羽毛角蛋白/PVA复合纳米纤维膜的制备及表征

doi:10.11896/j.issn.1005-023X.2018.02.008

《材料导报》期刊社

2018, Vol. 32

Issue (2): 198-202 https://doi.org/10.11896/j.issn.1005-023X.2018.02.008

物理材料研究｜材料

羽毛角蛋白/PVA复合纳米纤维膜的制备及表征

何明¹,窦瑶¹,陈曼²,尹国强²,崔英德^1,³,陈循军²

1 西北工业大学材料学院,西安 710072
2 仲恺农业工程学院化学化工学院,广州 510225
3 广州科技职业技术学院,广州 510550

Preparation and Characterization of Feather Keratin/PVA Composite Nanofibrous Membranes by Electrospinning

Ming HE¹,Yao DOU¹,Man CHEN²,Guoqiang YIN²,Yingde CUI^1,³,Xunjun CHEN²

1 School of Materials Science and Engineering, Northwestern Polytechnical University,Xi’an 710072;
2 College of Chemistry and Chemical Engineering,Zhongkai University of Agriculture and Engineering, Guangzhou 510225
3 Guangzhou Vocational College of Science and Technology,Guangzhou 510550

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摘要

以羽毛角蛋白(FK)和聚乙烯醇(PVA)为原料,水为溶剂,通过静电纺丝技术制备了FK/PVA复合纳米纤维膜。探讨了复合纳米纤维中FK与PVA的相容性,研究了FK的添加对纤维膜微观形貌、结晶度、热稳定性、亲水性等性能的影响。SEM结果表明,在聚合物总质量分数为14%的条件下制备的FK/PVA复合纳米纤维,表面平整光滑,平均直径为250~320 nm,FK含量越大,直径越小。FTIR结果表明,FK与PVA具有良好的相容性,分子间存在氢键作用力。XRD结果表明,FK的加入破坏了PVA分子的规整排列,复合纳米纤维膜的结晶度下降。TG分析与接触角测试结果表明,随着体系中FK配比的增大,复合纳米纤维膜的热稳定性和亲水性均得到提高。

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	何明
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关键词: 羽毛角蛋白聚乙烯醇静电纺丝纳米纤维

Abstract:

Feather keratin (FK)/PVA composite nanofibrous membranes were prepared through an electrospinning process, using water as solvent. The interaction and compatibility between FK and PVA, as well as the effect of incorporating FK on the morphology, crystallinity, thermal stability and hydrophilicity of the composite nanofibrous membranes were evaluated. At a total polymer concentration of 14%, the prepared nanofibers were smooth, bead-free and the average diameter was in the range of 250—320 nm. The more FK was added, the lower fiber diameter was obtained. The favorable compatibility and strong interactions between FK and PVA were confirmed by FTIR analysis. XRD analysis indicated that the arrangement of PVA chain in the composite nanofibrous membranes was disturbed by the incorporation of FK, resulting the decrease of crystallinity. According to TG and contact angle analysis, the thermal stability and hydrophilicity of the composite nanofibers were both enhanced by increasing the FK content.

Key words: feather keratin poly(vinyl alcohol) electrospinning nanofibers

出版日期: 2018-01-25 发布日期: 2018-01-25

ZTFLH:

TQ342.94

基金资助: 广东省科技计划项目(2013B010403029);广东省自然科学基金(2016A030313371)

引用本文:

何明,窦瑶,陈曼,尹国强,崔英德,陈循军. 羽毛角蛋白/PVA复合纳米纤维膜的制备及表征[J]. 《材料导报》期刊社, 2018, 32(2): 198-202.
Ming HE,Yao DOU,Man CHEN,Guoqiang YIN,Yingde CUI,Xunjun CHEN. Preparation and Characterization of Feather Keratin/PVA Composite Nanofibrous Membranes by Electrospinning. Materials Reports, 2018, 32(2): 198-202.

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https://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.02.008 或 https://www.mater-rep.com/CN/Y2018/V32/I2/198

表1 FK/PVA纳米纤维膜的平均直径

图1 FK/PVA纳米纤维膜的扫描电镜图

表2 FK/PVA复合纳米纤维膜与FK粉末的红外特征峰分析

图2 FK/PVA复合纳米纤维膜与FK粉末的红外光谱

图3 FK/PVA复合纳米纤维膜与FK粉末的XRD谱

表3 FK/PVA复合纳米纤维膜与FK粉末的TG分析

图4 FK/PVA复合纳米纤维膜与FK粉末的TG曲线

图5 FK/PVA复合纳米纤维膜的接触角

1	Agarwal S, Greiner A, Wendorff J H . Electrospinning of manmade and biopolymer nanofibers-progress in techniques,materials,and applications[J]. Advanced Functional Materials, 2010,19(19):2863.
2	Agarwal S, Wendorff J H, Greiner A . Progress in the field of electrospinning for tissue engineering applications[J]. Advanced Materials, 2009,21(32-33):3343.
3	Yen K C, Chen C Y, Huang J Y , et al. Fabrication of keratin/fibroin membranes by electrospinning for vascular tissue engineering[J]. Journal of Materials Chemistry B, 2016,4(2):237.
4	Liu Y, Yu X, Li J , et al. Fabrication and properties of high-content keratin/poly (ethylene oxide) blend nanofibers using two-step cross-linking process[J]. Journal of Nanomaterials, 2015,2015(10):1.
5	Varesano A, Vineis C, Tonetti C , et al. Chemical and physical modifications of electrospun keratin nanofibers induced by heating treatments[J]. Journal of Applied Polymer Science, 2014,131(15):40532.
6	Zoccola M, Aluigi A, Vineis C , et al. Study on cast membranes and electrospun nanofibers made from keratin/fibroin blends[J]. Biomacromolecules, 2008,9(10):2819.
7	Fan J, Lei T D, Li J , et al. High protein content keratin/poly (ethy-lene oxide) nanofibers crosslinked in oxygen atmosphere and its cell culture[J]. Materials and Design, 2016,104:60.
8	Cho D, Nnadi O, Netravali A , et al. Electrospun hybrid soy protein/PVA fibers[J]. Macromolecular Materials and Engineering, 2010,295(8):763.
9	Zhang M, Liu Y J, Yi H L , et al. Electrospun zein/PVA fibrous mats as three-dimensional surface for embryonic stem cell culture[J]. Journal of the Textile Institute, 2014,105(3):246.
10	Li S, Yang X H . Fabrication and characterization of electrospun wool keratin/poly(vinyl alcohol) blend nanofibers[J]. Advances in Materials Science and Engineering, 2014,2014(3):1.
11	Choi J, Panthi G, Liu Y , et al. Keratin/poly (vinyl alcohol) blended nanofibers with high optical transmittance[J]. Polymer, 2015,58(1):146.
12	Song N B, Lee J H, Mijan M A , et al. Development of a chicken feather protein film containing clove oil and its application in smoked salmon packaging[J]. LWT-Food Science and Technology, 2014,57(2):453.
13	Xu X Z, Jiang L, Zhou Z P , et al. Preparation and properties of electrospun soy protein isolate/polyethylene oxide nanofiber membranes[J]. ACS Applied Materials and Interfaces, 2012,4(8):4331.
14	Edwards A, Jarvis D, Hopkins T , et al. Poly(caprolactone)/keratin-based composite nanofibers for biomedical applications[J]. Journal of Biomedical Materials Research Part B-Applied Biomaterials, 2015,103(1):21.
15	Wang H Y, Yin G Q, Feng G Z , et al. Preparation,structure and properties of blend films of feather keratin and sodium carboxy methyl cellulose[J]. Materials Review B:Research Papers, 2014,28(8):67(in Chinese).
16	王海洋, 尹国强, 冯光炷 , 等. 羽毛角蛋白/CMC复合膜的制备及结构和性能[J]. 材料导报:研究篇, 2014,28(8):67.
17	Islam M S, Karim M R . Fabrication and characterization of poly(vinyl alcohol)/alginate blend nanofibers by electrospinning method[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2010,366(1-3):135.

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