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材料导报  2025, Vol. 39 Issue (2): 23100113-7    https://doi.org/10.11896/cldb.23100113
  高分子与聚合物基复合材料 |
N/O/P共掺杂三聚氰胺基多孔碳材料的制备及储锌性能研究
李朋娟, 邹振羽, 黄鹏飞, 金鑫, 吴晓雨, 李晓丽*
东北林业大学化学化工与资源利用学院,哈尔滨 150040
Preparation and Zinc Storage Properties of N/O/P Co-doped Melamine-based Porous Carbon Materials
LI Pengjuan, ZOU Zhenyu, HUANG Pengfei, JIN Xin, WU Xiaoyu, LI Xiaoli*
College of Chemistry, Chemical Engineering and Resource Utilization, Northeast Forestry University, Harbin 150040, China
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摘要 以三聚氰胺(Melamine)、六对醛基苯氧基环三磷腈(HAPCP)为原料,采用水热法制备富含氮、磷、氧元素的交联产物,通过炭化-活化法制备碳基材料,将其用作锌离子混合电容器的阴极材料。采用扫描电镜(SEM)、X射线衍射(XRD)、X射线光电子能谱(XPS)、拉曼光谱(Raman)、氮气吸-脱附实验(N2 adsorption-desorption)对碳基材料的形貌、结构以及化学成分进行表征分析。测试结果表明:碳基材料表面多孔粗糙,具有无定形碳结构,且含有氮、磷和氧原子。HAPCP与三聚氰胺物质的量比为1∶5且活化温度为800 ℃的碳基材料(HMAc-800)在0.5 A·g-1电流密度下的比电容高达390 F·g-1。以HMAc-800为阴极、锌片为阳极组装的锌离子混合电容器在能量密度139 Wh·kg-1时功率密度达456 W·kg-1,具有良好的储能能力。
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李朋娟
邹振羽
黄鹏飞
金鑫
吴晓雨
李晓丽
关键词:  三聚氰胺  碳基材料  电化学性能  锌离子混合电容器    
Abstract: In this work, via a hydrothermal process, melamine and hexa-p-aldehyde phenoxycyclotriphosphazene (HAPCP) were used as raw materials to prepare the cross-linking product rich in nitrogen, phosphorus, and oxygen, which was subsequently carbonized and activated to obtain the carbon-based electrode material for cathode of zinc-ion hybrid capacitors. The morphology, structure, and chemical composition of the carbon-based electrode material were characterized by means of scanning electron microscopy (SEM), X-ray diffractometry (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and nitrogen adsorption-desorption test. The experiment indicated that the prepared carbon-based material had a porous and rough surface morphology, amorphuous carbon structure, and contained nitrogen, phosphorus, and oxygen heteroatoms. The resultant product with a HAPCP/melamine molar ratio of 1∶5 and an activation temperature of 800 ℃ (HMAc-800) exhibited a specific capacitance of 390 F·g-1 at a current density of 0.5 A·g-1. The zinc-ion hybrid capacitor, assembled with HMAc-800 as the cathode material and a zinc sheet as the anode, delivered a power density of 456 W·kg-1 at an energy density of 139 Wh·kg-1, demonstrated a strong energy storage capacity.
Key words:  melamine    carbon-based material    electrochemical performance    zinc-ion hybrid capacitor
出版日期:  2025-01-25      发布日期:  2025-01-21
通讯作者:  *李晓丽,东北林业大学化学化工与资源利用学院副教授、硕士研究生导师。目前主要从事磷腈衍生物的制备及其在阻燃材料和电化学储能领域的应用研究。lixiaoli0903@163.com   
引用本文:    
李朋娟, 邹振羽, 黄鹏飞, 金鑫, 吴晓雨, 李晓丽. N/O/P共掺杂三聚氰胺基多孔碳材料的制备及储锌性能研究[J]. 材料导报, 2025, 39(2): 23100113-7.
LI Pengjuan, ZOU Zhenyu, HUANG Pengfei, JIN Xin, WU Xiaoyu, LI Xiaoli. Preparation and Zinc Storage Properties of N/O/P Co-doped Melamine-based Porous Carbon Materials. Materials Reports, 2025, 39(2): 23100113-7.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.23100113  或          https://www.mater-rep.com/CN/Y2025/V39/I2/23100113
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