Please wait a minute...
材料导报  2026, Vol. 40 Issue (6): 25020082-8    https://doi.org/10.11896/cldb.25020082
  金属与金属基复合材料 |
Ta添加对铁基非晶合金涂层耐腐蚀性能的影响
童福佳1, 张冠1,2,3,*, 谢磊4, 赵冬梅1, 任铁真5
1 新疆大学智能制造现代产业学院,乌鲁木齐 830017;
2 新疆工程学院新疆煤矿机电工程技术研究中心,乌鲁木齐 830023;
3 新疆工程学院机电工程学院,乌鲁木齐 830023;
4 新疆大学物理科学与技术学院,乌鲁木齐 830046;
5 新疆大学化学工程与技术学院,乌鲁木齐 830046
Effect of Adding Ta on Corrosion Resistance of Fe-based Amorphous Alloy Coatings
TONG Fujia1, ZHANG Guan1,2,3,*, XIE Lei4, ZHAO Dongmei1, REN Tiezhen5
1 College of Intelligent Manufacturing Modern Industry, Xinjiang University, Urumqi 830017, China;
2 Xinjiang Coal Mine Electromechanical Engineering Technology Research Center, Xinjiang Institute of Engineering, Urumqi 830023, China;
3 College of Mechanical and Electrical Engineering, Xinjiang Institute of Engineering, Urumqi 830023, China;
4 School of Physics Science and Technology, Xinjiang University, Urumqi 830046, China;
5 School of Chemical Engineering and Technology, Xinjiang University, Urumqi 830046, China
下载:  全 文 ( PDF ) ( 56422KB ) 
输出:  BibTeX | EndNote (RIS)      
摘要 为了提高SAM2X5铁基非晶合金涂层的硬度和耐腐蚀性能,通过添加不同含量的Ta元素与基体中的C元素在涂层中原位合成TaC增强相的方法,改善涂层的微观组织,提高涂层的硬度与耐腐蚀性能。与不含Ta涂层相比,含Ta涂层中原位合成了TaC相。并且随着Ta含量的增加,TaC相增多,涂层中的非晶相含量降低。适量Ta元素的添加明显提高了涂层的显微硬度,10%(质量分数)Ta涂层具有最高的硬度(1 476.38HV0.3)。电化学测试、扫描电镜(SEM)和X射线光电子能谱仪(XPS)分析表明,适量添加Ta元素有利于促进Cr3+/Cr6+/Mo6+/W6+氧化物的生成,此外致密稳定的Ta2O5氧化物与其他氧化物起到了协同作用。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
童福佳
张冠
谢磊
赵冬梅
任铁真
关键词:  激光熔覆  铁基非晶合金复合涂层  显微硬度  耐腐蚀性能    
Abstract: To enhance the hardness and corrosion resistance of SAM2X5 Fe-based amorphous alloy coatings, different contents of Ta were added to in-situ synthesize TaC reinforcement phases through reactions with C in the matrix. This approach aims to improve the coating's microstructure and consequently enhance its mechanical and corrosion-resistant properties. Compared with coatings without Ta, those with Ta additions exhibit in-situ formation of TaC phases. With the increase of Ta content, the amount of TaC phases increases, while the amorphous phase fraction in the coating decreases. The appropriate addition of Ta significantly improves the microhardness of the coating, with the 10% Ta coating achieving the highest hardness(1 476.38HV0.3). Electrochemical tests, scanning electron microscopy(SEM), and X-ray photoelectron spectroscopy(XPS) analyses reveal that the addition of Ta facilitated the formation of Cr3+/Cr6+/Mo6+/W6+ oxides. Moreover, the formation of a dense and stable Ta2O5 oxide acts synergistically with other oxides, further enhancing the corrosion resistance.
Key words:  laser cladding    Fe-based amorphous alloy composite coating    microhardness    corrosion resistance
出版日期:  2026-03-25      发布日期:  2026-04-03
ZTFLH:  TG174.4  
基金资助: 自治区高校基本科研业务费科研项目(XJEDU2023P14);自治区科技计划项目-重点研发专项(202207120031)
通讯作者:  *张冠,博士,新疆大学智能制造现代产业学院硕士研究生导师,新疆工程学院机电工程学院副教授,新疆大学化工学院博士后。目前主要从事增材制造3D打印、防腐防污涂层设计与制备、耐磨耐蚀涂层设计与制备等方面的研究。gzhang89@163.com   
作者简介:  童福佳,新疆大学智能制造现代产业学院硕士研究生,在张冠副教授的指导下进行研究。研究方向为非晶合金。
引用本文:    
童福佳, 张冠, 谢磊, 赵冬梅, 任铁真. Ta添加对铁基非晶合金涂层耐腐蚀性能的影响[J]. 材料导报, 2026, 40(6): 25020082-8.
TONG Fujia, ZHANG Guan, XIE Lei, ZHAO Dongmei, REN Tiezhen. Effect of Adding Ta on Corrosion Resistance of Fe-based Amorphous Alloy Coatings. Materials Reports, 2026, 40(6): 25020082-8.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25020082  或          https://www.mater-rep.com/CN/Y2026/V40/I6/25020082
1 Zhong M, Liu W. Proceedings of the Institution of Mechanical Engineers, Part C:Journal of Mechanical Engineering Science, 2010, 224(5), 1041.
2 Tham L M, Gupta M, Cheng L. Acta Materialia, 2001, 49(16), 3243.
3 Daniel B S, Murthy V S R, Murty G S. Journal of Materials Processing Technology, 1997, 68(2), 132.
4 Lee J C, Byun J Y, Oh C S, et al. Acta Materialia, 1997, 45(12), 5303.
5 Paraye N K, Neog S P, Ghosh P K, et. al. Surface and Coatings Technology, 2021, 405, 126533.
6 Bartkowski D, Bartkowska A, Jurci P. Optics and Laser Technology, 2021, 136, 106784.
7 Ferro D, Rau J V, Albertini V R, et al. Surface and Coatings Technology, 2008, 202(8), 1455.
8 Lv X, Zhan Z, Cao H, et. al. Surface and Coatings Technology, 2020, 396, 125937.
9 Wang K, Du D, Liu G, et. al. Journal of Alloys and Compounds, 2019, 802, 373.
10 Lv Y H, Li J, Tao Y F, et al. Journal of Alloys and Compounds, 2016, 679, 202.
11 Li M Y, Chao M J, Liang E J, et al. Surface Engineering, 2013, 29(8), 616.
12 Li Z, Yan H, Zhang P, et al. Surface and Coatings Technology, 2021, 405, 126592.
13 Morton C W, Wills D J, Stjernberg K. International Journal of Refractory Metals and Hard Materials, 2005, 23(4-6), 287.
14 Yu T, Deng Q, Dong G, et. al. Journal of Wuhan University of Technology Materials Science Edition, 2013, 28(3), 437.
15 Murzakov M, Petrovskiy V, Birukov V, et al. Physics Procedia, 2015, 71, 202.
16 Zhao Z, Hui P, Liu F, et. al. Journal of Alloys and Compounds, 2019, 790, 189.
17 Hu L F, Li J, Tao Y F, et. al. Surface and Coatings Technology, 2017, 311, 295.
18 Maurya R S, Sahu A, Laha T. Materials and Design, 2016, 93, 96.
19 Yu T. Journal of Mechanical Engineering, 2011, 47(22), 25.
20 Fang H, Chen R, Chen X, et. al. Intermetallics, 2019, 104, 43.
21 Takeuchi A, Inoue A. Materials Transactions, 2005, 46(12), 2817.
22 Wang H Z, Cheng Y H, Song W, et. al. Intermetallics, 2021, 136, 107266.
23 Fernandez R, Lecomte J C, Kattamis T Z. Metallurgical and Materials Transactions A, 1978, 9(10), 1381.
24 Zhang H, Zhang Y, Cao Q, et. al. Ceramics International, 2023, 49(1), 894.
25 Zhou S, Xu T, Hu C, et. al. Optics and Laser Technology, 2021, 140, 106967.
26 Abioye T E, Farayibi P K, McCartney D G, et. al. Journal of Materials Processing Technology, 2016, 231, 89.
27 Mahata N, Banerjee A, Bijalwan P, et. al. Journal of Materials Engineering and Performance, 2017, 26(11), 5538.
28 Wang H, Cheng Y, Geng R, et. al. Journal of Alloys and Compounds, 2023, 952, 169842.
29 Pruna A, Pilan L. Composites Part B, Engineering, 2012, 43(8), 3251.
30 Yang Y, Zhang C, Peng Y, et. al. Corrosion Science, 2012, 59, 10.
31 Dai N, Zhang L C, Zhang J, et. al. Corrosion Science, 2016, 111, 703.
32 Wang L, Chao Y. Materials Letters, 2012, 69, 76.
33 Hu Y, Kong D J. Journal of Materials Engineering and Performance, 2024, 33, 9406.
34 Cui Q, Yi D, Wang H, et. al. Journal of Rare Earths, 2019, 37(12), 1341.
35 Xu X, Lu H F, Luo K Y, et. al. Journal of Materials Processing Technology, 2020, 284, 116736.
[1] 李涛. 氮化物涂层在PEMFC金属双极板领域的应用[J]. 材料导报, 2026, 40(6): 25010055-10.
[2] 李雪峰, 李海新, 杨柯楠, 俞传永, 吉小超, 李庚泽, 徐天生, 魏敏. 超高速激光熔覆研究现状与进展[J]. 材料导报, 2026, 40(4): 25010050-11.
[3] 林婕, 张海瑞, 丁昊昊, 姚鑫宇, 姚重阳, 王尧. 飞行器运输振动下GH4169/WC激光熔覆复合涂层摩擦磨损性能研究[J]. 材料导报, 2026, 40(4): 25020059-10.
[4] 浦娟, 李欣竹, 孙华为, 秦建, 程亚芳. 柔性镍基碳化钨金属布真空钎焊工艺研究[J]. 材料导报, 2026, 40(3): 25010128-8.
[5] 俞伟元, 景瑞, 董鹏飞, 吴保磊, 李扬, 强潇. 高速激光熔覆Fe基非晶涂层裂纹及组织分析[J]. 材料导报, 2025, 39(7): 24030107-6.
[6] 王森巍, 王丽, 王明庆, 佘加, 易嘉琰, 陈先华, 潘复生. Mg-xSc(x=0.5,1.0,3.0,5.0)生物医用合金组织与性能研究[J]. 材料导报, 2025, 39(5): 24090019-8.
[7] 雷经发, 赵晨霞, 刘涛, 沈朝阳, 李思悦. 激光熔覆Inconel 625合金高温高应变率下的力学行为及本构模型[J]. 材料导报, 2025, 39(4): 23120263-7.
[8] 张泽疆, 李新梅, 朱春金, 李航, 杨定力. 纳米TiB2对CoCrFeNiSi高熵合金涂层耐磨与耐蚀性能的影响[J]. 材料导报, 2025, 39(3): 23090210-9.
[9] 李欢欢, 王善林, 陈玉华, 宋石平, 涂文斌. 钛铝合金激光填丝修复裂纹机理分析[J]. 材料导报, 2025, 39(24): 24120046-7.
[10] 董照帅, 李新梅, 贾黎明, 贾海洋, 闫芷琪, 巫理平. 激光熔覆制备BCC/FCC梯度涂层及其磨损和拉伸性能的研究[J]. 材料导报, 2025, 39(24): 24120023-7.
[11] 王帅, 罗兵辉, 邢莎莎, 袁光辉, 谢宁, 姜根. 低温预时效对Al-4.5Zn-1.4Mg合金组织和耐腐蚀性能的影响[J]. 材料导报, 2025, 39(23): 24040234-6.
[12] 梁文杰, 董强胜, 章晓波. 增材制造铝合金组织结构与性能研究进展[J]. 材料导报, 2025, 39(19): 24100182-15.
[13] 龙海洋, 徐鑫, 马占山, 贾志强, 刘泽宇, 余烁, 史海江, 王新, 贵永亮. 曲面激光熔覆的研究现状及发展趋势[J]. 材料导报, 2025, 39(18): 24080076-8.
[14] 韩娟, 龙雨, 徐流杰, 赖伟基, 龙绍檑, 邓澄, 周圣丰, 于振涛, 李卫, 易艳良. 激光熔覆高熵合金涂层的研究进展[J]. 材料导报, 2025, 39(13): 24050222-16.
[15] 杜娴, 禹东欣, 柳建, 蔡志海, 何东昱, 王晓龙. Si含量对激光熔覆FeCoNiBSiNb非晶合金复合材料力学和摩擦学性能的影响[J]. 材料导报, 2025, 39(12): 24050125-7.
[1] Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO2/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[2] Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[3] Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[4] Wen XI,Zheng CHEN,Shi HU. Research Progress of Deformation Induced Localized Solid-state Amorphization in Nanocrystalline Materials[J]. Materials Reports, 2018, 32(1): 116 -121 .
[5] Laima LUO, Mengyao XU, Xiang ZAN, Xiaoyong ZHU, Ping LI, Jigui CHENG, Yucheng WU. Progress in Irradiation Damage of Tungsten and Tungsten AlloysUnder Different Irradiation Particles[J]. Materials Reports, 2018, 32(1): 41 -46 .
[6] Fengsen MA,Yan YU,Jie ZHANG,Haibo CHEN. A State-of-the-art Review of Cytotoxicity Evaluation of Biomaterials[J]. Materials Reports, 2018, 32(1): 76 -85 .
[7] Huimin PAN,Jun FU,Qingxin ZHAO. Sulfate Attack Resistance of Concrete Subjected to Disturbance in Hardening Stage[J]. Materials Reports, 2018, 32(2): 282 -287 .
[8] Acidifier at High Temperature SiO2Bearing, , , , . Research on Stabilization of Free CaO in Basic Oxygen Furnace Slag with[J]. Materials Reports, 2018, 32(2): 301 -306 .
[9] Ziming LIU,Huaxin CHEN,Rui XIONG,Yongdan WANG,Xiaowen WANG. Experimental Investigation on Properties of Steel Wool Fiber/Brucite Fiber Reinforced Asphalt Mortar[J]. Materials Reports, 2018, 32(2): 295 -300 .
[10] ZHANG Hehe, LI Fangfang, WANG Haiyan, PENG Zhiguang, TANG Yougen. Iron Electrode Derived from Fe/Co-MOF and Its Electrochemical Performance for Nickel-Iron Batteries[J]. Materials Reports, 2018, 32(5): 719 -724 .
Viewed
Full text


Abstract

Cited
  Shared   
  Discussed