生物质基硬碳钠离子电池负极材料预处理研究进展

doi:10.11896/cldb. 24030195

材料导报

2025, Vol. 39

Issue (9): 24030195-12 https://doi.org/10.11896/cldb. 24030195

高分子与聚合物基复合材料

生物质基硬碳钠离子电池负极材料预处理研究进展

张文浩, 韩文佳, 陈安祥, 周世晋, 王晓龙, 陈仪玮, 李霞^*

齐鲁工业大学(山东省科学院)生物基材料与绿色造纸国家重点实验室,济南 250353

Research Progress on Pretreatment of Anode Materials for Biomass-based Hard Carbon Sodium-ion Batteries

ZHANG Wenhao, HAN Wenjia, CHEN Anxiang, ZHOU Shijin, WANG Xiaolong, CHEN Yiwei, LI Xia^*

State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China

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摘要生物质基硬碳因成本低廉、碳源丰富而广泛应用于钠离子电池负极材料的制备。但由于生物质前驱体组分和结构特性的局限,直接碳化制备的生物质基硬碳材料电性能难以满足需求。因此,通过在特定条件下对生物质前驱体进行预处理,调整和优化生物质前驱体的组分和结构,增强其电化学性能成为当下的研究热点。本文从预处理角度出发,首先总结了近年来生物质资源化利用预处理工艺、作用以及机理,然后综述了化学法、物理法与生物法等三种生物质基硬碳钠离子电池负极材料预处理方法的研究进展,以期为后续研究者在生物质基硬碳材料预处理工艺的选择、应用上提供参考。

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关键词: 生物质硬碳钠离子电池负极材料预处理

Abstract: Biomass-based hard carbon is a widely used material in the preparation of anode materials for sodium-ion batteries due to its low cost and abundance of carbon sources. However, the electrical properties of biomass-based hard carbon materials prepared by direct carbonization are difficult to meet the demand due to the limitations of biomass precursor components and structural properties. Consequently, there has been a surge in research activity aimed at optimising the components and structure of biomass precursors through the application of specific pretreatment techniques. This paper presents a comprehensive overview of the various pretreatment processes, their roles and mechanisms of biomass resource utilisation, and the latest research developments in the field of biomass-based hard carbon anode materials for sodium-ion batteries. The paper reviews the efficacy of three main categories of chemical, physical and biological pretreatment techniques, and provides a reference point for subsequent researchers engaged in the selection and application of pretreatment processes for biomass-based hard carbon materials.

Key words: biomas hard carbon sodium-ion battery anode material pretreatment

出版日期: 2025-05-10 发布日期: 2025-04-28

ZTFLH:	TM911
	TQ35

基金资助: 国家自然科学基金(22308179);国家重点研发计划(2020YFC1910301);山东省重点研发计划(重大科技创新工程)(2021CXGC011002);济南市“新高校20条”资助项目(20228103);齐鲁工业大学(山东省科学院)揭榜制项目(2022JBZ01-05);山东省自然科学基金(ZR2021QC158;ZR2023QB038);齐鲁工业大学人才科研项目(2023RCKY175;2023RCKY188);山东省科技型中小企业创新能力提升工程项目(2023TSGC0319)

通讯作者: ^*李霞,博士,齐鲁工业大学轻工学部讲师。目前主要从事生物质基硬碳负极材料、生物质资源高值化利用以及功能纸基材料等方面的研究。lixia@qlu.edu.cn

作者简介: 张文浩,齐鲁工业大学轻工学部硕士研究生,在李霞讲师的指导下进行研究。目前主要研究领域为生物质基硬碳负极材料的制备及电化学性质。

引用本文:

张文浩, 韩文佳, 陈安祥, 周世晋, 王晓龙, 陈仪玮, 李霞. 生物质基硬碳钠离子电池负极材料预处理研究进展[J]. 材料导报, 2025, 39(9): 24030195-12.
ZHANG Wenhao, HAN Wenjia, CHEN Anxiang, ZHOU Shijin, WANG Xiaolong, CHEN Yiwei, LI Xia. Research Progress on Pretreatment of Anode Materials for Biomass-based Hard Carbon Sodium-ion Batteries. Materials Reports, 2025, 39(9): 24030195-12.

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https://www.mater-rep.com/CN/10.11896/cldb. 24030195 或 https://www.mater-rep.com/CN/Y2025/V39/I9/24030195

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