Polypyrrole is one of conductive polymers with the best conductive stability. Because of its simple preparation, environmental friendliness, high conductivity, high conductivity and unique doping, the preparation of polypyrrole composites in order to improve the stability is becoming a hot spot in the research field of conductive polymer-based supercapacitors electrode materials. Polypyrrole electrode materials and binary, ternary composite electrode materials with the carbon materials or metal oxide materials used in the research development of supercapacitors in recent years are reviewed. The charge storage mechanism, polypyrrole polymerization mechanism and preparation methods are introduced. Meanwhile, this paper prospected the current hot research fields and development prospect of the polypyrrole and its composite electrode materials.
Zhang Hongli, Chen Lijia . Analysis of the development of China’s new energy industry and core technologies[J]. Energy Research and Information, 2013,4(29):187(in Chinese).
Fu Min, Sun Yong, Wang Shuyang . Power system technologies for biomass energy automobiles[J]. Energy Research and Information, 2012,1(28):7(in Chinese).
Yu A, Chen Z . Electrochemical supercapacitors for energy storage and delivery: Advanced materials, technologies and applications[J]. Applied Energy, 2015,153:1.
4
Armand M , TarasconJ M. Building better batteries[J]. Nature, 2008,451:652.
5
Inagaki M, Konno H, Tanaike O . Carbon materials for electroche-mical capacitors[J]. Power Sources, 2010,195(24):7780.
6
Zhao Xue, Qiu Pingda, Jiang Haijing , et al. Latest research progress of electrode materials for supercapacitor[J]. Electronic Components and Materials, 2010,1(34):1(in Chinese).
Li Xin, Wei Bingqing . Supercapacitors based on nanostructured carbon[J]. Nano Energy, 2013,2:159.
8
HuangY, Li H, Wang Z , et al. Nanostructured polypyrrole as a flexible electrode material of supercapacitor[J]. Nano Energy, 2016,22:422.
9
Xiao Xingzhong, Yi Qingfeng . Synjournal and electrochemical capacity of MnO2/SMWCNT/PANI ternary composites[J]. Journal of Inorganic Materials, 2013,8(28):825(in Chinese).
Wang G P, Zhang L, Zhang J J . A review of electrode materials for electrochemical supercapacitors[J]. Chemical Society Reviews, 2012,41(2):797.
11
Yang Peihua, Mai Wenjie . Flexible solid-state electrochemical supercapacitors[J]. Nano Energy, 2014,8:274.
12
Nithya V D, Sabari Arul N . Review on a-Fe2O3 based negative electrode for high performance supercapacitors[J]. Journal of Power Sources, 2016,327:297.
13
Shinde S S, Gund G S, Dubal D P , et al. Morphological modulation of polypyrrole thin films through oxidizing agents and their concurrent effect on supercapacitor performance[J]. Electrochimica Acta, 2014,119:1.
14
Li X, Zhitomirsky I . Electrodeposition of polypyrroleecarbon nanotube composites for electrochemical supercapacitors[J]. Journal of Power Sources, 2013,221:49.
15
Wang Jiangan, Yang Ying, Huang Zhenghong , et al. MnO2/polypyrrole nanotubular composites: Reactive template synjournal, characterization and application as superior electrode materials for high-performance supercapacitors[J]. Electrochimica Acta, 2014,130:642.
16
Feng Huixia, Wang Bin, Tan Lin , et al. Progress in the research on conductive polymer-based electrode materials for supercapacitors[J]. Chemical Industry and Engineering Progress, 2014,3(33):689(in Chinese).
Rajkumar M, Hsu C T, Wu T H , et al. Advanced materials for aqueous supercapacitors in the asymmetric design[J]. Progress in Natural Science:Materials International, 2015,25:527.
18
Zhu Lei, Wu Borong, Chen Hui , et al. State of art for study and application of supercapacitor[J]. Chinese Journal of Rare Meterials, 2003,3(27):385(in Chinese).
Arbizzani C, Mastragostino M, Meneghello L . Polymer-based redox supercapacitors: A comparative study[J]. Electrochimica Acta, 1996,41:21.
20
Mastragostino M, Arbizzani C, Paraventi R , et al. Polymer selection and cell design for electric-vehicle supercapacitors[J]. Journal of the Electrochemical Society, 2000,147(2):407.
21
Clemente A, Panero S, Spila E , et al. Solid-state, polymer-based, redox capacitors[J]. Solid State Ionics, 1996,85:273.
22
Hashmi S A, Upadhyaya H M. Polypyrrole and poly(3-emthylthiophene)-based solid state redox supercapacitors usuing ion conduting polymer electrolyte[J].Solid State Ionics, 2002, 152-153:883.
23
Hyuck Lee, Hyeongkeun Kim, Mi Suk Cho , et al. Fabrication of polypyrrole(PPy)/carbon nanotube(CNT) composite electrode on ceramic fabric for supercapacitor applications[J]. Electrochimica Acta, 2011,56:7460.
24
Zhang Z M, Wan M X, Wei Y . Highly crystalline polyaniline nano-structures doped with dicarboxylic acids[J]. Advanced Functional Materials, 2006,16:1100.
25
Gardini G P . The oxidation of monocyclic pyrroles[J]. Advances in Heterocyclic Chemistry, 1973,15:67.
26
Attia M F, Azib T, Salmi Z , et al. One-step uv-induced modification of cellulose fabrics by polypyrrole/silver nanocomposite films[J]. Journal of Colloid and Interface Science, 2013,393:130.
27
Levi M D, Aurbaeh D . A short review on the strategy towards development of Pi-eonjugated polymers with highly reversible P-and n-doping[J]. Journal of Power Sources, 2008,180(2):902.
28
Zhou H X, Yang L Q, Liu S B . A tale of current and volage interplay of band gap and energy levels of conjugated polymersin bulk heterojunetion solar cells[J]. Macromolecules, 2010,43(24):10390.
29
Ramya R, Sivasubramanian R , Sangaranarayanan M V et al. Conducting polymers-based electrochemical supercapacitors—Progress and prospects[J]. Electrochimica Acta, 2013,101:109.
30
Li Yanxi, Song Hui , Zhang Chengxiang et al. Research progress of polypyrrole and its composite materials[J]. Chemical Propellants & Polymeric Materials, 2016,3(14):19(in Chinese).
Patil B H, Bulakhe R N, Lokhande C D . Supercapacitive perfor-mance of chemically synthesized polypyrrole thin films: Effect of monomer to oxidant ratio[J]. Mater Electron, 2014,25:2188.
32
Hu Xiaoping, Liu Zhihu, You Dan , et al. Progress in preparation, modification and applications of polypyrrole[J]. New Chemical Mate-rials, 2012,7(40):110(in Chinese).
Zhai Jing . Study on Synthesis and capacitance performance of polypyrrole and its composites[D]. Chengdu:Southwest Jiaotong University, 2015(in Chinese).
33
翟晶 . 聚吡咯及其复合材料的制备与电容性能研究[D]. 成都:西南交通大学, 2015.
34
Zhao Junhong, Wu Jinping, Li Bing , et al. Facile synjournal of polypyrrole nanowires for high-performance supercapacitor electrode materials[J]. Progress in Natural Science: Materials International, 2016,26(3):237.
35
Dubal D P, Patil S V, Kim W B , et al. Supercapacitors based on electrochemically deposited polypyrrole nanobricks[J]. Materials Letters, 2011,65:2628.
36
Du Hongxiu . Preparation, structure and electrochemical perfor-mance of polypyrrole nano-arrays[D]. Nanjing:Southeast University, 2015(in Chinese).
36
杜洪秀 . 聚吡咯纳米阵列材料的制备、结构与电化学性能研究[D]. 南京:东南大学, 2015.
37
Wang Xiuyun, Nie Haoyu, Kan Lili , et al. Process of conductive polypyrrole film by in situ polymerization[J]. New Chemical Mate-rials, 2014,11(42):184(in Chinese).
Chen Yong, Kang Guiying, Xu Hui , et al. Two composites based on CoMoO4 nanorods and PPy nanoparticles:Fabrication, structure and electrochemical properties[J]. Synthetic Metals, 2016,215:50.
39
Chen S, Zhitomirsky I . Polypyrrole coated carbon nanotubes for supercapacitors, prepared using indigo carmine as a dispersant and dopant[J]. Materials Letters, 2014,135:47.
40
Qian Tao . Preparation and application of novel polypyrrole/carbon nanocomposites[J]. Nanjing: Nanjing University, 2014(in Chinese).
40
钱涛 . 新型聚吡咯/碳纳米管复合材料的制备[D]. 南京:南京大学, 2014.
41
Xu Jie, Wang Daxiang, Yuan Ye , et al. Polypyrrole/reduced graphene oxide coated fabric electrodes for supercapacitor application[J]. Organic Electronics, 2015,24:153.
42
Li Y J, Ni X Y, Shen J , et al. Preparation and performance of polypyrrole/nitric acid activated carbon aerogel nanocomposite materials for supercapacitors[J]. Acta Physco-Chimica Sinica, 2016,32(2):493.
43
Sharma R K, Rastogi A C, Desu S B , et al. Manganese oxide embedded polypyrrole nanocomposites for electrochemical supercapacitor[J]. Electrochimica Acta, 2006,53(26):7690.
44
Xiong W, Pan X, Li Y , et al. Hierarchical Co3O4@PPy core/shell nanowire arrays on nickel foam for electrochemical energy storage[J]. Materials Letters 2015,157:23.
45
Wu Xinming, Wang Qiguan, Zhang Wenzhi , et al. Nanorod structure of polypyrrole-covered MoO3 for supercapacitors with excellent cycling stability[J]. Materials Letters, 2016,182:121.
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2018, Vol. 32 
