高熵氧化物陶瓷制备与应用的研究进展

doi:10.11896/cldb.24100178

材料导报

2025, Vol. 39

Issue (24): 24100178-9 https://doi.org/10.11896/cldb.24100178

无机非金属及其复合材料

高熵氧化物陶瓷制备与应用的研究进展

郭洪飞, 张爱迪, 赵敏^*

内蒙古工业大学材料科学与工程学院,呼和浩特 010051

Progress in Preparation and Application of High-entropy Oxide Ceramics

GUO Hongfei, ZHANG Aidi, ZHAO Min^*

School of Materials Science and Engineering, Inner Mongolia University of Technology, Hohhot 010051, China

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摘要高熵陶瓷作为一种新型功能材料,因其高熵化带来的高模量、高硬度、低热导率等优异性能受到国内外的广泛关注。本文首先概述了高熵陶瓷的设计原则,接着根据晶体结构的差异,将高熵氧化物陶瓷分为岩盐型、钙钛矿型、萤石型和尖晶石型等类别,并讨论了它们各自的特性和应用。还详细讨论了高熵氧化物陶瓷的多种制备方法,包括固相反应法、溶胶-凝胶法、共沉淀法以及其他先进方法,如微波烧结技术和放电等离子烧结。此外,高熵氧化物陶瓷因其优异的热学性能、力学性能和催化活性,在锂离子电池材料、热障涂层材料、催化材料和介电材料等领域展现出广泛的应用潜力。最后展望了高熵氧化物陶瓷未来的研究方向,具体包括新体系的开发、设计理论的完善、磁场调控策略的优化以及理论计算的应用等。

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关键词: 高熵氧化物高熵陶瓷高熵效应制备方法

Abstract: As a new type of functional material, high-entropy ceramics have attracted widespread attention at home and abroad due to their excellent properties such as high modulus, high hardness, and low thermal conductivity brought about by high-entropy. This summary first outlined the design principles of high-entropy ceramics, and then divides high-entropy oxide ceramics into categories such as rock salt type, perovskite type, fluorite type, and spinel type based on the differences in crystal structure, and discussed their respective characteristics and applications. Various preparation methods of high-entropy oxide ceramics, including solid state reaction method, sol gel method, coprecipitation method and other advanced methods, such as microwave sintering technology and spark plasma sintering, were also discussed in detail. In addition, high-entropy oxide ceramics had shown extensive application potential in fields such as lithium-ion battery materials, thermal barrier coating materials, catalytic materials, and dielectric materials due to their excellent thermal properties, mechanical properties, and catalytic activity. Finally, the future research directions of high-entropy oxide ceramics were discussed, including the development of new systems, improvement of design theories, optimization of magnetic field control strategies, and application of theoretical calculations.

Key words: high-entropy oxide high-entropy ceramics high-entropy effect preparation method

出版日期: 2025-12-25 发布日期: 2025-12-17

ZTFLH:

TQ174.1

基金资助: 国家自然科学基金(52465061);内蒙古自治区科技创新重大示范工程“揭榜挂帅”项目(2024JBGS0035);内蒙古自治区自然科学基金重点项目(2024ZD26);教育部中国高校产学研创新基金重点项目(2021ITA05005);内蒙古自治区重点研发和成果转化计划项目(2023YFJM0007)

通讯作者: ^*赵敏,博士,讲师,目前主要研究领域为铬酸镧陶瓷连接、高熵陶瓷。951074865@qq.com

作者简介: 郭洪飞,教授,博士研究生导师,内蒙古工业大学副校长、内蒙古科学技术研究院常务副院长。目前主要从事智能制造、材料加工、军民融合研究工作。

引用本文:

郭洪飞, 张爱迪, 赵敏. 高熵氧化物陶瓷制备与应用的研究进展[J]. 材料导报, 2025, 39(24): 24100178-9.
GUO Hongfei, ZHANG Aidi, ZHAO Min. Progress in Preparation and Application of High-entropy Oxide Ceramics. Materials Reports, 2025, 39(24): 24100178-9.

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https://www.mater-rep.com/CN/10.11896/cldb.24100178 或 https://www.mater-rep.com/CN/Y2025/V39/I24/24100178

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