团簇-晶核共组装亚纳米材料的研究进展

doi:10.11896/cldb.24100015

材料导报

2025, Vol. 39

Issue (12): 24100015-10 https://doi.org/10.11896/cldb.24100015

无机非金属及其复合材料

团簇-晶核共组装亚纳米材料的研究进展

叶庆华^1,2, 赵亚丽², 蔡铭心^2,3, 翟锦秀², 曹行健², 刘熙俊⁴, 何佩雷^2,3,*

1 宁波大学材料科学与化学工程学院,浙江宁波 315211
2 中国科学院宁波材料技术与工程研究所,全省先进燃料电池与电解池技术重点实验室,浙江宁波 315201
3 中国科学院大学材料科学与光电技术学院,北京 100049
4 广西大学资源环境与材料学院,广西有色金属及特色材料加工重点实验室,南宁 530004

Research Progress on Sub-1 nm Materials Based on Cluster-Nuclei Co-assembly

YE Qinghua^1,2, ZHAO Yali², CAI Mingxin^2,3, ZHAI Jinxiu², CAO Xingjian², LIU Xijun⁴, HE Peilei^2,3,*

1 School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, China
2 Zhejiang Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang, China
3 College of Materials Sciences and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China
4 Guangxi Key Laboratory of Processing for Non-ferrous Metals and Featured Materials, School of Resources, Environment and Materials, Guangxi University, Nanning 530004, China

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摘要亚纳米材料是指特征尺寸至少在一个维度上小于1 nm的材料。与传统纳米材料相比,亚纳米材料往往有特殊的性能,因而具有广阔的应用前景。清华大学的王训教授课题组实现了在良/不良溶剂体系中制备亚纳米材料,并提出了团簇-晶核共组装策略来实现亚纳米尺度上材料组分的调控。目前,该策略已发展成为制备各种组分亚纳米材料的普适方法。亚纳米材料因超高的比表面积和接近100%的表面原子暴露率而具有快速的电子/离子传输特性,在储能、催化和光热转化等领域中获得了广泛的应用。本文介绍了团簇-晶核共组装策略的概念和亚纳米材料的形成机理,同时,综述了近年来利用团簇-晶核共组装策略制备的亚纳米材料的研究现状,就其合成方法、结构等进行系统的介绍,讨论了这些亚纳米材料在储能、催化、光热转化、有机凝胶等方面的应用,最后提出了亚纳米材料目前面临的挑战和未来的研究方向,旨在为亚纳米材料的设计和精确合成提供新的视角。

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	叶庆华
	赵亚丽
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	翟锦秀
	曹行健
	刘熙俊
	何佩雷

关键词: 亚纳米团簇-晶核共组装策略储能类高分子性质光热转化

Abstract: Sub-1 nm materials are defined as materials with characteristic dimensions smaller than 1 nm in at least one dimension. Compared to conventional nanomaterials, sub-1 nm materials often exhibit unique properties, leading to a wide range of potential applications. Professor Wang Xun’s research group at Tsinghua University has successfully developed methods for synthesizing sub-1 nm materials in good- and poor-solvent system and proposed a cluster-nuclei co-assembly strategy to achieve compositional control at the sub-1 nm scale. This strategy has evolved into a universal method for the synthesis of various sub-1 nm materials. Due to their exceptionally high specific surface area and nearly 100% surface atom exposure, sub-1 nm materials exhibit rapid electron/ion transport characteristics, making them widely applicable in energy storage, catalysis, and photothermal conversion. This review introduces the concept of the cluster-nuclei co-assembly strategy and elucidates the formation mechanisms of sub-1 nm materials. Additionally, it reviews the current research status of sub-1 nm materials synthesized through this strategy, systematically discussing their synthesis methods and structures, as well as their applications in energy storage, catalysis, and photothermal conversion. Finally, the challenges facing sub-1 nm materials today and future research directions are presented, aiming to provide new perspectives for the design and precise synthesis of sub-1 nm materials.

Key words: sub-1 nm cluster-nuclei co-assembly strategy energy storage macromolecule-like features photothermal conversion

出版日期: 2025-06-25 发布日期: 2025-06-19

ZTFLH:

O61

基金资助: 国家自然科学基金(22101289);中国科学院百人计划项目

通讯作者: ^*何佩雷,博士,中国科学院宁波材料技术与工程研究所研究员、博士研究生导师。目前主要从事亚纳米材料自组装等方面的研究。hepeilei@nimte.ac.cn

作者简介: 叶庆华,宁波大学材料科学与化学工程学院硕士研究生,在何佩雷研究员的指导下进行研究。目前主要研究领域为团簇-晶核共组装亚纳米材料的设计与应用。

引用本文:

叶庆华, 赵亚丽, 蔡铭心, 翟锦秀, 曹行健, 刘熙俊, 何佩雷. 团簇-晶核共组装亚纳米材料的研究进展[J]. 材料导报, 2025, 39(12): 24100015-10.
YE Qinghua, ZHAO Yali, CAI Mingxin, ZHAI Jinxiu, CAO Xingjian, LIU Xijun, HE Peilei. Research Progress on Sub-1 nm Materials Based on Cluster-Nuclei Co-assembly. Materials Reports, 2025, 39(12): 24100015-10.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24100015 或 https://www.mater-rep.com/CN/Y2025/V39/I12/24100015

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