钙钛矿基叠层太阳电池的最新进展及发展趋势

doi:10.11896/cldb.24080136

材料导报

2025, Vol. 39

Issue (20): 24080136-11 https://doi.org/10.11896/cldb.24080136

无机非金属及其复合材料

钙钛矿基叠层太阳电池的最新进展及发展趋势

王芹芹^1,*, 黄玮¹, 顾斯雯², 丁建宁¹

1 扬州大学碳中和技术研究院,江苏扬州 225101
2 常州大学材料科学与工程学院,江苏常州 213164

Recent Progress and Development Trend of Perovskite-based Tandem Solar Cells

WANG Qinqin^1,*, HUANG Wei¹, GU Siwen², DING Jianning¹

1 Institute of Technology for Carbon Neutralization, Yangzhou University, Yangzhou 225101, Jiangsu, China
2 School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, China

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摘要单结太阳电池的功率转换效率受到Shockley-Quiesser极限的限制,实现高效率的有效途径是开发叠层太阳电池。近些年,随着有机/无机钙钛矿太阳电池迅速发展,钙钛矿材料优异的光电性能和可调的带隙使其成为与硅、铜铟镓硒(CIGS)和有机太阳电池结合开发叠层太阳电池的潜在候选者。本文介绍了叠层太阳电池串联结构的种类;分析并探讨了与钙钛矿叠层的主流太阳电池在两端与四端结构上涉及的材料选择、界面缺陷调控、工作性能、转化效率等内容及其优劣势;最后,讨论了叠层太阳电池在器件结构、效率、大面积制造、稳定性、成本等五个方面面临的挑战,并从这五个角度展望了未来的发展趋势。

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	王芹芹
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关键词: 叠层太阳电池钙钛矿硅 CIGS 有机太阳电池

Abstract: The power conversion efficiency of single-junction solar cells is limited by the Shockley-Quiesser limit. An effective way to realize high efficiency is to develop tandem solar cells. With the rapid development of organic/inorganic perovskite solar cells in recent years, the excellent photovoltaic properties and tunable bandgap of perovskite materials make them potential candidates for the development of tandem solar perovskite cells in combination with silicon, CIGS and organic solar cells. This paper introduces the types of tandem structures of tandem solar cells;analyzes and discusses the mainstream solar cells with perovskite stacks in terms of two and four terminal structures regarding material selection, regulation of interfacial defects, operating performance, conversion efficiency, and their advantages and disadvantages. At the end, it addresses the five obstacles that tandem solar cells will encounter: device structure, efficiency, large-area fabrication, stability, and cost. It also anticipates the direction of future development from these five angles.

Key words: tandem solar cell perovskite silicon CIGS organic solar cell

发布日期: 2025-10-27

ZTFLH:

TM914

基金资助: 国家自然科学基金(62304199)

通讯作者: *王芹芹,博士,扬州大学碳中和技术研究院副教授、硕士研究生导师。目前主要围绕高效晶硅电池产业化技术和工程应用及晶硅/钙钛矿叠层电池前沿技术开展研究。wangqinqin@yzu.edu.cn

引用本文:

王芹芹, 黄玮, 顾斯雯, 丁建宁. 钙钛矿基叠层太阳电池的最新进展及发展趋势[J]. 材料导报, 2025, 39(20): 24080136-11.
WANG Qinqin, HUANG Wei, GU Siwen, DING Jianning. Recent Progress and Development Trend of Perovskite-based Tandem Solar Cells. Materials Reports, 2025, 39(20): 24080136-11.

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https://www.mater-rep.com/CN/10.11896/cldb.24080136 或 https://www.mater-rep.com/CN/Y2025/V39/I20/24080136

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