Research Progress on the Application of Ionic Liquids in the Preparation of Nano Materials
LI Cuili1, SHEN Chunyu2, YANG Ying2, WANG Xinglong2, TANG Jianwei2,3,4, HUA Quanxian1,3, LIU Yong1,3,4, LIU Pengfei2,3,4, DING Junxiang2,3,4, SHEN Bo2,3,4, WANG Baoming2,3,4,*
1 College of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China 2 School of Ecology and Environment, Zhengzhou University, Zhengzhou 450001, China 3 National Calcium Magnesium Phosphate Compound Fertilizer Technology Research and Promotion Center, Zhengzhou 450001, China 4 Henan Provincial Collaborative Engineering Technology Research Center for Pollution Reduction and Carbon Reduction, Zhengzhou 450001, China
Abstract: As an innovative environmentally friendly green solvent, ionic liquids(IL)have been widely used as structure-directing agents, reaction solvents, reducing agents and solvents in the field of nanomaterial preparation due to their adjustable physical and chemical properties, wide solubility, biocompatibility and excellent ionic conductivity. In view of the outstanding performance of different kinds of ionic liquids in the field of preparation and modification of nanomaterials, the application of ionic liquids in the field of preparation of nanomaterials is described in detail. The application progress of ionic liquids in the preparation of nanomaterials such as metals, metal oxides, carbon nanotubes and nanocellulose is analyzed. At the same time, the functional characteristics of ionic liquids in regulating the stability, morphology and properties of nanomaterials are summarized. New suggestions are put forward for the application of ionic liquids in the preparation of nanomaterials in the future. It is pointed out that the precise regulation of ionic liquids to prepare specific functional nanomaterials is an important research direction in the future.
李翠利, 申纯宇, 杨英, 王兴龙, 汤建伟, 化全县, 刘咏, 刘鹏飞, 丁俊祥, 申博, 王保明. 离子液体在纳米材料制备中的应用进展[J]. 材料导报, 2025, 39(7): 24020066-9.
LI Cuili, SHEN Chunyu, YANG Ying, WANG Xinglong, TANG Jianwei, HUA Quanxian, LIU Yong, LIU Pengfei, DING Junxiang, SHEN Bo, WANG Baoming. Research Progress on the Application of Ionic Liquids in the Preparation of Nano Materials. Materials Reports, 2025, 39(7): 24020066-9.
1 Guo L, He N, Zhao Y, et al. Theranostics, 2020, 10(7), 3206. 2 Tang H W, Wang J L, Chang Z R, et al. Surface Technology, 2007(1), 56 (in Chinese). 汤宏伟, 王蒋亮, 常照荣, 等. 表面技术, 2007(1), 56. 3 Zhang H. Ionic liquid-based synthesis of ultrafine metal nanomaterials and study on its electrocatalytic performance. Master's Thesis, North University of China, China, 2020 (in Chinese). 张虹. 基于离子液体的超细金属纳米材料的制备及其电催化性能研究. 硕士学位论文, 中北大学, 2020. 4 Xia W, Zhu J, Guo W, et al. Journal of Materials Chemistry A, 2014, 2(30), 11606. 5 Wang Q W, Wang W J, Chen W J, et al. China Pulp & Paper, 2023(12), 52 (in Chinese). 王钦雯, 王雯君, 陈玟锦, 等. 中国造纸, 2023(12), 52. 6 Stankic S, Suman S, Haque F, et al. Journal of Nanobiotechnology, 2016, 14(1), 73. 7 Yu J, Yang X, Zhang Y D, et al. Modern Chemical Industry, 2024, 44(2), 76 (in Chinese). 于佳, 杨茜, 章亚东. 等. 现代化工, 2024, 44(2), 76. 8 Liew K M, Lei Z X, Zhang L W. Composite Structures, 2015, 120, 90. 9 Tie S N, Huanc W H, Sun Z B, et al. China Powder Science and Technology, 2024, 30(1), 1 (in Chinese). 铁生年, 黄伟豪, 孙增宝, 等. 中国粉体技术, 2024, 30(1), 1. 10 Noremylia M B, Hassan M Z, Ismail Z. International Journal of Biological Macromolecules, 2022, 206, 954. 11 Zhu Y A, Chen Q, Kong B H, et al. Journal of Chinese Institute of Food Science and Technology, 2024, 24(1), 466(in Chinese). 朱迎澳, 陈倩, 孔保华, 等. 中国食品学报, 2024, 24(1), 466. 12 Chen T T, Yin J T, Xu Y J, et al. CIESC Journal, 2021, 72(5), 2436 (in Chinese). 陈婷婷, 尹炯婷, 许映杰. 等. 化工学报, 2021, 72(5), 2436. 13 Huang Y L. Mining and Metallurgy, 1997(4), 62 (in Chinese). 黄艳玲. 矿冶, 1997(4), 62. 14 Wu Q, Miao W, Zhang Y, et al. Nanotechnology Reviews, 2020, 9(1), 259. 15 Wu W, Jiang C, Roy V A L. Nanoscale, 2015, 7(1), 38. 16 Zhu W, Chen Z, Pan Y, et al. Advanced Materials, 2019, 31(38), 1800426. 17 Gan X M, Xu G T, Zhang G Q, et al. Comprehensive Utilization of Resources in China, 2003(9), 39 (in Chinese). 甘晓明, 徐高田, 张国卿, 等. 中国资源综合利用, 2003(9), 39. 18 Zhang H, Luo Y, Cui P L, et al. Chemical Industry and Engineering Progress, 2020, 39(5), 9 (in Chinese). 张虹, 罗莹, 崔朋蕾, 等. 化工进展, 2020, 39(5), 9. 19 Li R X, Wang J J. Chemical Industry and Engineering Progress, 2002(1), 43 (in Chinese). 李汝雄, 王建基. 化工进展, 2002(1), 43. 20 Vijayaram S, Razafindralambo H, Sun Y Z, et al. Biological Trace Element Research, 2024, 202(1), 360. 21 Liu Y, Liu C H, Debnath T, et al. Nature Communications, Nature Publishing Group, 2023, 14(1), 1. 22 Xu J, Ma J, Peng Y, et al. Chinese Chemical Letters, 2023, 34(4), 107527. 23 Lyu F X, Liu X P, Chen X. Science Focus, 2019, 14(6), 10 (in Chinese). 吕凤先, 刘小平, 陈欣. 科学观察, 2019, 14(6), 10. 24 Zare I, Chevrier D M, Cifuentes-Rius A, et al. Materials Today, 2023, 66, 159. 25 Zeng Q F, Deng Y H, Zhang Y W, et al. Journal of Xiangtan University, 2020, 42(4), 8 (in Chinese). 曾庆丰, 邓永和, 张宇文, 等. 湘潭大学学报(自然科学版), 2020, 42(4), 8. 26 Wang D, Tejerina B, Lagzi I, et al. ACS Nano, 2011, 5(1), 530. 27 Blanchard L A, Brennecke J F. Industrial & Engineering Chemistry Research, 2001, 40(11), 2550. 28 Zhang H, Luo Y, Cui P L, et al. Chemical Industry and Engineering Progress, 2020, 39(5), 1803 (in Chinese). 张虹, 罗莹, 崔朋蕾, 等. 化工进展, 2020, 39(5), 1803. 29 Kim K S, Demberelnyamba D, Lee H. Langmuir, 2004, 20(3), 556. 30 Patil V, Mahajan S, Kulkarni M, et al. Chemosphere, 2020, 243, 125302. 31 Samari F, Dorostkar S. Journal of the Iranian Chemical Society, 2016, 13(4), 689. 32 Farjadian F, Akbarizadeh A R, Tayebi L. Heliyon, 2020, 6, 8. 33 Maneewattanapinyo P, Pichayakorn W, Monton C, et al. Pharmaceutics, 2023, 15(4), 1098. 34 Bernardi F, Scholten J D, Fecher G H, et al. Chemical Physics Letters, 2009, 479(1), 113. 35 Migowski P, Zanchet D, Machado G, et al. Physical Chemistry Chemical Physics, 2010, 12(25), 6826. 36 Vanecht E, Binnemans K, Patskovsky S, et al. Physical Chemistry Chemical Physics, 2012, 14(16), 5662. 37 Oncsik T, Desert A, Trefalt G, et al. Physical Chemistry Chemical Physics, 2016, 18(10), 7511. 38 Frolov A I, Kirchner K, Kirchner T, et al. Faraday Discussions, 2011, 154, 235. 39 Cheng P, Liu C, Yang Y, et al. Chemical Physics, 2015, 452, 1. 40 Gupta S K, Mao Y. Progress in Materials Science, 2021, 117, 100734. 41 Wang Y Q, Zhong Z X, Xing W H. CIESC Journal, 2021, 72(5), 2339 (in Chinese). 汪艳秋, 仲兆祥, 邢卫红. 化工学报, 2021, 72(5), 2339. 42 Zhao H L, You J H, Zhang Q G, et al. Chemistry Bulletin, 2009, 72(12), 1065 (in Chinese). 赵海丽, 尤景汉, 张庆国, 等. 化学通报, 2009, 72(12), 1065. 43 Azizi S, Shadjou N. Heliyon, 2021, 7(1), e05915. 44 Feng S, Yu H, Zhang X, et al. Sensors and Actuators B: Chemical, 2022, 359, 131529. 45 Shahvelayati A S, Sheshmani S, Siminghad M. Materials Chemistry and Physics, 2022, 278, 125442. 46 Sabbaghan M, Nadafan M. Optical Materials, 2023, 139, 113758. 47 Ding Y, Wang P, Wang Z, et al. Polymer Engineering & Science, 2011, 51(8), 1519. 48 Luo R M. Protein adsorption and glycosylated functionalization of muti-walled-carbon nanotubes. Master's Thesis, Beijing Polytechnic University, China, 2011 (in Chinese). 罗蓉梅. 多壁碳纳米管的糖基化修饰及蛋白质吸附研究. 硕士学位论文, 北京化工大学, 2011. 49 Yang L B. Preparation and separation research of organic/inorganic hybrid thin-film composite membrane. Master's Thesis, Beijing Polytechnic University, China, 2019 (in Chinese). 杨丽彬. 有机/无机杂化薄层复合膜的制备及分离性能研究. 硕士学位论文, 北京工业大学, 2019. 50 Zhao Z G, Liu X W, Wang X, et al. Optics & Precision Engineering, 2011, 19(1), 118 (in Chinese). 赵振刚, 刘晓为, 王鑫, 等. 光学精密工程, 2011, 19(1), 118. 51 Miyako E, Itoh T, Nara Y, et al. Chemistry-A European Journal, 2009, 15(31), 7520. 52 Fukushima T, Aida T. Chemistry-A European Journal, 2007, 13(18), 5048. 53 Song S C, Li H, Yang J T, et al. Journal of Functional Materials, 2018, 49(1), 1033 (in Chinese). 宋时传, 李海, 杨锦涛, 等. 功能材料, 2018, 49(1), 1033. 54 Xu Q, Zhang W. E-Polymers, 2021, 21(1), 166. 55 Liu Z, Yin S, Hu Q, et al. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2022, 634, 127894. 56 Therattil J, Anil K S, Pothan L A, et al. Functional Composites and Structures, 2020, 2(3), 035003. 57 Wang J, Chu H, Li Y, et al. ACS Nano, 2008, 2, 2540. 58 Ribeiro R S A, Pohlmann B C, Calado V, et al. Engineering in Life Sciences, 2019, 19(4), 279. 59 Charreau H, Cavallo E, Foresti M L. Carbohydrate Polymers, 2020, 237, 116039. 60 Ahankari S S, Subhedar A R, Bhadauria S S, et al. Carbohydrate Polymers, 2021, 255, 117479. 61 Chinmay Z, Balasubramanian K. European Polymer Journal, 2020, 133, 109758. 62 Moohan J, Stewart S A, Espinosa E, et al. Applied Sciences, 2020, 10(1), 65. 63 Karimian A, Parsian H, Majidinia M, et al. International Journal of Biolo-gical Macromolecules, 2019, 133, 850. 64 Bacakova L, Pajorova J, Bacakova M, et al. Nanomaterials, 2019, 9(2), 164. 65 Trache D, Tarchoun A F, Derradji M, et al. Frontiers in Chemistry, 2020, 8. 66 Khalil H P S A, Jummaat F, Yahya E B, et al. Polymers, 2020, 12(9), 2043. 67 Lengowski E C, Bonfatti J E A, Kumode M M N, et al. Sustainable polymer composites and nanocomposites, Springer International Publishing, Cham, 2019, pp. 1001. 68 Nemoto J, Saito T, Isogai A. ACS Applied Materials & Interfaces, 2015, 7(35), 19809. 69 Putro J N, Kurniawan A, Ismadji S, et al. Environmental Nanotechnology, Monitoring & Management, 2017, 8, 134. 70 Zhou Y, Khan T M, Liu J C, et al. Organic Electronics, 2014, 15(3), 661. 71 Mohammed N, Grishkewich N, Berry R M, et al. Cellulose, 2015, 22(6), 3725. 72 Lasrado D, Ahankari S, Kar K. Journal of Applied Polymer Science, 2020, 137(27), 48959. 73 Phanthong P, Reubroycharoen P, Hao X, et al. Carbon Resources Conversion, 2018, 1(1), 32. 74 Abitbol T, Rivkin A, Cao Y, et al. Current Opinion in Biotechnology, 2016, 39, 76. 75 Heise K, Kontturi E, Allahverdiyeva Y, et al. Advanced Materials (Deerfield Beach, Fla. ), 2021, 33(3), e2004349. 76 Babicka M, Woźniak M, Szentner K, et al. Materials, 2021, 14(12), 3264. 77 Haron G A S, Mahmood H, Noh H B, et al. Journal of Applied Polymer Science, 2024, 141(2), e54780. 78 Fuster M G, Moulefera I, Muñoz M N, et al. Polymers, 2023, 15(2), 382. 79 Tayyab Z, Safi S Z, Rahim A, et al. Journal of Biomaterials Science:Polymer Edition, 2019, 30(9), 785. 80 Chen B Q, Lin C X, Liu Y F, et al. CIESC Journal, 2020, 71(3), 903 (in Chinese). 陈蓓秋, 林春香, 刘以凡, 等. 化工学报, 2020, 71(3), 903.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2025, Vol. 39 
