亚铁离子对硫酸盐还原菌腐蚀行为的影响

doi:10.11896/cldb.25020003

材料导报

2026, Vol. 40

Issue (5): 25020003-9 https://doi.org/10.11896/cldb.25020003

金属与金属基复合材料

亚铁离子对硫酸盐还原菌腐蚀行为的影响

张雅妮^1,*, 段博文¹, 宋伟¹, 张成鑫¹, 樊冰², 王思敏³

1 西安石油大学材料科学与工程学院,西安 710065;
2 中国石油集团工程材料研究院有限公司,西安 710077;
3 首钢集团长治钢铁有限公司,山西长治 046031

Effect of Ferrous Ion on the Corrosion Behavior of Sulfate-reducing Bacteria

ZHANG Yani^1,*, DUAN Bowen¹, SONG Wei¹, ZHANG Chengxin¹, FAN Bing², WANG Simin³

1 School of Materials Science and Engineering, Xi'an Shiyou University, Xi'an 710065, China;
2 China National Petroleum Engineering Materials Research Institute Co., Ltd., Xi'an 710077, China;
3 Shougang Group Changzhi Iron and Steel Co., Ltd., Changzhi 046031, Shanxi, China

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摘要亚铁离子(Fe²⁺)对SRB的生长和对碳钢的MIC起重要作用。本工作通过生物培养技术、浸泡实验、电化学等实验方法,结合Na₂S₂O₃滴定技术、扫描电镜(SEM)、X射线光电子能谱(XPS)、激光共聚焦等分析手段,研究了Fe²⁺对硫酸盐还原菌环境中X80管线钢腐蚀行为的影响,包含SRB数量的变化、硫离子含量及价态的变化、表面生物膜的特征,截面形貌、腐蚀速率及电化学过程特征。结果表明:Fe²⁺浓度为5 g/L时,Fe²⁺促进SRB的生长,延长SRB的生命周期,峰值SRB数量为5.15×10⁷ cm^-3;但高浓度Fe²⁺(≥10 g/L)抑制了SRB的生长,缩短SRB的生命周期。对于SRB腐蚀,在低浓度Fe²⁺环境中,初期腐蚀速率由Fe²⁺对基体表面的活化和对SRB的活性促进共同决定,中后期由致密的SRB膜层决定,因此X80钢腐蚀速率随暴露时间的延长先增加后降低。在高浓度Fe²⁺环境中,初期腐蚀速率由Fe²⁺对基体表面的活化和低活性SRB共同决定,中后期由多裂隙混生膜层决定,腐蚀速率随暴露时间的延长持续增加。20 d后,随溶液中Fe²⁺浓度的增加,X80钢的点蚀速率和平均失重速率同步增长,当Fe²⁺浓度为40 g/L时,最大平均失重速率为0.102 4 mm/a。

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关键词: 硫酸盐还原菌亚铁离子 X80钢腐蚀

Abstract: Ferrous ions (Fe²⁺) play an important role in the growth of SRB and MIC of carbon steel. In this work, the effects of Fe²⁺ on the corrosion behavior of X80 pipeline steel in the environment of sulfate-reducing bacteria were studied by biological culture technology, immersion experiment, electrochemistry and other experimental methods, combined with Na₂S₂O₃ titration technology, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), laser confocal and other analytical methods. The results showed that the Fe²⁺ of 5 g/L concentration promoted the growth of SRB and prolonged the life cycle of SRB, with a peak SRB quantity of 5.15×10⁷ cm^-3. High concentrations Fe²⁺ (≥10 g/L) inhibited the growth of SRB and shortened the life cycle of SRB. In the low concentration of Fe²⁺ environment, the corrosion rate is determined by activation of the substrate surface and high activity of SRB in the initial stage, and determined by the dense SRB film layer in the middle and late stages, so the corrosion rate of X80 steel increases and then decreases with the extension of exposure time. In the high concentration of Fe²⁺ environment, the corrosion rate is determined by activation of the substrate surface and lower activity of SRB in the initial stage, and is determined by the multi-cleavage miscible film layer in the middle and later stages, and the corrosion rate increases with the exposure time. After 20 days exposure, the pitting corrosion rate and the average rate of weight loss of the X80 steel increase synchronously, and the maximum average rate of weight loss is 0.102 4 mm/a when the concentration of Fe²⁺ is 40 g/L.

Key words: sulfate-reducing bacteria ferrous ions X80 steel corrosion

出版日期: 2026-03-10 发布日期: 2026-03-10

ZTFLH:

TG172

基金资助: 国家自然科学基金(52401111);陕西省自然科学基础研究计划(2024JC-YBQN-0457);高校院所科技人员服务企业项目(25GXKJRC00035)

通讯作者: ^*张雅妮,博士,西安石油大学材料科学与工程学院副教授、硕士研究生导师。目前主要从事金属材料的腐蚀与防护、石油器件的失效分析等研究工作。zhangyn@xsyu.edu.cn

引用本文:

张雅妮, 段博文, 宋伟, 张成鑫, 樊冰, 王思敏. 亚铁离子对硫酸盐还原菌腐蚀行为的影响[J]. 材料导报, 2026, 40(5): 25020003-9.
ZHANG Yani, DUAN Bowen, SONG Wei, ZHANG Chengxin, FAN Bing, WANG Simin. Effect of Ferrous Ion on the Corrosion Behavior of Sulfate-reducing Bacteria. Materials Reports, 2026, 40(5): 25020003-9.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.25020003 或 https://www.mater-rep.com/CN/Y2026/V40/I5/25020003

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