Rapid Preparation of HKUST-1 in Water at Room Temperature and Its Adsorption on Reactive Blue 194
NA Liyan1, ZHANG Liying1, ZHANG Fengjie2, HUA Ruinian1
1 College of Life Science, Dalian Minzu University, Dalian 116600, China; 2 College of Environment and Bioresources, Dalian Minzu University, Dalian 116600, China
Abstract: Coordination polymer material HKUST-1 was synthesized rapidly specific at room temperature by mixing Cu(NO3)2 and ammonium salt of H3BTC in aqueous system. The phase composition, morphology and specific surface areas were characterized by powder XRD, SEM and N2 sorption. The results indicated that the HKUST-1 samples were phase-pure micro particles with BET surface areas of 1 246 m2·g-1. The adsorbent activities of the samples were evaluated for the removal of reactive blue 194 from waste water. The influences of adsorbent amount, pH va-lue, initial concentration, reaction time and regeneration of spent adsorbent were investigated. The results suggested that the as-synthesized HKUST-1 exhibited good adsorption property for reactive blue 194. The adsorption process could reach equilibrium in 60 min at room temperature and the removal rate was 95.7%. The adsorption isotherm model accorded with the Langmuir isotherm model and the kinetic analysis revealed that the adsorption process was well-matched with the pseudo-second-order model. The as-synthesized HKUST-1 material could be a promising adsorbent for dyes removal from waste water for its excellent performance, simple synthesis process and easy regeneration.
那立艳, 张丽影, 张凤杰, 华瑞年. 室温非有机体系中HKUST-1的快速制备及对活性蓝194的吸附[J]. 材料导报, 2020, 34(4): 4137-4141.
NA Liyan, ZHANG Liying, ZHANG Fengjie, HUA Ruinian. Rapid Preparation of HKUST-1 in Water at Room Temperature and Its Adsorption on Reactive Blue 194. Materials Reports, 2020, 34(4): 4137-4141.
1 Forgacs E, Cserháti T, Oros G. Environment International, 2004, 30(7), 95. 2 Cervantes F J,Dos Santos A B. Reviews in Environmental Science and Biotechnology, 2011, 10(2), 125. 3 Da Silva M E R, Firmino P I M, De Sousa M R, et al. Applied Bioche-mistry and Biotechnology, 2012, 166(4),1057. 4 Vosoughifar A. Journal of Materials Science: Materials in Electronics, 2018, 29(4), 3194. 5 Zhang Q L, Dong R F, Wu Y F.et al. ACS Applied Materials and Interfaces, 2017, 9(5), 4674. 6 Nikooe N, Saljoughi E. Applied Surface Science, 2017, 413(15), 41. 7 Pendergast M T M, Hoek E M V.Energy and Environmental Science, 2011, 4(6), 1946. 8 Jiang J Q. Current Opinion in Chemical Engineering, 2015, 8, 36. 9 Vijayaraghavan G, Rajasekaran R, Shantha Kumar S. International Journal of Chemical Sciences, 2013, 11(4),1824. 10 Sharma P, Kaur H, Sharma M, et al.Environmental Monitoring and Assessment, 2011, 183(1-4), 151. 11 Al-Qodah Z, Shawabkah R.Brazilian Journal of Chemical Engineering, 2009, 26(1), 127. 12 Yahya M A, Al-Qodah Z, Ngah C W Z, et al.Asian Journal of Chemistry, 2015, 27(6), 2331. 13 Ahmad A A, Idris A, Hameed B H.Desalination and Water Treatment, 2013, 51(13-15), 2554. 14 Khan N A, Hasan Z, Jhung S H.Journal of Hazardous Materials, 2013, 244-245(15), 444. 15 Abbasi A R, Rizvandi M.Ultrasonics Sonochemistry, 2018, 40, 465. 16 Abbasi A R, Karimi M, Daasbjerg K. Ultrasonics Sonochemistry, 2017, 37, 182. 17 Na L Y, Zhang L Y, Zhang F J, et al.Journal of Functional Matericals, 2018, 49(6), 06179(in Chinese). 那立艳, 张丽影, 张凤杰 等.功能材料, 2018, 49(6), 06179. 18 Chui S S Y, Lo S M F, Charmant J P H, et al.Science, 1999, 283, 1148. 19 Liu J C, Culp J T, Natesakhawat S, et al.The Journal of Physical Che-mistry C, 2007, 111(26), 9305. 20 Schlesinger M, Schulze S, Hietschold M, et al.Microporous and Mesoporous Materials, 2010, 132(1), 121. 21 Xi J H, He M C, Lin C Y. Microchemical Journal, 2011, 97(1), 85. 22 Liu Y. Journal of Chemical and Engineering Data, 2009, 54 (7), 1981. 23 Ghosal P S, Gupta A K. Journal of Molecular Liquids, 2017, 225,137. 24 Pengthamkeerati P, Satapanajaru T, Singchan O. Journal of Hazardous Materials, 2008, 153(3), 1149. 25 Srivastava V C, Swamyl M M, Mall I D, et al. Colloids and Surface A: Physicochemical and Engineering Aspects, 2006, 272(1-2), 89.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2020, Vol. 34 
