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《材料导报》期刊社  2017, Vol. 31 Issue (7): 114-120    https://doi.org/10.11896/j.issn.1005-023X.2017.07.018
  新材料新技术 |
燃煤烟气中单质汞的催化氧化技术研
王红妍1,2, 王宝冬1, 李俊华2, 孙琦1
1 北京低碳清洁能源研究所,北京 102209;
2 清华大学环境学院,北京 100084
Progress in Catalytic Oxidation Technology for Element Mercury in Coal-fired Flue Gas
WANG Hongyan1,2, WANG Baodong1, LI Junhua2, SUN Qi1
1 National Institute of Clean-and-Low-Carbon Energy, Beijing 102209;
2 School of Environment, Tsinghua University, Beijing 100084
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摘要 针对燃煤电厂烟气中汞的脱除问题,综述了单质汞氧化催化剂与催化氧化机理的研究现状;着重阐述了碳基、金属及金属氧化物催化剂和选择性催化还原(SCR)催化剂对单质汞的催化氧化性能,分析了活性组分、烟气条件等对各催化剂氧化单质汞性能的影响;指出异相反应是单质汞氧化的重要途径,不同催化剂、不同烟气气氛下氧化机理不同;最后结合我国燃煤电厂的现状,提出深入研究单质汞的催化氧化机理,进一步提高SCR催化剂的催化氧化单质汞活性、抗硫性及稳定性将是燃煤烟气汞污染控制技术的重点发展方向。
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王红妍
王宝冬
李俊华
孙琦
关键词:  燃煤烟气    催化  氧化  机理  催化剂    
Abstract: Aiming at the problem of Hg0 removal from the flue gas of coal-fired power plant, the catalysts of mercury oxidation and catalytic mechanisms are summarized in this work. The catalytic oxidation performance of carbon-based materials, metals and metal oxides and selective catalytic reduction (SCR) catalysts are reviewed. The influence of active component, flue gas condition on mercury oxidation performance of catalysts is briefly discussed. Heterogeneous reaction is an important way of promoting the oxidation of elemental mercury. The oxidation mechanisms varied with catalysts or atmosphere. Finally, taking into consideration the situation of coal-fired power plants in China, future research directions including developing effective and stable SCR catalysts with a low SO2/SO3 conversion rate are proposed. The mechanism of Hg0 oxidation need to be better understood as well.
Key words:  coal-fired flue gas    mercury    catalysis    oxidation    mechanisms    catalyst
出版日期:  2017-04-10      发布日期:  2018-05-08
ZTFLH:  X511  
基金资助: 青年千人启动经费(GB9300120001)
通讯作者:  王宝冬,男,1978年生,教授级高级工程师,主要从事电厂污染物控制方面的研究 E-mail:wangbaodong@nicenergy.com   
作者简介:  王红妍:女,1986年生,博士,主要从事大气污染控制研究
引用本文:    
王红妍, 王宝冬, 李俊华, 孙琦. 燃煤烟气中单质汞的催化氧化技术研[J]. 《材料导报》期刊社, 2017, 31(7): 114-120.
WANG Hongyan, WANG Baodong, LI Junhua, SUN Qi. Progress in Catalytic Oxidation Technology for Element Mercury in Coal-fired Flue Gas. Materials Reports, 2017, 31(7): 114-120.
链接本文:  
https://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.07.018  或          https://www.mater-rep.com/CN/Y2017/V31/I7/114
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