身管内壁铬钽及其合金涂层研究进展

doi:10.11896/cldb.24010200

材料导报

2025, Vol. 39

Issue (7): 24010200-8 https://doi.org/10.11896/cldb.24010200

金属与金属基复合材料

身管内壁铬钽及其合金涂层研究进展

高峰, 郭策安, 张健^*

沈阳理工大学装备工程学院, 沈阳 110159

Research Progress of Cr, Ta and Cr-Ta Alloy Coating on the Inner Wall of Gun Barrel

GAO Feng, GUO Ce'an, ZHANG Jian^*

School of Equipment Engineering, Shenyang Ligong University, Shenyang 110159, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 7950KB )
输出: BibTeX | EndNote (RIS)

摘要新一代火炮对射程、初速和穿透能力要求的提高,增加了火炮身管内壁的磨损和烧蚀。为了适应未来火炮的发展需求,需要开发能够承受恶劣内弹道环境的火炮身管材料。本文回顾了身管材料的发展历程,分析了影响身管寿命的热因素、化学因素、机械因素,归纳出了身管涂层的延寿措施。在材料选用方面,身管涂层材料除了已经在使用的铬以外,难熔金属钽和铬钽合金被认为是主要的候选材料。还归纳总结了Cr、Ta及其合金涂层的制备技术,包括电镀、多弧离子镀、激光淬火、激光熔覆、磁控溅射、熔盐电化学沉积、电火花沉积、爆炸包覆焊、双层辉光等离子技术等。本文为延长身管寿命、探索新型炮钢身管涂层材料及其制备技术提供了参考和借鉴。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	高峰
	郭策安
	张健

关键词: Cr-Ta合金涂层身管寿命耐磨性耐烧蚀性

Abstract: The new requirements for range, initial velocity and penetration ability of the new generation of artillery increase the risk of wear and ablation of the inner wall of the gun barrel. In order to meet the development needs of future artillery, it is necessary to develop gun barrel materials that can withstand harsh internal ballistic environments. This paper summarized the development of barrel materials, analyzed the thermal factors, chemical factors and mechanical factors that affect the life of barrel, and put forward the main measures to prolong the life of barrel coating. In addition to the chromium that is commonly used, refractory metal tantalum and chromium tantalum alloys are considered to be the main alternative materials. This paper also summarized the coating preparation techniques of Cr, Ta and their alloys such as electroplating, multi-arc ion plating, laser quenching, laser cladding, magnetron sputtering, molten salt electrochemical deposition, electric spark deposition, explosive cladding welding, double glow plasma technology, etc. It will provide references for prolonging the life of the barrel, exploring new gun steel barrel coating materials and their preparation techniques.

Key words: Cr-Ta alloy coating barrel life wear resistance ablation resistance

出版日期: 2025-04-10 发布日期: 2025-04-10

ZTFLH:

TG144

基金资助: 国家装备预研基金(61406190105);辽宁省应用基础研究计划(2022JH2/101300006);沈阳理工大学“光选”团队项目(2021004)

通讯作者: *张健,博士,沈阳理工大学教授、博士研究生导师。主要从事武器系统新材料新工艺的技术研发,重点研究材料的腐蚀与防护技术。zhangjian6165@aliyun.com

作者简介: 高峰,沈阳理工大学装备工程学院博士研究生。目前主要从事武器系统新材料新工艺的技术研发,重点研究材料的腐蚀与防护技术。

引用本文:

高峰, 郭策安, 张健. 身管内壁铬钽及其合金涂层研究进展[J]. 材料导报, 2025, 39(7): 24010200-8.
GAO Feng, GUO Ce'an, ZHANG Jian. Research Progress of Cr, Ta and Cr-Ta Alloy Coating on the Inner Wall of Gun Barrel. Materials Reports, 2025, 39(7): 24010200-8.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24010200 或 https://www.mater-rep.com/CN/Y2025/V39/I7/24010200

1 Zhang S S. Journal of Xi'an Technological University, 1989, 9(1), 1 (in Chinese).
张树松. 西安工业大学学报, 1989, 9(1), 1.
2 Huang J F, Zhang J, Chen J Y, et al. Journal of Gun Launch & Control, 2023, 44(1), 10 (in Chinese).
黄进峰, 张津, 陈俊宇, 等. 火炮发射与控制学报, 2023, 44(1), 10.
3 Wang J, Xu Y F, Liu P K, et al. Acta Armamentarii, 2023, 44(4), 1034 (in Chinese).
王军, 许耀峰, 刘朋科, 等. 兵工学报, 2023, 44(4), 1034.
4 Zhang N, Lyu C R, Xu L. China Metallurgy, 2019, 29(5), 6 (in Chinese).
张楠, 吕超然, 徐乐. 中国冶金, 2019, 29(5), 6.
5 Yuan X D, Gao L Q, Zhang H F. Development and Application of Materials, 2017, 32(5), 98 (in Chinese).
袁晓冬, 高灵清, 张海峰. 材料开发与应用, 2017, 32(5), 98.
6 Yu W, Tian Q T, Yu X D, et al. Journal of Sichuan Ordnance, 2010, 31(2), 97 (in Chinese).
于伟, 田庆涛, 于旭东, 等. 四川兵工学报, 2010, 31(2), 97.
7 Xu Y F, Shan C L, Liu P K, et al. Journal of Gun Launch & Control, 2020, 41(3), 89 (in Chinese).
许耀峰, 单春来, 刘朋科, 等. 火炮发射与控制学报, 2020, 41(3), 89.
8 Yang G L. Equipment Environmental Engineering, 2022, 19(7), 10 (in Chinese).
杨国来. 装备环境工程, 2022, 19(7), 10.
9 Sopok S, Rickard C, Dunn S. Wear, 2005, 258(1-4), 671.
10 Cote P J, Todaro M E, Kendall G, et al. Surface and Coatings Technology, 2003, 163(163), 478.
11 Underwood J H, Witherell M D, Sopok S, et al. Wear, 2004, 257(9-10), 992.
12 Fu J W, Li Y Z, Chen S Y, et al. Equipment Environmental Engineering, 2022, 19(7), 10 (in Chinese).
付佳维, 李延泽, 陈诗雨, 等. 装备环境工程, 2022, 19(7), 10.
13 Turley D M, Gumming G, Gunner A, et al. Wear, 1994, 176(1), 9.
14 Lazovik I N, Ashurkov A A. Russian Aeronautics, 2007, 50(2), 210.
15 Song Y M, Wen G Z, Zhang J. Equipment Environmental Engineering, 2022, 19(7), 1 (in Chinese).
宋彦明, 温钢柱, 张杰. 装备环境工程, 2022, 19(7), 1.
16 Xu Y F, Shan C L, Liu P K, et al. Journal of Gun Launch & Control, 2019, 40(4), 90 (in Chinese).
许耀峰, 单春来, 刘朋科, 等. 火炮发射与控制学报, 2019, 40(4), 90.
17 Poláš ek M, Krbat'a M, Eckert M, et al. Procedia Structural Integrity, 2023, 43, 306.
18 Mao B Q, Zhao Q J, Bai X H, et al. Acta Armamentarii, 2023, 44(3), 638 (in Chinese).
毛保全, 赵其进, 白向华, 等. 兵工学报, 2023, 44(3), 638.
19 Garrett W, Sherman A J, Stiglich J. Materials and Manufacturing Processes, 2006, 21(6), 618.
20 Gao W, Zhang J, Huang J F, et al. Materials Reports, 2017, 31(13), 90 (in Chinese).
高文, 张津, 黄进峰, 等. 材料导报, 2017, 31(13), 90.
21 Zhang G X, Zhang K, Chen G N, et al. Corrosion Science and Protection Technology, 2006(6), 418 (in Chinese).
张国祥, 张坤, 陈光南, 等. 腐蚀科学与防护技术, 2006(6), 418.
22 Turley D. Wear, 1989, 131(1), 135.
23 Yin K M, Wang C M. Surface & Coatings Technology, 1999, 114(2-3), 213.
24 Cote P J, Todaro M E, Kendall G, et al. Surface and Coatings Technology, 2003, 163, 478.
25 Cote P J, Kendall G, Todaro M E. Surface and Coatings Technology, 2001, 146, 65.
26 Horst R, Gert S, Hartmut W. E. U. patent, EP1003008, 2000.
27 Zhang K, Chen G N, Peng Y C. Physical Testing and Chemical Analysis(Part A:Physical Testing, 2006(4), 171(in Chinese).
张坤, 陈光南, 彭玉春. 理化检验(物理分册), 2006(4), 171.
28 Zhang G X, Chen G N, Zhang K, et al. China Surface Engineering, 2006(6), 25 (in Chinese).
张国祥, 陈光南, 张坤, 等. 中国表面工程, 2006(6), 25.
29 Zhang G X, Chen G N, Li H X, et al. Materials Engineering, 2007(9), 18 (in Chinese).
张国祥, 陈光南, 李怀学, 等. 材料工程, 2007(9), 18.
30 Zhang G X, Chen G N, Zhang K, et al. Heat Treatment of Metal, 2007(3), 52 (in Chinese).
张国祥, 陈光南, 张坤, 等. 金属热处理, 2007(3), 52.
31 Zhang G X, Chen G N, Zhang K, et al. Acta Armamentarii, 2006(6), 978 (in Chinese).
张国祥, 陈光南, 张坤, 等. 兵工学报, 2006(6), 978.
32 Li H X, Chen G N, Zhang G X, et al. Transactions of Materials and Heat Treatment, 2006(2), 94 (in Chinese).
李怀学, 陈光南, 张国祥, 等. 材料热处理学报, 2006(2), 94.
33 Li H X, Chen G N, Gong S L. Chinese Journal of Lasers, 2011, 38(3), 114 (in Chinese).
李怀学, 陈光南, 巩水利. 中国激光, 2011, 38(3), 114.
34 Li H X, Chen G N, Zhang K, et al. Transactions of Materials and Heat Treatment, 2007(4), 111 (in Chinese).
李怀学, 陈光南, 张坤, 等. 材料热处理学报, 2007(4), 111.
35 Li H X, Chen G N, Zhang K, et al. Surface and Coatings Technology, 2007, 201(24), 9558.
36 Cote P J, Rickard C. Wear, 2000, 241(1), 17.
37 Wu J, Shen M, Hu M, et al. Corrosion Science, 2021, 187, 109476.
38 Hu M, Shen M, Liu Z, et al. Corrosion Science, 2018, 143, 212.
39 Hu M. Study on Cr coating properties of gun barrel materials prepared by different methods. Ph. D. Thesis, North University of China, China, 2019 (in Chinese).
胡明. 不同制备方法的火炮身管材料Cr涂层性能研究. 博士学位论文, 中北大学, 2019.
40 Turley D M. Wear, 1989, 131(1), 135.
41 Barile C, Casavola C, Pappalettera G, et al. Coatings, 2022, 12(10), 1536.
42 Zhang J, Wei D J, Guo C A. Corrosion Science and Protection Technology, 2008(2), 110 (in Chinese).
张健, 魏德君, 郭策安. 腐蚀科学与防护技术, 2008(2), 110.
43 Guo C A, Zhang J, Shang G M, et al. Journal of Shenyang Ligong University, 2013, 32(2), 76 (in Chinese).
郭策安, 张健, 尚光明, 等. 沈阳理工大学学报, 2013, 32(2), 76.
44 Xu P. Study on laser cladding pure chromium powder on gun steel surface. Master's Thesis, Changchun University of Science and Technology, China, 2006 (in Chinese).
许鹏. 炮钢表面激光熔覆纯铬粉末的研究. 硕士学位论文, 长春理工大学, 2006.
45 De Rosset W S, Audino M J. Materials and Manufacturing Processes, 2006, 21(6), 571.
46 Hirvonen J K, Demaree J D, Marble D K, et al. Surface and Coatings Technology, 2005, 196(1-3), 167.
47 Niu Y, Chen M, Wang J, et al. Surface and Coatings Technology, 2017, 321, 19.
48 Guo C A, Zhou F, Hu M, et al. Materials Reports, 2018, 32(18), 3213 (in Chinese).
郭策安, 周峰, 胡明, 等. 材料导报, 2018, 32(18), 3213.
49 Matson D W, Mcclanahan E D, Rice J P, et al. Surface and Coatings Technology, 2000, 133, 411.
50 Matson D W, McClanahan E D, Lee S L, et al. Surface and Coatings Technology, 2001, 146, 344.
51 Lee S L, Windover D, Audino M, et al. Surface and Coatings Technology, 2002, 149(1), 62.
52 Warrender J M, Mulligan C P, Underwood J H. Wear, 2007, 263(7-12), 1540.
53 Lee S L, Cipollo M, Windover D, et al. Surface and Coatings Technology, 1999, 120, 44.
54 Wang S, Xiong D S, Li J L, et al. China Surface Engineering, 2015, 28(2), 101 (in Chinese).
王升, 熊党生, 李建亮, 等. 中国表面工程, 2015, 28(2), 101.
55 Suh Y, Chen W, Maeng S, et al. Thin Solid Films, 2010, 518(19), 5452.
56 Wan Y, Xiong D S, Li J L. Journal of Shanghai Jiaotong University, 2018, 52(7), 853 (in Chinese).
万轶, 熊党生, 李建亮. 上海交通大学学报, 2018, 52(7), 853.
57 Warnecke C. U. S. patent application, US6352740, 2002.
58 Wang Y C. Performance of electrospark deposited MCrAlY coating on gun steel. Master's Thesis, Shenyang Ligong University, China, 2016 (in Chinese).
王远超. 炮钢表面电火花沉积MCrAlY性能的研究. 硕士学位论文, 沈阳理工大学, 2016.
59 Underwood J H, Vigilante G N, Mulligan C P. Wear, 2007, 263(7), 1616.
60 Venkatraman M, Neumann J P. Journal of Phase Equilibria, 1987, 8(2), 112.
61 Ahmad I, Spiak W A, Janz G J. Journal of Applied Electrochemistry, 1981, 11, 291.
62 Li C Y, Guo C A, Liu Q, et al. Journal of Shenyang Ligong University. 2022, 41(2), 31 (in Chinese).
李彩燕, 郭策安, 柳泉, 等. 沈阳理工大学学报, 2022, 41(2), 31.
63 Kim J H, Akiyama E, Habazaki H, et al. Corrosion Science, 1994, 36(3), 511.
64 Kim J H, Akiyama E, Habazaki H, et al. Corrosion Science, 1993, 34(12), 1947.
65 Chang L C, Chen Y I, Kao H L. Thin Solid Films, 2012, 520(23), 6929.

[1]	张泽疆, 李新梅, 朱春金, 李航, 杨定力. 纳米TiB₂对CoCrFeNiSi高熵合金涂层耐磨与耐蚀性能的影响[J]. 材料导报, 2025, 39(3): 23090210-9.
[2]	万福程, 梁继超, 于爱华, 张嘉振, 路新. 钛涂层制备与后处理工艺及应用研究进展[J]. 材料导报, 2025, 39(2): 24010131-9.
[3]	申爱琴, 陈荣伟, 郭寅川, 范建航, 戴晓倩, 丑涛. 季冻区纳米SiO₂改性SAP路面混凝土的耐磨性[J]. 材料导报, 2024, 38(7): 23010093-6.
[4]	张雷, 龙伟民, 樊志斌, 都东, 刘大双, 孙志鹏, 李宇佳, 尚勇. CuTi对Ti-6Al-4V钛合金表面金刚石/AlSi复合钎涂层组织与耐磨性能的影响[J]. 材料导报, 2024, 38(21): 23080114-4.
[5]	高吉昌, 门秀花, 姜帅, 付秀丽, 蒋振峰, 李艳. 高铬铸铁叶片堆焊工艺研究进展[J]. 材料导报, 2024, 38(17): 23050109-9.
[6]	王婷, 胡斌, 王文琴, 王非凡. 微弧火花沉积Zr基非晶涂层的组织及性能[J]. 材料导报, 2024, 38(16): 22090308-6.
[7]	朱志彬, 蒋丽, 李艳辉, 张伟. 高熵复合材料微观结构、力学性能及耐磨性研究进展[J]. 材料导报, 2024, 38(14): 23050131-12.
[8]	俞伟元, 董鹏飞, 吴保磊. 超音速火焰喷涂氧燃比对铁基非晶涂层性能的影响[J]. 材料导报, 2024, 38(12): 22120200-6.
[9]	胡海波, 朱丽慧, 涂有旺, 段元满, 吴晓春, 顾炳福. 深冷处理工艺对M2高速钢显微组织与性能的影响[J]. 材料导报, 2023, 37(9): 21110028-6.
[10]	张曦挚, 崔红, 胡杨, 邓红兵. 利用等离子喷涂制备C/C复合材料表面耐烧蚀抗氧化涂层的研究进展[J]. 材料导报, 2023, 37(6): 21050162-7.
[11]	王鼎, 周艳文, 张开策, 粟志伟, 杜峰, 武俊生, 郭诚. 离子氮化中氮在典型钢中的扩散行为研究[J]. 材料导报, 2022, 36(Z1): 22010109-6.
[12]	周维, 樊坤阳, 黄淙, 刘子京, 万维财, 贡太敏. 烧结温度对团聚高温快速烧结WC-10Co-4Cr粉末及其HVOF涂层性能的影响[J]. 材料导报, 2022, 36(6): 20120041-6.
[13]	吕绪明, 江涛, 张云汉, 苑建志, 杨凯, 党博, 张平则. 纯铜表面Ta-W合金层的抗高温氧化及摩擦行为[J]. 材料导报, 2022, 36(23): 22050017-5.
[14]	杨海屹, 张莎莎, 姚正军, 刘子利. 电子束重熔对铁基粉末冶金表面耐磨性能的影响[J]. 材料导报, 2022, 36(17): 20100136-5.
[15]	种振曾, 孙耀宁, 程旺军, 韩晨阳, 苏才津, 娜菲沙·迪力夏提, 樊子龙. 纳米WC对AlCoCrFeNi高熵合金涂层耐磨与耐蚀性能的影响[J]. 材料导报, 2022, 36(14): 22030230-6.

[1]	Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO₂/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[2]	Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[3]	Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[4]	Lijing YANG,Zhengxian LI,Chunliang HUANG,Pei WANG,Jianhua YAO. Producing Hard Material Coatings by Laser-assisted Cold Spray:a Technological Review[J]. Materials Reports, 2018, 32(3): 412 -417 .
[5]	Zhiqiang QIAN,Zhijian WU,Shidong WANG,Huifang ZHANG,Haining LIU,Xiushen YE,Quan LI. Research Progress in Preparation of Superhydrophobic Coatings on Magnesium Alloys and Its Application[J]. Materials Reports, 2018, 32(1): 102 -109 .
[6]	Wen XI,Zheng CHEN,Shi HU. Research Progress of Deformation Induced Localized Solid-state Amorphization in Nanocrystalline Materials[J]. Materials Reports, 2018, 32(1): 116 -121 .
[7]	Xing LIANG, Guohua GAO, Guangming WU. Research Development of Vanadium Oxide Serving as Cathode Materials for Lithium Ion Batteries[J]. Materials Reports, 2018, 32(1): 12 -33 .
[8]	Hao ZHANG,Yongde HUANG,Yue GUO,Qingsong LU. Technological and Process Advances in Robotic Friction Stir Welding[J]. Materials Reports, 2018, 32(1): 128 -134 .
[9]	Laima LUO, Mengyao XU, Xiang ZAN, Xiaoyong ZHU, Ping LI, Jigui CHENG, Yucheng WU. Progress in Irradiation Damage of Tungsten and Tungsten AlloysUnder Different Irradiation Particles[J]. Materials Reports, 2018, 32(1): 41 -46 .
[10]	Fengsen MA,Yan YU,Jie ZHANG,Haibo CHEN. A State-of-the-art Review of Cytotoxicity Evaluation of Biomaterials[J]. Materials Reports, 2018, 32(1): 76 -85 .

Viewed

Full text

Abstract

Cited

Shared

Discussed