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材料导报  2026, Vol. 40 Issue (6): 25040155-11    https://doi.org/10.11896/cldb.25040155
  无机非金属及其复合材料 |
低温等离子体在钠离子电池负极材料制备与改性中的应用
王旭1,2,3,†, 何心4,†, 解志鹏1,2,3, 张达1,2,3,*, 侯圣平1,2,3, 吴越1,2,3, 东鹏1,2,3, 陈嘉乐1,2,3, 梁风1,2,3,*
1 昆明理工大学真空冶金国家工程研究中心,昆明 650093;
2 昆明理工大学云南省有色金属真空冶金重点实验室,昆明 650093;
3 昆明理工大学冶金与能源工程学院,昆明 650093;
4 昆明理工大学体育学院,昆明 650500
Application of Low Temperature Plasma in the Anode Preparation and Modification of Sodium Ion Battery
WANG Xu1,2,3,†, HE Xin4,†, XIE Zhipeng1,2,3, ZHANG Da1,2,3,*, HOU Shengping 1,2,3, WU Yue1,2,3, DONG Peng1,2,3, CHEN Jiale1,2,3, LIANG Feng1,2,3,*
1 National Engineering Research Center for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, China;
2 Key Laboratory for Nonferrous Vacuum Metallurgy of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, China;
3 Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China;
4 Faculty of Physical Education, Kunming University of Science and Technology, Kunming 650500, China
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摘要 钠离子电池(SIBs)因其优异的低温性能和丰富的钠资源储量而备受关注。负极材料作为SIBs的关键组成部分,直接影响其能量密度和功率密度等性能,然而,目前负极材料面临着化学反应动力学迟缓、体积膨胀大、容量低、首圈库仑效率低等关键问题。为了解决上述问题,研究者们通过各种材料制备与改性手段以提高电池性能,这对推进钠离子电池的实际应用极为重要。低温等离子体因其高能活性粒子可突破热力学限制、低温处理可避免基材热损、干式处理工艺无需化学溶剂介入等优点,在材料制备与改性方面具有广阔的应用前景。本文系统介绍低温等离子体技术在SIBs负极材料的制备、结构调控、界面优化及活性基团引入等方面的应用进展。最后,展望了低温等离子体在电池材料制备与改性领域应用未来的研究前景。
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王旭
何心
解志鹏
张达
侯圣平
吴越
东鹏
陈嘉乐
梁风
关键词:  钠离子电池  负极材料  低温等离子体  制备  改性    
Abstract: Sodium-ion batteries (SIBs) have attracted much attention because of their excellent low-temperature performance and abundant sodium resources. Anode materials, which are a key component of SIBs, determine the energy density and power density of SIBs. However, anode materials faced several challenges of sluggish kinetics, volume expansion, low connectivity, low initial coulombic efficiency, etc. To solve the aforementioned issues, various material preparation and modification methods are utilized by researchers to enhance battery performance, which is crucial for advancing the practical application of SIBs. Because of its advantages of high reactive particles that can break through thermodyna-mic limits and avoid heat loss of substrate and solvent-free dry processing, low-temperature plasma has a broad application prospect in material preparation and modification. In this paper, the application of low-temperature plasma technology in the preparation, structure control, interface optimization, and introduction of active groups of SIB anode materials is systematically reviewed. Finally, prospects for future research and applications of low-temperature plasma in battery material synthesis and modification are outlined.
Key words:  sodium ion battery    anode material    low-temperature plasma    preparation    modification
出版日期:  2026-03-25      发布日期:  2026-04-03
ZTFLH:  O646  
基金资助: 国家自然科学基金(12205127;12175089);云南省科技厅基础研究计划(202401AV070008;202301AS070051;202401AT070329;202301BE070001-052;202301AU070064);云南省“兴滇英才支持计划”(KKXY202252001;KKXX202452067)
通讯作者:  *张达,博士,昆明理工大学讲师,硕士研究生导师,主要从事等离子体冶金、材料制备与改性等方面的研究。zhangda@kust.edu.cn
梁风,博士,昆明理工大学教授,博士研究生导师,日本九州大学客座教授。主要从事等离子体冶金及等离子体制备改性功能材料等方面的研究。 liangfeng@kust.edu.cn   
作者简介:  王旭,昆明理工大学冶金与能源工程学院硕士研究生,在梁风教授的指导下研究等离子体改性钠离子电池硬碳负极。
†共同第一作者
引用本文:    
王旭, 何心, 解志鹏, 张达, 侯圣平, 吴越, 东鹏, 陈嘉乐, 梁风. 低温等离子体在钠离子电池负极材料制备与改性中的应用[J]. 材料导报, 2026, 40(6): 25040155-11.
WANG Xu, HE Xin, XIE Zhipeng, ZHANG Da, HOU Shengping, WU Yue, DONG Peng, CHEN Jiale, LIANG Feng. Application of Low Temperature Plasma in the Anode Preparation and Modification of Sodium Ion Battery. Materials Reports, 2026, 40(6): 25040155-11.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25040155  或          https://www.mater-rep.com/CN/Y2026/V40/I6/25040155
1 Xu N S, Li X, Zhao X, et al. Energy & Environmental Science, 2011, 4, 4942.
2 Goodenough J B, Kim Y. Chemistry of Materials, 2010, 22, 587.
3 Simon P, Gogotsi Y. Nature Materials, 2008, 7, 845.
4 Tarascon J M, Armand M. Nature, 2001, 414, 359.
5 Armand M, Tarascon J M. Nature, 2008, 451, 652.
6 Eftekhari A, Kim D W. Journal of Power Sources, 2018, 395, 336.
7 Tian Z H, Zhang Y, Zhu J X, et al. Advanced Energy Materials, 2021, 11, 17.
8 Bin D S, Li Y M, Sun Y G, et al. Advanced Energy Materials, 2018, 8, 8.
9 Zhang B A, Rousse G, Foix D, et al. Advanced Materials, 2016, 28, 9824.
10 Wang X G, Li Q C, Zhang L, et al. Advanced Materials, 2018, 30, 10.
11 Qian J F, Wu X Y, Cao Y L, et al. Angewandte Chemie-International Edition, 2013, 52, 4633.
12 Zhu Y J, Wen Y, Fan X L, et al. ACS Nano, 2015, 9, 3254.
13 Nayak P K, Yang L T, Brehm W, et al. Angewandte Chemie-International Edition, 2018, 57, 102.
14 Wang C L, Xu Y, Fang Y G, et al. Journal of the American Chemical Society, 2015, 137, 3124.
15 Wei Z Q, Mao P C, Liu C, et al. ACS Applied Materials & Interfaces, 2021, 13, 58652.
16 Liu H W, Tao L, Zhang Y Q, et al. ACS Applied Materials & Interfaces, 2017, 9, 36849.
17 Kim J H, Yun J H, Kim D K. Advanced Energy Materials, 2018, 8, 1703499.
18 Yu X Q, Pan H L, Wan W, et al. Nano Letters, 2013, 13, 4721.
19 Xiao L F, Lu H Y, Fang Y J, et al. Advanced Energy Materials, 2018, 8, 1703238.
20 Sun T, Liu G Y, Du L Y, et al. Materials Today Energy, 2020, 16, 100395.
21 Eder S, Yoo D J, Nogala W, et al. Angewandte Chemie-International Edition, 2020, 59, 12958.
22 Gu S, Wu S F, Cao L J, et al. Journal of the American Chemical Society, 2019, 141, 9623.
23 Mao P Y, Wang Y, Xiao P D, et al. Journal of Alloys and Compounds, 2022, 892, 162157.
24 Lin Y M, Qiu Z Z, Li D Z, et al. Energy Storage Materials, 2018, 11, 67.
25 Tan X Y, Mo R W, Xu J H, et al. Advanced Energy Materials, 2022, 12, 2102345.
26 Chong S K, Sun L, Shu C Y, et al. Nano Energy, 2019, 63, 103868.
27 Liang Z X, Li Q H, Zhang W, et al. Journal of Energy Chemistry, 2022, 75, 369.
28 Dong S H, Li C X, Li Z Q, et al. Small, 2018, 14, 10.
29 Qie L, Chen W M, Xiong X Q, et al. Advanced Science, 2015, 2, 1500195.
30 Chen X Y, Liu C Y, Fang Y J, et al. Carbon Energy, 2022, 4, 1133.
31 Sun Y, Wu Q J, Liang X, et al. Materials Chemistry Frontiers, 2021, 5, 4089.
32 Kogelschatz U. Plasma Chemistry and Plasma Processing, 2003, 23, 1.
33 Li K, Tang X L, Yi H H, et al. Applied Surface Science, 2013, 264, 557.
34 Tu X, Man W D, You Z H, et al. Vaccum and Cryogenics, 2014, 20(2), 63(in Chinese).
涂昕, 满卫东, 游志恒, 等. 真空与低温, 2014, 20(2), 63.
35 Chen J, Weng Y, Yuan X N, et al. Journal of Chemical Engineering of Chinese Universities, 2011, 25(3), 495(in Chinese).
陈杰, 翁扬, 袁细宁, 等. 高校化学工程学报, 2011, 25(3), 495.
36 Shao H Y, Wang Y T, Xu H R, et al. Materials Science and Engineering B-Solid State Materials for Advanced Technology, 2004, 110, 221.
37 Donnelly V M, Kornblit A. P Journal of Vacuum Science & Technology A, 2013, 31, 48.
38 Pandiyaraj K N, Selvarajan V, Deshmukh R R, et al. Plasma Science and Technology, 2013, 15, 56.
39 Zhou Q, Zhao Z B, Chen Y S, et al. Journal of Materials Chemistry, 2012, 22, 6061.
40 Gagnon H, Piyakis K, Wertheimer M R. Plasma Processes and Polymers, 2014, 11, 106.
41 Liu Y C, Xie Z P, Lu S Q, et al. Dalton Transactions, 2024, 53, 11454.
42 Yao Z Y, Kang Y, Hou M J, et al. Advanced Functional Materials, 2022, 32, 2111919.
43 Lu S Q, Xie Z P, Zhang D, et al. Carbon, 2024, 230, 119632.
44 Phelps A, Petrović Z L, Jelenković B. Physical Review E, 1993, 47, 2825.
45 Chen Q, Li J S, Li Y F. Journal of Physics D-Applied Physics, 2015, 48, 26.
46 Romanelli F, Laxaback M, Abel I, et al. Nuclear Fusion, 2011, 51, 22.
47 Ye K, Liang F, Yao Y C, et al. Materials Reports, 2019, 33(7), 1089(in Chinese).
叶凯, 梁风, 姚耀春, 等. 材料导报, 2019, 33(7), 1089.
48 Pütterich T, Dux R, Neu R, et al. Plasma Physics and Controlled Fusion, 2013, 55, 11.
49 Gurnett D A, Kurth W S, Stone E C, et al. Astronomical Journal, 2021, 161, 11.
50 Petitpas G, Rollier J D, Darmon A, et al. International Journal of Hydrogen Energy, 2007, 32, 2848.
51 Foest R, Schmidt M, Becker K. International Journal of Mass Spectrometry, 2006, 248, 87.
52 Duan S X, Liu X, Wang Y N, et al. Plasma Processes and Polymers, 2017, 14, 21.
53 Sun X, Bao J C, Li K, et al. Advanced Functional Materials, 2021, 31, 26.
54 Yang Y, Huang B C, Ye D Q. Chemical Industry and Engineering Progress, 2008(11), 1760(in Chinese).
杨岳, 黄碧纯, 叶代启. 化工进展, 2008(11), 1760.
55 Luo F. Study on adsorption properties of low temperature plasma modified carbon materials. Ph. D. Thesis, Zhejiang University, China, 2009(in Chinese).
罗凡. 低温等离子体改性碳材料吸附性能的研究. 博士学位论文, 浙江大学, 2009.
56 Kogelschatz U, Eliasson B, Egli W. Pure and Applied Chemistry, 1999, 71, 1819.
57 Shenton M J, Stevens G C. Journal of Physics D-Applied Physics, 2001, 34, 2761.
58 Kim H H. Plasma Processes and Polymers, 2004, 1, 91.
59 Qiu Y C, Shi W, Zhang W Y. High voltage engineering, Xi'an Jiaotong University Press, China, 1995, pp. 66(in Chinese).
邱毓昌, 施围, 张文元. 高电压工程, 西安交通大学出版社, 1995, pp. 66.
60 Zhang D, Mylsamy G, Yang X X, et al. Ceramics International, 2021, 47, 16972.
61 Wang H, Sun Y Z, Fang Z, et al. China Dyeing and Finishing, 2005(19), 5(in Chinese).
王辉, 孙岩洲, 方志, 等. 印染, 2005(19), 5.
62 Sun J, Zheng G Y, Lee H W, et al. Nano Letters, 2014, 14, 4573.
63 Morrish R, Silverstein R, Wolden C A. Journal of the American Chemical Society, 2012, 134, 17854.
64 Shi Y M, Zhang B. Chemical Society Reviews, 2016, 45, 1781.
65 Lee J, Williams T S, Hicks R F. Journal of Vacuum Science & Technology A, 2021, 39, 9.
66 Chen J, Shi X R, Qi S J, et al. Carbon, 2015, 95, 338.
67 Ouyang B, Zhang Y, Xia X, et al. Materials Today Nano, 2018, 3, 28.
68 Morrish R, Haak T, Wolden C A. Chemistry of Materials, 2014, 26, 3986.
69 Liang H F, Gandi A N, Anjum D H, et al. Nano Letters, 2016, 16, 7718.
70 Friedrich J. Plasma Processes and Polymers, 2011, 8, 783.
71 Srinivasan R, Demirev P A, Carkhuff B G, et al. Journal of the Electrochemical Society, 2020, 167, 8.
72 Jäckle M, Gross A. Journal of Chemical Physics, 2014, 141, 7.
73 Zhao S Q, Guo Z Q, Yang J, et al. Small, 2021, 17, 5.
74 Sun Y, Wu Q J, Liang X, et al. Materials Chemistry Frontiers, 2021, 5, 4089.
75 Zhen Y C, Chen Y, Li F, et al. Proceedings of the National Academy of Sciences, 2021, 118, e2111119118.
76 Yan X M, Liang S T, Shi H T, et al. Journal of Colloid and Interface Science, 2021, 583, 535.
77 Kim H, Kim D Y, Zen S, et al. ACS Applied Materials & Interfaces, 2020, 12, 43750.
78 Wang W G, Liu Y, Wu X, et al. Advanced Materials Technologies, 2018, 3, 20.
79 Aravindan V, Lee Y S, Yazami R, et al. Materials Today, 2015, 18, 345.
80 Dawson J A, Robertson J. Journal of Physical Chemistry C, 2016, 120, 22910.
81 Liu Y, Zhao F P, Li J T, et al. Journal of Materials Chemistry A, 2017, 5, 20005.
82 He H N, Huang D, Pang W K, et al. Advanced Materials, 2018, 30, 8.
83 Cai Q L, Li X L, Hu E T, et al. Small, 2022, 18, 10.
84 Gan Q M, He H N, Zhao K M, et al. ACS Applied Materials & Interfaces, 2018, 10, 7031.
85 Song J J, Lee D H, Oh S M, et al. Journal of Alloys and Compounds, 2023, 941, 8.
86 Natarajan S, Subramanyan K, Aravindan V. Small, 2019, 15, 14.
87 Zhang X, Zhou Y P, Luo B, et al. Nano-Micro Letters, 2018, 10, 7.
88 Huang B, Tai K P, Zhang M G, et al. Electrochimica Acta, 2014, 118, 143.
89 Yang H, Xu R, Gong Y, et al. Nano Energy, 2018, 48, 448.
90 Wang Q Q, Ma Y J, Liu L, et al. Nanomaterials, 2020, 10, 12.
91 Cheng D L, Liu J W, Li X, et al. Journal of Power Sources, 2017, 350, 1.
92 Hwang J Y, Myung S T, Sun Y K. Chemical Society Reviews, 2017, 46, 3529.
93 Zhang H, Hasa I, Passerini S. Advanced Energy Materials, 2018, 8, 40.
94 Fu Y P, Zhang Z B, Zhu C B. Nanoscale, 2020, 12, 16716.
95 Luo M H, Yu H X, Hu F Y, et al. Chemical Engineering Journal, 2020, 380, 32.
96 Zhou Q, Liu L, Huang Z F, et al. Journal of Materials Chemistry A, 2016, 4, 5505.
97 Chao D L, Ouyang B, Liang P, et al. Advanced Materials, 2018, 30, 6.
98 Tang B, Qi G Y, Sun X Y, et al. Molecular Cancer, 2016, 15, 12.
99 Nandi D K, Yeo S, Ansari M Z, et al. Electrochim Acta, 2019, 322, 10.
100 Yeo S, Nandi D K, Rahul R, et al. Applied Surface Science, 2018, 459, 596.
101 Sreedhara M B, Gope S, Vishal B, et al. Journal of Materials Chemistry A, 2018, 6, 2302.
102 Fu Y Q, Wei Q L, Zhang G X, et al. Advanced Energy Materials, 2018, 8, 28.
103 Lao M M, Zhang Y, Luo W B, et al. Advanced Materials, 2017, 29, 23.
104 Tan H T, Chen D, Rui X H, et al. Advanced Functional Materials, 2019, 29, 32.
105 Perveen T, Siddiq M, Shahzad N, et al. Renewable & Sustainable Energy Reviews, 2020, 119, 30.
106 Cheng D L, Wei A K, Ye L Y, et al. ACS Sustainable Chemistry & Engineering, 2022, 10, 12177.
107 Park G D, Lee J H, Kang Y C. Nanoscale, 2016, 8, 11889.
108 Lee J S, Saroha R, Cho J S. Nano-Micro Letters, 2022, 14, 22.
109 Lu C, Li Z Z, Xia Z, et al. Nano Research, 2019, 12, 3051.
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[6] Ping ZHU,Guanghui DENG,Xudong SHAO. Review on Dispersion Methods of Carbon Nanotubes in Cement-based Composites[J]. Materials Reports, 2018, 32(1): 149 -158 .
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