阻燃改性环氧树脂的抗紫外老化研究

doi:10.11896/cldb.22080234

材料导报

2024, Vol. 38

Issue (1): 22080234-7 https://doi.org/10.11896/cldb.22080234

高分子与聚合物基复合材料

阻燃改性环氧树脂的抗紫外老化研究

赵明明¹, 王继辉¹, 倪爱清², 陈俊磊^1,*, 王昌增¹, 邬志超¹

1 武汉理工大学材料科学与工程学院,武汉 430070
2 武汉理工大学材料复合新技术国家重点实验室,武汉 430070

Study on Anti-ultraviolet Aging of Flame Retardant Modified Epoxy Resin

ZHAO Mingming¹, WANG Jihui¹, NI Aiqing², CHEN Junlei^1,*, WANG Changzeng¹, WU Zhichao¹

1 School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
2 State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 8127KB )
输出: BibTeX | EndNote (RIS)

摘要以阻燃改性环氧树脂为研究对象,添加不同配比的光稳定剂Tinuvin 770和抗氧剂Irganox 1010,研究紫外老化对材料性能的影响。对紫外老化前后材料的化学结构、表面形貌、力学性能、阻燃性能和热性能等进行测试分析,研究表明紫外线会破坏阻燃剂的结构,使得环氧树脂发生降解和氧化。两种助剂的加入使紫外老化后试样的力学性能保留率和阻燃性能得到提升,其中,只添加抗氧剂Irganox 1010的试样在老化28 d后性能表现最优异,拉伸、弯曲强度保留率从未添加助剂试样的80.37%、81.61%分别提升到100.10%、92.50%,极限氧指数(Limiting oxygen index,LOI)由34.4%提升到37.5%,老化后的试样也表现出更好的热稳定性。结果表明,添加抗氧剂Irganox 1010对提升阻燃改性环氧树脂的抗紫外老化效果最佳。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	赵明明
	王继辉
	倪爱清
	陈俊磊
	王昌增
	邬志超

关键词: 紫外老化环氧树脂本征型磷系阻燃剂光稳定剂抗氧剂

Abstract: The effect of UV aging on the properties of flame retardant modified epoxy resin (E51) after adding different ratios of light stabilizer Tinuvin 770 and antioxidant Irganox 1010 was studied. Chemical structure, surface morphology, mechanical properties, flame retardant properties and thermal properties were tested, it is found that UV irradiation destroys the structure of flame retardants, and degrades and oxidizes epoxy re-sins. Different ratios of anti-aging agents improve the retention rates of mechanical properties and flame retardant properties. Antioxidant-only samples showed the best performance after 28 d of aging. The retention rates of tensile and flexural strengths increased to 100.10% and 92.50%, compared with 80.37% and 81.61% of the samples without anti-aging agent. The limiting oxygen index (LOI) increased from 34.4% to 37.5% and the antioxidants made the thermal stability of the samples better. The results show that the addition of antioxidant Irganox 1010 is the best for improving the anti-ultraviolet aging properties of flame retardant modified epoxy resin.

Key words: ultraviolet aging epoxy resin intrinsic phosphorus flame retardant light stabilizer antioxidant

发布日期: 2024-01-16

ZTFLH:

TQ314

通讯作者: 陈俊磊,武汉理工大学材料科学与工程学院实验师。2012年河南科技大学材料成型及控制工程专业本科毕业,2015年大连理工大学材料加工工程专业硕士毕业,2020年武汉理工大学材料科学与工程专业博士毕业。目前主要从事复合材料成型制备、复合材料阻燃性能及复合材料回收再利用等方面的研究工作。已在国外学术刊物上发表SCI论文9篇,包括Composites Part B:Enginee-ring、Composite Structures等。junleichen@whut.edu.cn

作者简介: 赵明明,2019年6月于武汉理工大学获得理学学士学位。现为武汉理工大学材料科学与工程学院硕士研究生,在王继辉教授的指导下进行研究。目前主要研究领域为树脂基复合材料。

引用本文:

赵明明, 王继辉, 倪爱清, 陈俊磊, 王昌增, 邬志超. 阻燃改性环氧树脂的抗紫外老化研究[J]. 材料导报, 2024, 38(1): 22080234-7.
ZHAO Mingming, WANG Jihui, NI Aiqing, CHEN Junlei, WANG Changzeng, WU Zhichao. Study on Anti-ultraviolet Aging of Flame Retardant Modified Epoxy Resin. Materials Reports, 2024, 38(1): 22080234-7.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.22080234 或 https://www.mater-rep.com/CN/Y2024/V38/I1/22080234

1 Kocijan A, Conradi M, Hočevar M. Materials, 2019, 12(11), 1877.
2 Zheng Z C, Ma W S. Polymer Materials Science & Engineering, 2018, 34(3), 111 (in Chinese).
郑梓聪, 马文石. 高分子材料科学与工程, 2018, 34(3), 111.
3 Jiao C, Dong J, Chen X, et al. Journal of Thermal Analysis and Calorimetry, 2013, 114(3), 1201.
4 Chen R F, Zhang Y X. Synthetic Materials Aging and Application, 2022, 51(3), 113 (in Chinese).
陈瑞芳, 张琰鑫. 合成材料老化与应用, 2022, 51(3), 113.
5 Kużdżał E, Cichy B, Kicko-Walczak E, et al. Journal of Applied Polymer Science, 2017, 134(2), 44371.
6 Guo Y N. Preparation and properties of cyclotriphosphazene-based halogen-free flame resistance optical resins. Ph. D. Thesis, Huazhong University of Science and Technology, China, 2011 (in Chinese).
郭雅妮. 基于环三磷腈的无卤阻燃光学树脂的制备与性能. 博士学位论文, 华中科技大学, 2011.
7 Zhou Y, Zhang D H, Qin S H. Materials Reports, 2019, 33(5), 901 (in Chinese).
周颖, 张道海, 秦舒浩. 材料导报, 2019, 33(5), 901.
8 Xiao L, Sun D, Niu T, et al. High Performance Polymers, 2014, 26(1), 52.
9 Gao L P, Wang D Y, Wang Y Z, et al. Polymer Degradation and Stabi-lity, 2008, 93(7), 1308.
10 Woo R S C, Zhu H, Leung C K Y, et al. Composites Science and Technology, 2008, 68(9), 2149.
11 Wang G J, Sun Y N, Jiang W L, et al. Materials Science and Technology, 2017, 25(3), 46 (in Chinese).
王国建, 孙耀宁, 蒋万乐, 等. 材料科学与工艺, 2017, 25(3), 46.
12 Fernández-Álvarez M, Velasco F, Bautista A. Journal of Materials Research and Technology, 2021, 10, 1042.
13 Nicholas J, Mohamed M, Dhaliwal G S, et al. Composites Part B:Engineering, 2016, 94, 370.
14 George G A, Sacher R E, Sprouse J F. Journal of Applied Polymer Science, 1977, 21(8), 2241.
15 Dong F P. Study on ultraviolet resistance of modified epoxy resin with nano ZnO. Master’s Thesis, Chongqing University, China, 2007 (in Chinese).
董福平. 纳米ZnO改性LED封装用环氧树脂的抗紫外老化研究. 硕士学位论文, 重庆大学, 2007.
16 Liu F, Zhang Z B, Xu L L, et al. In:Advanced Materials Research. Shenyang, 2012, pp. 812.
17 Imbuluzqueta G, Yurrita N, Aizpurua J, et al. Solar Energy Materials and Solar Cells, 2019, 200, 109947.
18 Beraldo C H M, Silveira M R S, Baldissera A F, et al. Progress in Organic Coatings, 2020, 149, 105903.
19 Wang P. Preparation, properties and flame-retardant mechanism of flame-retardant epoxy resins based on DOPO-based nitrogenous compounds. Ph. D. Thesis, Donghua University, China, 2016 (in Chinese).
王鹏. 基于DOPO含氮化合物阻燃环氧树脂的制备、性能与阻燃机理研究. 博士学位论文, 东华大学, 2016.
20 Tian X J, Wang Z W, Yu Q, et al. Polymer Materials Science & Engineering, 2014, 30(8), 31 (in Chinese).
田秀娟, 王忠卫, 于青, 等. 高分子材料科学与工程, 2014, 30(8), 31.
21 Lee S H, Oh S W, Lee Y H, et al. Journal of Engineered Fibers and Fabrics, 2020, 15, 1558925020901323.
22 Zhao J. Study on key analytical technology of bisphenol A epoxy resin system. Ph. D. Thesis, Qingdao University of Science and Technology, China, 2016 (in Chinese).
赵娟. 双酚A环氧树脂体系主要性能表征技术研究. 博士学位论文, 青岛科技大学, 2016.
23 Fu C Y. Research on properties evolution and fatigue properties of resin matrix composites after UV aging. Master’s Thesis, Wuhan University of Technology, 2020 (in Chinese).
付晨阳. 树脂基复合材料紫外老化后性能演变及疲劳性能研究. 硕士学位论文, 武汉理工大学, 2020.
24 Salmeia K A, Gaan S. Polymer Degradation and Stability, 2015, 113, 119.
25 Beraldo C H M, Silveira M R S, Baldissera A F, et al. Progress in Organic Coatings, 2020, 149, 105903.
26 Shen M Y, Chen W J, Kuan C F, et al. Materials Chemistry and Phy-sics, 2016, 173, 205.
27 Huo S, Wang J, Yang S, et al. Polymer Degradation and Stability, 2017, 146, 250.

[1]	吕炎, 白二雷, 王志航, 夏伟. 低温养护对环氧树脂基砂浆早期性能的影响及机理[J]. 材料导报, 2024, 38(5): 23080222-6.
[2]	杨菊香, 贾园, 马文建, 李朋娜, 屈颖娟. 互穿网络结构的二氧化硅/环氧树脂复合材料的制备及介电性能研究[J]. 材料导报, 2024, 38(5): 22080082-6.
[3]	何丽红, 马悦帆, 杨克, 徐心硕, 李青林. 水性有机硅改性环氧树脂的制备与性能[J]. 材料导报, 2024, 38(3): 22050109-5.
[4]	周铭钰, 刘曙光, 吴超凡, 刘军, 张恒龙, 张帅, 李启石. 基于水性环氧乳化沥青的超薄磨耗层级配设计及性能对比研究[J]. 材料导报, 2024, 38(24): 23110085-8.
[5]	刘圣洁, 曹旭, 张钰林, 傅永腾, 焦晓东. 水性环氧树脂复合改性乳化沥青固化行为及性能研究[J]. 材料导报, 2024, 38(24): 23090085-7.
[6]	颜蜀雋, 谭雅莉, 庞忠荣, 万鹏颖, 齐福刚. 六方氮化硼负载纳米氧化铝复合填料的制备及改性环氧涂层的防腐性能研究[J]. 材料导报, 2024, 38(20): 22110089-6.
[7]	吴妹, 徐晓磊, 李晓, 刘玖红, 于光睿, 段好东, 韩玉玺, 于青, 王忠卫. 甲基取代二芳基氧化膦阻燃改性环氧树脂的研究[J]. 材料导报, 2024, 38(16): 23040213-10.
[8]	李嘉, 肖鹏, 范思源, 周壹伍. 基于表面能理论的粘结剂-UHPC粘结失效模式分析[J]. 材料导报, 2024, 38(14): 23030069-7.
[9]	朱昊, 李勇, 还大军. 短切CF/PEEK复合材料的制备及抗紫外老化性能[J]. 材料导报, 2024, 38(14): 23020237-6.
[10]	于天夫, 李祥, 杨薛明, 胡宗杰, 季畅. 利用聚多巴胺硅烷双重改性氮化硼提高环氧树脂复合材料热物性[J]. 材料导报, 2024, 38(11): 22070092-6.
[11]	安绍都, 邵伟光, 樊桂琪, 李万利, 王建超, 杨建雄, 蔡利海. 热塑性聚氨酯耐油抗紫外老化性能改进研究[J]. 材料导报, 2024, 38(10): 23020156-5.
[12]	朱刚建, 李文晓. 核壳颗粒增韧改性环氧树脂基体研究评述[J]. 材料导报, 2024, 38(10): 22120066-9.
[13]	孔令云, 席晗. 道路沥青紫外老化及抗老化材料研究综述[J]. 材料导报, 2024, 38(1): 22060166-13.
[14]	鲁玉鑫, 卢林刚. 聚磷酸铵-单宁酸-三聚氰胺/环氧树脂复合材料的阻燃及力学性能[J]. 材料导报, 2023, 37(9): 21090236-8.
[15]	张进, 谭璐, 邢宝岩, 李作鹏, 赵建国, 屈文山, 张璐. 环氧导电胶的反应动力学及其应用[J]. 材料导报, 2023, 37(8): 22020025-6.

[1]	Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO₂/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[2]	Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[3]	Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[4]	Lijing YANG,Zhengxian LI,Chunliang HUANG,Pei WANG,Jianhua YAO. Producing Hard Material Coatings by Laser-assisted Cold Spray:a Technological Review[J]. Materials Reports, 2018, 32(3): 412 -417 .
[5]	Zhiqiang QIAN,Zhijian WU,Shidong WANG,Huifang ZHANG,Haining LIU,Xiushen YE,Quan LI. Research Progress in Preparation of Superhydrophobic Coatings on Magnesium Alloys and Its Application[J]. Materials Reports, 2018, 32(1): 102 -109 .
[6]	Wen XI,Zheng CHEN,Shi HU. Research Progress of Deformation Induced Localized Solid-state Amorphization in Nanocrystalline Materials[J]. Materials Reports, 2018, 32(1): 116 -121 .
[7]	Xing LIANG, Guohua GAO, Guangming WU. Research Development of Vanadium Oxide Serving as Cathode Materials for Lithium Ion Batteries[J]. Materials Reports, 2018, 32(1): 12 -33 .
[8]	Hao ZHANG,Yongde HUANG,Yue GUO,Qingsong LU. Technological and Process Advances in Robotic Friction Stir Welding[J]. Materials Reports, 2018, 32(1): 128 -134 .
[9]	Laima LUO, Mengyao XU, Xiang ZAN, Xiaoyong ZHU, Ping LI, Jigui CHENG, Yucheng WU. Progress in Irradiation Damage of Tungsten and Tungsten AlloysUnder Different Irradiation Particles[J]. Materials Reports, 2018, 32(1): 41 -46 .
[10]	Fengsen MA,Yan YU,Jie ZHANG,Haibo CHEN. A State-of-the-art Review of Cytotoxicity Evaluation of Biomaterials[J]. Materials Reports, 2018, 32(1): 76 -85 .

Viewed

Full text

Abstract

Cited

Shared

Discussed