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材料导报  2026, Vol. 40 Issue (6): 25010055-10    https://doi.org/10.11896/cldb.25010055
  金属与金属基复合材料 |
氮化物涂层在PEMFC金属双极板领域的应用
李涛*
东方电气集团东方锅炉股份有限公司机械工业高温、高压材料与焊接重点实验室,成都 610000
Application of Nitride Coatings in the Field of PEMFC Metal Bipolar Plates
LI Tao*
Key Laboratory of High Temperature and High Pressure Materials and Welding for Machinery Industry, Dongfang Boiler Co., Ltd., Chengdu 610000, China
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摘要 质子交换膜燃料电池(PEMFC)具有能量密度高、转换效率高、不受卡诺循环限制、环境友好等优势,是一种理想的便携式电源装置。金属双极板作为PEMFC的核心部件之一,需具有优异的耐腐蚀和导电性能。然而,在PEMFC的工作环境中,金属易被腐蚀,形成的金属离子会破坏质子膜;同时金属表面形成的低导电率氧化物会增加双极板与气体扩散层之间的界面接触电阻,从而影响电堆性能。目前常用的方法是在双极板表面制备高导电的耐蚀涂层以提高性能。基于此,本文介绍了氮化钛、氮化铬、氮化铌等氮化物涂层在PEMFC领域的应用,并对氮化物涂层未来的研究方向给出了建议。
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李涛
关键词:  质子交换膜燃料电池  金属双极板  氮化物涂层  耐腐蚀性能  导电性能    
Abstract: Proton exchange membrane fuel cell (PEMFC) is considered an ideal portable power device with the advantages of high energy density, high conversion efficiency and environmental friendliness. Meanwhile, PEMFC is also not limited by the Carnot cycle. As one of the core components of PEMFC, the metal bipolar plate should exhibit both excellent corrosion resistance and high electrical conductivity. However, the metal is easily corroded to generate metal ions in acidic and humid PEMFC environments, which could destroy the proton membrane. At the same time, the low conductivity oxide formed on the metal surface would increase the interface contact resistance between the bipolar plate and gas diffusion layer, which would further affect the performance of the stack. At present, depositing the coating with high corrosion resistance and electrical conductivity is a common method to improve the performance of bipolar plates. Based on this, the applications of nitride coatings such as titanium nitride, chromium nitride, and niobium nitride in the PEMFC field are introduced in this paper, and the future research directions of nitride coatings are also suggested.
Key words:  proton exchange membrane fuel cell    metal bipolar plate    nitride coating    corrosion resistance    electrical conductivity
出版日期:  2026-03-25      发布日期:  2026-04-03
ZTFLH:  TK91  
基金资助: 东方电气集团东方锅炉股份有限公司科研项目(3522030)
通讯作者:  *李涛,博士,东方电气集团东方锅炉股份有限公司材料研发部技术研发人员,主要从事电站锅炉、光热电站、氢能等能源领域用功能材料的应用研究,以及表面技术、失效分析等工作。930405614@qq.com   
引用本文:    
李涛. 氮化物涂层在PEMFC金属双极板领域的应用[J]. 材料导报, 2026, 40(6): 25010055-10.
LI Tao. Application of Nitride Coatings in the Field of PEMFC Metal Bipolar Plates. Materials Reports, 2026, 40(6): 25010055-10.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25010055  或          https://www.mater-rep.com/CN/Y2026/V40/I6/25010055
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