不同挤压道次FeCoCrNiMo/5083Al基复合材料的腐蚀性能研究

doi:10.11896/cldb.24120199

材料导报

2026, Vol. 40

Issue (5): 24120199-6 https://doi.org/10.11896/cldb.24120199

金属与金属基复合材料

不同挤压道次FeCoCrNiMo/5083Al基复合材料的腐蚀性能研究

钱思成¹, 贺毅强^1,2,*, 郇昌宝¹, 顾航¹, 王童¹, 陶凯¹, 黄威³, 贺晓¹, 曹颖¹, 卢翰文¹

1 江苏海洋大学机械工程学院,江苏连云港 222005;
2 上海电机学院机械学院,上海 200240;
3 连云港市沃新高新材料有限公司,江苏连云港 222303

Study on the Corrosion Performance of FeCoCrNiMo/5083Al Matrix Composites with Different Extrusion Passes

QIAN Sicheng¹, HE Yiqiang^1,2,*, HUAN Changbao¹, GU Hang¹, WANG Tong¹, TAO Kai¹, HUANG Wei³, HE Xiao¹, CAO Ying¹, LU Hanwen¹

1 School of Mechanical Engineering, Jiangsu Ocean University, Lianyungang 222005, Jiangsu, China;
2 Mechanical College, Shanghai Dianji Unviersity, Shanghai 200240, China;
3 Lianyungang Woshigh New Materials Co., Ltd., Lianyungang 222303, Jiangsu, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 34072KB )
输出: BibTeX | EndNote (RIS)

摘要 5083铝因优异的耐蚀性能和高强度,在船舶、海洋装备中得到广泛应用。本研究探讨了挤压道次及Cl^-浓度对15%(体积分数,若无特别说明,下同) FeCoCrNiMo HEA增强5083Al复合材料腐蚀行为的影响。结果表明,经1—4道次ECAP后,材料均呈现显著阳极钝化,腐蚀以点蚀为主。三道次挤压试样表现出最优耐蚀性,其E_corr与I_corr最佳。随着挤压道次的增加,晶粒显著细化,从而削弱了晶界处的成分偏聚并改善界面结合质量;与此同时,引入的适量位错可作为钝化膜成核的优先位点,共同促进耐蚀性的提升,晶粒细化与溶质再分配减弱晶界偏析、均化电化学响应并增强界面结合;适度位错和亚晶界缺陷促进钝化膜成核与自修复,从而提高耐蚀性;在等离子强度电解液中,Cl^-浓度升高主导腐蚀加剧,E_corr负移、I_corr增大、点蚀敏感性急剧升高。机制在于Cl^-溶解钝化膜、增大反应面积并强化基体-HEA电偶腐蚀效应。研究明确了优化挤压工艺及控制Cl^-环境对提升该复合材料海洋环境耐蚀性的关键作用。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	钱思成
	贺毅强
	郇昌宝
	顾航
	王童
	陶凯
	黄威
	贺晓
	曹颖
	卢翰文

关键词: 多道次等径角挤压高熵合金腐蚀点蚀

Abstract: AA5083 aluminum is widely used in ships and marine equipment owing to its excellent corrosion resistance and high strength. This work investigates the effects of ECAP pass number and Cl^- concentration on the corrosion behavior of a 15 vol% FeCoCrNiMo HEA-reinforced AA5083 composite. The results show that after 1—4 ECAP passes, all specimens exhibit pronounced anodic passivation, with pitting as the do-minant corrosion mode. The three-pass condition delivers the best corrosion resistance, as evidenced by the most favorable E_corr and I_corr. With increasing pass number, grain refinement and solute redistribution mitigate grain-boundary segregation, homogenize the electrochemical response, and strengthen interfacial metallurgical bonding; meanwhile, an appropriate density of dislocations and subgrain boundaries promotes rapid nuc-leation and self-healing of the passive film, thereby improving corrosion resistance. In electrolytes of higher ionic strength, the elevated Cl^- concentration becomes the governing factor that aggravates corrosion, leading to a negative shift of E_corr, an increase in I_corr, and a sharp rise in pitting susceptibility. This behavior is attributed to Cl^- induced dissolution of the passive film, enlargement of the effective reaction area, and the intensified galvanic coupling between the Al matrix and the HEA reinforcement. These findings highlight that optimizing the ECAP processing route and controlling Cl^- containing environments are critical to enhancing the marine corrosion resistance of this composite.

Key words: multi-channel equal-diameter angular extrusion high entropy alloy corrosion pitting corrosion

出版日期: 2026-03-10 发布日期: 2026-03-10

ZTFLH:

GT146.2

基金资助: 江苏省自然科学基金(BK20201467);江苏省“333高层次人才培养工程”科研资助项目(JXQC-058);江苏省研究生科研与实践创新计划项目(KYCX2024-40); 江苏省高等学校自然科学研究项目(18KJB430008); 连云港市科技计划项目(CG2227)

通讯作者: ^*张雅妮,博士,西安石油大学材料科学与工程学院副教授、硕士研究生导师。目前主要从事金属材料的腐蚀与防护、石油器件的失效分析等研究工作。zhangyn@xsyu.edu.cn

作者简介: 钱思成,江苏海洋大学机械工程学院硕士研究生,主要研究领域为颗粒增强铝基复合材料和层压复合材料。

引用本文:

钱思成, 贺毅强, 郇昌宝, 顾航, 王童, 陶凯, 黄威, 贺晓, 曹颖, 卢翰文. 不同挤压道次FeCoCrNiMo/5083Al基复合材料的腐蚀性能研究[J]. 材料导报, 2026, 40(5): 24120199-6.
QIAN Sicheng, HE Yiqiang, HUAN Changbao, GU Hang, WANG Tong, TAO Kai, HUANG Wei, HE Xiao, CAO Ying, LU Hanwen. Study on the Corrosion Performance of FeCoCrNiMo/5083Al Matrix Composites with Different Extrusion Passes. Materials Reports, 2026, 40(5): 24120199-6.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24120199 或 https://www.mater-rep.com/CN/Y2026/V40/I5/24120199

1 Jaume J, Marques M, Délia M L, et al. Corrosion Science, 2022, 194, 109934.
2 Su T, Zhao Y J, Hu Z L, et al. Nonferrous Metals Engineering, 2020, 10(7), 32 (in Chinese).
苏天, 赵艳君, 胡治流, 等. 有色金属工程, 2020, 10(7), 32.
3 Aballe A, Bethencourt M, Botana F, et al. Corrosion Science, 2001, 43(9), 1657.
4 Ezuber H, El H A, El S F. Materials & Design, 2008, 29(4), 801.
5 Gimenez P, Rameau J, Reboul M. Corrosion, 1981, 37(12), 673.
6 Ananiadis E, Argyris K T, Matikas T E, et al. Applied Sciences, 2021, 11 (3), 1300.
7 Bogdanov R, Vorkel V, Ignatenko V, et al. Materials Chemistry and Physics, 2023, 295, 127123.
8 Wang N, Wu B, Wu W, et al. Materials Today Communications, 2020, 25, 101366.
9 Segal V. Materials Science and Engineering: A, 1999, 271(1-2), 322.
10 Estrin Y, Vinogradov A. Acta Materialia, 2013, 61(3), 782.
11 Singh N, Agrawal M K. Results in Engineering, 2024, 22, 102221.
12 Abd E A M I. Journal of Materials Research and Technology, 2020, 9 (6), 12525.
13 Deng C, Wang T, Wu P, et al. Nano Energy, 2023, 120, 109153.
14 Quanbing L, Zongde L, Shengyang G, et al. Journal of Chinese Society for Corrosion and Protection, 2021, 41(6), 883.
15 Yang Y, Zhou W, Tong Z, et al. Journal of Materials Engineering and Performance, 2019, 28(9), 6081.
16 Dai C, Zhao T, Du C, et al. Journal of Materials Science & Technology, 2020, 46(5), 64.
17 Jin L L, Tong X L, Chen W. Materials Letters, 2016, 171(13), 38.
18 Tobler W, Virtanen S. Corrosion Science, 2006, 48 (7), 1585.
19 Esquivel J, Murdoch H, Darling K, et al. Materials Research Letters, 2018, 6 (1), 79.
20 Mishra S, Beura V K, Singh A, et al. Materials Science and Enginee-ring: A, 2018, 729, 102.
21 Glenn A M, Hughes A E, Torpy A, et al. Surface and Interface Analysis, 2016, 48 (8), 780.
22 Duarte M J, Klemm J, Klemm S O, et al. Science, 2013, 341 (6144), 372.
23 Xiao D, Zhou P, Wu W, et al. Materials & Design, 2017, 116, 438.
24 Gollapudi S. Corrosion Science, 2012, 62, 90.
25 Rybal C O, Martynenko N, Anisimova N Y, et al. Russian Metallurgy (Metally), 202, 2022 (11), 1386.
26 Balyanov A, Kutnyakova J, Amirkhanova N, et al. Scripta Materialia, 2004, 51(3), 225.
27 Derakhshandeh M, Farvizi M, Javaheri M. Journal of Solid State Electrochemistry, 2021, 25(1), 279.
28 Xia D H, Ji Y, Zhang R, et al. Corrosion Science, 2023, 213, 110985.
29 Munoz A, Saidman S, Bessone J. Corrosion Science, 2002, 44(10), 2171.
30 Shi Y, Collins L, Balke N, et al. Applied Surface Science, 2018, 439, 533.
31 Sugimoto K, Sawada Y. Corrosion Science, 1977, 17(5), 425.
32 Wang C J, Chen Q J, Xia H X. Transactions of Nonferrous Metals Society of China, 2017, 27(12), 2663.
33 Zaid B, Saidi D, Benzaid A, et al. Corrosion Science, 2008, 50(7), 1841.
34 Li T, Li X G, Dong C F, et al. Chinese Journal of Engineering, 2009, 31(12), 1576.
35 Szklarska S Z. Corrosion Science, 1992, 33(8), 1193.

[1]	张雅妮, 段博文, 宋伟, 张成鑫, 樊冰, 王思敏. 亚铁离子对硫酸盐还原菌腐蚀行为的影响[J]. 材料导报, 2026, 40(5): 25020003-9.
[2]	黄瑞, 王明亮, 赵佳萱, 卢一平. 非金属Si元素对AlNbTiMoHfSi难熔高熵合金组织及力学性能的影响[J]. 材料导报, 2026, 40(5): 25040014-6.
[3]	覃祖安, 任鹏炜, 唐兴颖, 朱日广, 陈积权. 冲刷速率与压力耦合作用对X70管线钢腐蚀行为的影响机制[J]. 材料导报, 2026, 40(4): 24070182-7.
[4]	李炎, 曹睿, 车洪艳, 翟亚中. 剪切刀具硬质合金YG8的冲击磨粒磨损行为[J]. 材料导报, 2026, 40(4): 25010200-6.
[5]	王珂, 廖强. 高强钢在极地典型环境下的应力腐蚀开裂敏感性研究[J]. 材料导报, 2026, 40(3): 25010189-8.
[6]	谢芋江, 漆俊杰, 蒋文宇, 文雄, 温飞娟, 黄本生. 机器学习辅助耐磨耐腐蚀高熵合金设计的现状与展望[J]. 材料导报, 2026, 40(3): 25030043-8.
[7]	钟海霞, 钟庆东, 杨健, 章书剑, 王雪妹, 范佳宝. AlCl₃-EMIC离子液体电沉积Al-Ti合金及耐蚀性研究[J]. 材料导报, 2026, 40(2): 24100244-7.
[8]	李伟华, 周文杰, 宋宝睿, 黄俊玮. 防腐耐磨高熵合金涂层研究进展[J]. 材料导报, 2026, 40(2): 24120127-11.
[9]	宋海鹏, 张冠, 范雪茹, 黄勇, 谢磊, 赵冬梅, 李强, 任铁真. 过渡族金属微量添加对Fe基块状金属玻璃的玻璃形成能力、力学性能和耐腐蚀性的影响[J]. 材料导报, 2026, 40(2): 24120223-7.
[10]	彭丹珉, 孙志鹏, 胡述伟, 周明扬, 高阳, 邱玺, 张坤, 李垣明. 锆合金均匀腐蚀模型研究进展[J]. 材料导报, 2026, 40(2): 24120206-7.
[11]	刘国建, 孙锦滢, 曲洪漩, 徐家乐, 蒋域蓉, 沈方敏. 基于反应分子动力学的混凝土模拟孔溶液中钢筋腐蚀行为研究[J]. 材料导报, 2026, 40(2): 24120115-7.
[12]	徐超亮, 全琪炜, 武焕春, 李远飞, 贾文清, 尹建, 李时磊, 宋淼, 张乐福, 刘向兵, 郭相龙. 轻水反应堆环境对不锈钢辐照促进应力腐蚀开裂的影响综述[J]. 材料导报, 2026, 40(1): 25010139-11.
[13]	秦传广, 姜博, 刘乃志, 王晔, 胡茂良, 许红雨, 吉泽升, 尚金翅. Al7Si0.5Mg合金喷丸处理微观组织形貌及腐蚀行为研究[J]. 材料导报, 2025, 39(9): 24030204-7.
[14]	赵帅, 文绍牧, 廖柯熹, 秦林, 林冬, 高健. 无损检测技术在高含硫天然气管道中的应用研究进展[J]. 材料导报, 2025, 39(9): 24030169-9.
[15]	陈永达, 胡智淇, 关岩, 常钧, 陈兵. 羟丙基甲基纤维素与硅烷偶联剂对磷酸镁基钢结构防火涂料性能的影响[J]. 材料导报, 2025, 39(8): 24010194-7.

[1]	WU Yanfei, TAO Kai, BAI Wenjing, CAO Dali, LI Xiaoying, LIANG Yunxiao. Preparation and Characterization of Monolithic Epoxy-based Macroporous Polymer[J]. Materials Reports, 2017, 31(8): 31 -34 .
[2]	ZHOU Qingquan, SHUAI Gewang, LIU Jianbin. Effect of Ni and Si Mass Ratio on Microstructure and Properties of Cu-Cr-Zr Alloy[J]. Materials Reports, 2017, 31(6): 76 -80 .
[3]	BI Yubao, WANG Huifang, ZHAO Wanguo, LIANG Feng, ZHANG Haijun. Surface Modification of Flake Graphite for Carbon-containing Castables: A Technological Review[J]. Materials Reports, 2017, 31(15): 108 -114 .
[4]	LIU Chenghong, WANG Jun’an, XIONG Banghui, ZHANG Zhiquan, CHEN Jichang, HE Ying. Cubic Textured Ni-Cr-Mo-W Alloy Tape and Its Properties[J]. Materials Reports, 2017, 31(20): 53 -57 .
[5]	YIN Xueliang, CHEN Min, WANG Nan, XU Lei, PENG Kewu. Effect of Y₂O₃ Addition on Sintering Behavior of MA-CA₂-CA₆ Composite[J]. Materials Reports, 2018, 32(8): 1357 -1361 .
[6]	XIAO Yi, XU Chengyi, Ryou Min, CAO Jian. Effect of Cr₃C₂ Grain Size on the Microstructure and Wear Performance of Fe-based Alloy Plasma Transferred Arc Surfacing[J]. Materials Reports, 2018, 32(24): 4329 -4333 .
[7]	ZHOU Chao, WANG Hui, OUYANG Liuzhang, ZHU Min. The State of the Art of Hydrogen Storage Materials for High-pressure Hybrid Hydrogen Vessel[J]. Materials Reports, 2019, 33(1): 117 -126 .
[8]	ZHOU Hongming, WANG Boyi, LI Jian, CHENG Minghui. Effect of CuO Doping on Electrical Properties of YBCO Ceramics[J]. Materials Reports, 2019, 33(2): 220 -224 .
[9]	LIU Fei, YIN Jian, SHAO Qi, LU Chunhui. Improved Solidification Structure of in-situ Mg2Si/]Mg-.Al Composites by Applying Pulsed Magnetic Field： a Comparative Study[J]. Materials Reports, 2019, 33(2): 293 -297 .
[10]	LIAO Mingyi, SONG Yating. The Interactions Between Anionically Synthesized POSS End-functionalized Polybutadiene and Filled Silica[J]. Materials Reports, 2019, 33(2): 352 -356 .

Viewed

Full text

Abstract

Cited

Shared

Discussed