[7] WANG Tong, BAO Yan. Advances on Functional Polyacrylate/Inorganic Nanocomposite Latex for Leather Finishing[J]. Materials Reports, 2017, 31(1): 64 -71 .
[8] HUANG Dajian, MA Zonghong, MA Chenyang, WANG Xinwei. Preparation and Properties of Gelatin/Chitosan Composite Films Enhanced by Chitin Nanofiber[J]. Materials Reports, 2017, 31(8): 21 -24 .
[9] DU Wenbo, YAO Zhengjun, TAO Xuewei, LUO Xixi. High-temperature Anti-oxidation Property of Al2O3 Gradient Composite Coatings on TC11 Alloys[J]. Materials Reports, 2017, 31(14): 57 -60 .
[10] ZHANG Le, ZHOU Tianyuan, CHEN Hao, YANG Hao, ZHANG Qitu, SONG Bo, WONG Chingping. Advances in Transparent Nd∶YAG Laser Ceramics[J]. Materials Reports, 2017, 31(13): 41 -50 .
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed