Abstract: The inherently low toughness of Ti(C, N)-based cermets has limited their development and practical application. To overcome this limitation, Ti(C, N)-based cermets were fabricated by incorporating multi-walled carbon nanotubes (MWCNTs) as reinforcing agents, using spark plasma sintering (SPS) under optimized conditions:a sintering pressure of 25 MPa, a holding time of 12 min, and a sintering temperature of 1 400 ℃. Microstructural analysis and comprehensive property evaluation revealed that the Ti(C, N)-based cermet achieved its optimal perfor-mance at an MWCNTs content of 0.4wt%. The microstructure exhibits a distinct core-ring configuration with well-defined interfaces, and the Ti(C, N) hard-phase grains are refined to a minimum size of 0.50 μm. Under these optimized conditions, the sample achieves a density of 6.39 g/cm3, a Vickers hardness of 2 032HV, a fracture toughness of 11.6 MPa·m1/2, and a saturation magnetization strength of 6.2 emu/g. Compared to the cermet without MWCNTs, the sample shows an 8% increase in Vickers hardness and a 29% improvement in fracture toughness. SPS promotes the densification and enhances the mechanical properties of cermets. A suitable amount of MWCNTs inhibits grain growth, while the synergistic effects of their bridging and pull-out mechanisms lead to a notable improvement in fracture toughness.
1 Kang X Y, Lin N, He Y H, et al. Ceramics International, 2021, 47(14), 19934. 2 Besharatloo H, Nicolás M de, Roa J J, et al. Ceramics International, 2019, 45(16), 20202. 3 Zhang M M, Jiang Y, Lin N, et al. Corrosion Science, 2020, 177, 108959. 4 Lengauer W, Scagnetto F. Solid State Phenomena, 2018, 274, 53. 5 Wang X L, Wang Q F, Dong Z J, et al. Metals, 2020, 10(7), 927. 6 Yu H J, Liu Y, Jin Y Z, et al. International Journal of Refractory Metals and Hard Materials, 2011, 29(5), 586. 7 Li P P, Ye J W, Liu Y, et al. International Journal of Refractory Metals and Hard Materials, 2012, 35, 27. 8 Qiu H, Li X Q, Pan C L, et al. Journal of Materials Research and Technology, 2023, 25, 750. 9 Zhao L B, Lin N, Han X Q, et al. Metals and Materials International, 2021, 27, 2773. 10 Chen B, Shen J, Ye X, et al. Acta Materialia, 2017, 140, 317. 11 De Volder M F L, Tawfick S H, Baughman R H, et al. Science, 2013, 339(6119), 535. 12 Wu P, Liu S C, Jiang X R. Journal of Advanced Ceramics, 2018, 7, 58. 13 Hu Z Y, Zhang Z H, Cheng X W, et al. Materials & Design, 2020, 191, 108662. 14 Falodun O E, Obadele B A, Oke S R, et al. The International Journal of Advanced Manufacturing Technology, 2019, 102, 1689. 15 Lóh N J, Simão L, Faller C A, et al. Ceramics International, 2018, 42(11), 12556. 16 Han C L, Tian C G. Powder Metallurgy and Metal Ceramics, 2014, 53, 57. 17 Khanna V, Kumar V, Bansal S A. Materials Research Bulletin, 2021, 138, 111224. 18 Okpalugo T I T, Papakonstantinou P, Murphy H, et al. Carbon, 2005, 43(1), 153. 19 Xiao P, Ge X M, Wang H B, et al. Advanced Functional Materials, 2015, 25(10), 1520. 20 Zhang G G, Zhao Z W, Zheng H J, et al. Materials Characterization, 2022, 193, 112289. 21 Xi Z W, Jia W Z, Zhu Z R. Catalysis Letters, 2021, 151, 124. 22 Ke Z, Zheng Y, Zhang G T. et al. Ceramics International, 2020, 46(8), 12767. 23 Wang C G, Zhao S S, Song X X, et al. Advanced Energy Materials, 2022, 12(19), 2200157. 24 Jiang H, Fu S Y, Zhang Z C, et al. Molecules, 2024, 29(7), 1678. 25 Sadeghi B, Tan Z Q, Qi J S, et al. Composites Part B:Engineering, 2021, 223, 109133. 26 Dong D Q, Yang W, Xiang X, et al. Ceramics International, 2021, 47(6), 8020.