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材料导报  2026, Vol. 40 Issue (6): 25010106-7    https://doi.org/10.11896/cldb.25010106
  金属与金属基复合材料 |
MWCNTs对放电等离子烧结制备Ti(C,N)微观结构和综合性能的影响
乔木, 赵志伟*, 穆柄运, 张涵
河南工业大学材料科学与工程学院,郑州 450001
Effect of MWCNTs on Microstructure and Mechanical Properties of Ti(C,N) Prepared by Spark Plasma Sintering
QIAO Mu, ZHAO Zhiwei*, MU Bingyun, ZHANG Han
College of Materials Science and Engineering, Henan University of Technology, Zhengzhou 450001, China
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摘要 Ti(C,N)基金属陶瓷韧性较差影响了其发展和应用。为了改善这种缺陷,以多壁碳纳米管(MWCNTs)为添加剂,使用放电等离子烧结(SPS)炉,设置25 MPa的烧结压力、12 min的保温时间和1 400 ℃的烧结温度制备Ti(C,N)基金属陶瓷。通过微观结构分析和综合性能测试得出,MWCNTs含量为0.4%(质量分数,下同)的Ti(C,N)基金属陶瓷综合性能最佳。该金属陶瓷微观结构中出现界面分明的芯-环结构,Ti(C,N)硬质相晶粒尺寸平均值最小为0.50 μm。此时,该样品密度为6.39 g/cm3,维氏硬度为2 032HV,断裂韧性为11.6 MPa·m1/2,饱和磁化强度为6.2 emu/g。与未添加多壁碳纳米管的金属陶瓷相比,维氏硬度提高了8%,断裂韧性提高了29%。SPS可以促进金属陶瓷的致密化,从而提高金属陶瓷的力学性能。适当添加多壁碳纳米管可以抑制晶粒长大,在多壁碳纳米管的桥接-拔出机制共同作用下,金属陶瓷的断裂韧性提升较为明显。
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乔木
赵志伟
穆柄运
张涵
关键词:  多壁碳纳米管(MWCNTs)  Ti(C,N)  放电等离子烧结(SPS)  微观结构  力学性能    
Abstract: The inherently low toughness of Ti(C, N)-based cermets has limited their development and practical application. To overcome this limitation, Ti(C, N)-based cermets were fabricated by incorporating multi-walled carbon nanotubes (MWCNTs) as reinforcing agents, using spark plasma sintering (SPS) under optimized conditions:a sintering pressure of 25 MPa, a holding time of 12 min, and a sintering temperature of 1 400 ℃. Microstructural analysis and comprehensive property evaluation revealed that the Ti(C, N)-based cermet achieved its optimal perfor-mance at an MWCNTs content of 0.4wt%. The microstructure exhibits a distinct core-ring configuration with well-defined interfaces, and the Ti(C, N) hard-phase grains are refined to a minimum size of 0.50 μm. Under these optimized conditions, the sample achieves a density of 6.39 g/cm3, a Vickers hardness of 2 032HV, a fracture toughness of 11.6 MPa·m1/2, and a saturation magnetization strength of 6.2 emu/g. Compared to the cermet without MWCNTs, the sample shows an 8% increase in Vickers hardness and a 29% improvement in fracture toughness. SPS promotes the densification and enhances the mechanical properties of cermets. A suitable amount of MWCNTs inhibits grain growth, while the synergistic effects of their bridging and pull-out mechanisms lead to a notable improvement in fracture toughness.
Key words:  multi-walled carbon nanotubes (MWCNTs)    Ti(C,N)    spark plasma sintering (SPS)    microstructure    mechanical property
出版日期:  2026-03-25      发布日期:  2026-04-03
ZTFLH:  TG148  
基金资助: 国家自然科学基金(52274362)
通讯作者:  *赵志伟,博士,河南工业大学材料科学与工程学院教授、博士研究生导师。主要从事超硬材料制品、金属陶瓷基复合材料相关研究。zhiwei_zhao@haut.edu.cn   
作者简介:  乔木,河南工业大学材料科学与工程学院硕士研究生,在赵志伟教授的指导下研究放电等离子烧结和Ti(C,N)基金属陶瓷。
引用本文:    
乔木, 赵志伟, 穆柄运, 张涵. MWCNTs对放电等离子烧结制备Ti(C,N)微观结构和综合性能的影响[J]. 材料导报, 2026, 40(6): 25010106-7.
QIAO Mu, ZHAO Zhiwei, MU Bingyun, ZHANG Han. Effect of MWCNTs on Microstructure and Mechanical Properties of Ti(C,N) Prepared by Spark Plasma Sintering. Materials Reports, 2026, 40(6): 25010106-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25010106  或          https://www.mater-rep.com/CN/Y2026/V40/I6/25010106
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