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材料导报  2026, Vol. 40 Issue (9): 25040281-13    https://doi.org/10.11896/cldb.25040281
  无机非金属及其复合材料 |
低温等离子体技术改性材料处理大气污染物研究进展
韩明洪, 李芬*, 杨莹, 杨东东, 王瑞莹, 邢智超
哈尔滨理工大学材料科学与化学工程学院,哈尔滨 150000
Research Advances in Low-temperature Plasma Technology-modified Materials for Atmospheric Pollutant Treatment
HAN Minghong, LI Fen*, YANG Ying, YANG Dongdong, WANG Ruiying, XING Zhichao
The School of Material Science and Chemical Engineering, Harbin University of Science and Technology, Harbin 150000, China
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摘要 低温等离子体材料改性技术因工艺简便、环境友好、处理时间短、功能效果显著等优点,在材料改性领域得到广泛应用。本文概述了低温等离子体技术的发展,介绍了辉光放电(GD)、大气压等离子体射流(APPJ)、电晕放电(CD)和介质阻挡放电(DBD)四种放电方式的产生机制及其材料的改性功能,重点讨论了低温等离子体改性材料在SO2、NOx、H2S、VOCs、Hg等大气污染物治理上的研究应用及去除机理,并总结了低温等离子体改性材料处理各类大气污染物的研究现状及优缺点。分析表明,尽管该技术在材料表面精准调控方面已取得突破,但未来仍需面对多尺度反应机理解析、工艺参数智能化调控及工程化应用适配性等挑战。本文旨在为低温等离子体技术在环境功能材料设计及大气污染治理中的深入应用提供理论支撑与技术路径。
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韩明洪
李芬
杨莹
杨东东
王瑞莹
邢智超
关键词:  低温等离子体  改性材料  大气污染物  吸附    
Abstract: Low-temperature plasma (LTP) material modification technology is widely utilized in materials engineering due to its significant advantages, including operational simplicity, environmental compatibility, rapid processing, and pronounced functional efficacy. This review outlines the evolution of LTP technology and elucidates the generation mechanisms and material modification functionalities of four principal discharge modes: glow discharge (GD), atmospheric pressure plasma jet (APPJ), corona discharge (CD), and dielectric barrier discharge (DBD). It focuses specifically on the research applications and removal mechanisms of LTP-modified materials in mitigating key atmospheric pollutants such as SO2, NOX, H2S, volatile organic compounds (VOCs), and mercury (Hg). Furthermore, the current research status, advantages, and limitations of LTP-modified materials for diverse air pollutant abatement are critically summarized. Analysis indicates that despite notable breakthroughs in precise surface engineering, the field must address persistent challenges including the elucidation of multi-scale reaction mechanisms, development of intelligent process control, and enhancement of scalability for engineering applications. This review aims to provide a theoretical foundation and identify potential technical pathways for advancing LTP applications in environmental functional material design and atmospheric pollution control.
Key words:  low-temperature plasma    modified material    atmospheric pollutant    adsorption
收稿日期:  2026-05-10      出版日期:  2026-05-10      发布日期:  2026-05-18
ZTFLH:  X511  
基金资助: 国家自然科学基金(22278100)
通讯作者:  *李芬,哈尔滨理工大学材料科学与化学工程学院教授、硕士研究生导师。主要研究方向为:纳米脱硫剂的制备、脱臭性能分析与应用。hgxylf@126.com   
作者简介:  韩明洪,哈尔滨理工大学材料科学与化学工程学院硕士研究生,在李芬教授的指导下进行研究。目前主要研究领域为治理恶臭气体材料的性能研究。
引用本文:    
韩明洪, 李芬, 杨莹, 杨东东, 王瑞莹, 邢智超. 低温等离子体技术改性材料处理大气污染物研究进展[J]. 材料导报, 2026, 40(9): 25040281-13.
HAN Minghong, LI Fen, YANG Ying, YANG Dongdong, WANG Ruiying, XING Zhichao. Research Advances in Low-temperature Plasma Technology-modified Materials for Atmospheric Pollutant Treatment. Materials Reports, 2026, 40(9): 25040281-13.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25040281  或          https://www.mater-rep.com/CN/Y2026/V40/I9/25040281
1 Jiang P, Chen Y, Geng Y, et al.Journal of Cleaner Production, 2013, 58, 130.
2 Arpanaei A, Winther-Jensen B, Theodosiou E, et al.Journal of Chromatography A, 2010, 1217(44), 6905.
3 Laureano-Anzaldo C M, González-López M E, Pérez-Fonseca A A, et al.Carbohydrate Polymers, 2021, 252, 117195.
4 Esteves B M, Pereira H M.BioResources, 2009, 4(1), 370.
5 Valente Nabais J M, Carrott P J M, Ribeiro Carrott M M L, et al.Carbon, 2004, 42(7), 1315.
6 Wang S, Li J, Suo J, et al.Applied Surface Science, 2010, 256(7), 2293.
7 Liu S X, Chen X, Chen X Y, et al.Journal of Hazardous Materials, 2007, 141(1), 315
8 Wu L, Wan W, Shang Z, et al.Separation and Purification Technology, 2018, 197, 156.
9 Zhao H, Li X, Su F, et al.Materials & Design, 2025, 251, 113702.
10 Williams C F, Hather C, Conteh J S, et al.Biochemical and Biophysical Research Communications, 2023, 661, 89.
11 Wu T.Environmental Science: Advances, 2023, 2(4), 558.
12 Tian J Y, Pang R D.Advanced Materials Research, 2011, 201, 2488.
13 Huang C, Chen Y, Zhao Y, et al.BioResources, 2017, 12(4), 9075.
14 Gilman A B, Kuznetsov А А, Ozerin А N.Russian Chemical Bulletin, 2017, 66(4), 577.
15 Huang Y, Yu Q, Li M, et al.Plasma Processes and Polymers, 2021, 18(3), 2000171.
16 Langmuir I.Proceedings of the National Academy of Sciences, 1928, 14(8), 627.
17 Chizoba Ekezie F G, Sun D W, Cheng J H.Trends in Food Science & Technology, 2017, 69, 46.
18 Kogelschatz U.Plasma Chemistry and Plasma Processing, 2003, 23(1), 1.
19 Liu Y X, Liu Y Q, Liu Y X, et al.China Journal Minim Invasive Neurosurg, 2024, 28(1), 45 (in Chinese)
刘一啸, 刘雨晴, 刘雨萱, 等.中国微侵袭神经外科杂志, 2024, 28(1), 45.
20 Kim H.Plasma Processes and Polymers, 2004, 1(2), 91.
21 Quitzau M, Wolter M, Kersten H.Plasma Processes and Polymers, 2009, 6(S1), S392.
22 Nehra V, Kumar A, Dwivedi H K.International Journal of Engineering, 2008, 2(1), 53.
23 Chang R, Ji N, Li M, et al.Ultrasonics Sonochemistry, 2019, 58, 104660.
24 Wiącek A E, Terpiłowski K, Jurak M, et al.Polymer Testing, 2016, 50, 325.
25 Ma Y, Guo J, Liu S, et al.ACS Omega, 2024, 9(7), 7564.
26 Liao X, Cullen P J, Muhammad A I, et al.Food Engineering Reviews, 2020, 12(3), 321.
27 Bogaerts A.Journal of Analytical Atomic Spectrometry, 1999, 14(9), 1375.
28 Qiao Q S, Ba D M, Materials Protection, 2022, 55(2), 117 (in Chinese)
乔乾森, 巴德玛.材料保护, 2022, 55(2), 117.
29 Khaledian H R, Zolfaghari P, Elhami V, et al.Molecules, 2019, 24(3), 383.
30 Zolfaghari P, Khaledian H R, Aliasgharlou N, et al.Applied Surface Science, 2019, 490, 266.
31 Wen Y, Shen C, Ni Y, et al.Journal of Hazardous Materials, 2012, 201, 162.
32 Temmerman E, Leys C.Surface and Coatings Technology, 2005, 200(1-4), 686.
33 Liu W, Zhu L, Chen X, et al.Plasma Chemistry and Plasma Processing, 2019, 39(2), 487.
34 Liu Z Y.Study on the process of atmospheric pressure plasma jet deposition of SiO2 insulating film.Master’s Thesis, Dalian Jiaotong University, China, 2023 (in Chinese).
刘智宇.大气压等离子体射流沉积SiO2绝缘薄膜工艺研究.硕士学位论文, 大连交通大学.
35 Ren G L, Wang Y, Wang D, et al.Electroplating & Finishing, 2024, 43(1), 80 (in Chinese)
任根来, 王鹰, 王东, 等.电镀与涂饰, 2024, 43(1), 80.
36 Lu X, Jiang Z, Xiong Q, et al.Applied Physics Letters, 2008, 92(8), 81502.
37 Koh T L, Gordon M J.Journal of Vacuum Science & Technology, A: Va-cuum, Surfaces, and Films, 2013, 31(6), 61312.
38 Penkov O V, Khadem M, Lim W S, et al.Journal of Coatings Technology and Research, 2015, 12(2), 225.
39 Dowling D P, O’Neill F T, Langlais S J, et al.Plasma Processes and Polymers, 2011, 8(8), 718.
40 Moritzer E, Budde C, Leister C.Welding in the World, 2015, 59(1), 23.
41 Lommatzsch U, Pasedag D, Baalmann A, et al.Plasma Processes and Polymers, 2007, 4(S1), S1041.
42 Takemura Y, Yamaguchi N, Hara T.Japanese Journal of Applied Physics, 2008, 47(7R), 5644.
43 Krochmalny K, Pawlak-Kruczek H, Skoczylas N, et al.Energies, 2022, 15(12), 4396.
44 Mui T S M, Silva L L G, Prysiazhnyi V, et al.Surface and Coatings Technology, 2017, 312, 32.
45 Wang C X, Qiu Y P.Surface and Coatings Technology, 2007, 201(14), 6273.
46 McAdams R.Journal of Physics D: Applied Physics, 2001, 34(18), 2810.
47 Chang J S, Lawless P A, Yamamoto T.IEEE Transactions on Plasma Science, 1991, 19(6), 1152.
48 Talebizadeh P, Babaie M, Brown R, et al.Renewable and Sustainable Energy Reviews, 2014, 40, 886.
49 Sadeghi-Kiakhani M, Tayebi H allah.Journal of the Textile Institute, 2016, 1, 108(7), 1164.
50 Talebian A, Habibi S, Neshat P.Journal of the Textile Institute, 2021, 112(1), 144.
51 Wang X, Cao G, Xu W.Journal of Applied Polymer Science, 2009, 112(4), 1959.
52 Pascual M, Sanchis R, Sánchez L, et al.Journal of Adhesion Science and Technology, 2008, 22(13), 1425.
53 Komagata Y, Ikeda H, Fujio Y, et al.Journal of the Mechanical Behavior of Biomedical Materials, 2020, 105, 103708.
54 Xu L, Fang Z, Song P, et al.Applied Surface Science, 2010, 256(21), 6447.
55 Bárdos L, Baránková H.Thin Solid Films, 2010, 518(23), 6705.
56 Eliasson B, Hirth M, Kogelschatz U.Journal of Physics D: Applied Physics, 1987, 20(11), 1421.
57 Pan X, Zhang R, Peng S, et al.Fibers and Polymers, 2010, 11(3), 372.
58 Moreno-Couranjou M, Choquet P, Guillot J, et al.Plasma Processes and Polymers, 2009, 6(S1), S397.
59 Krupa A, Sobczyk A T, Jaworek A.Fibres & Textiles in Eastern Europe, 2014, 22(2), 104.
60 Vander Wielen L C, Östenson M, Gatenholm P, et al.Carbohydrate Polymers, 2006, 65(2), 179.
61 Qu G Z, Li J, Liang D L, et al.Journal of Electrostatics, 2013, 71(4), 689.
62 Li K, Liu G, Gao T, et al.Applied Catalysis A: General, 2016, 527, 171.
63 Wu H, Shen W, Zhao Q, et al.RSC Advances, 2024, 14(4), 2410.
64 Khan A A, Ling Y S, Chowdhury Z Z.European Physical Journal Plus, 2024, 139(8), 673.
65 Liu J H, Zhang M, Chen X Y, et al.Letters in Applied Microbiology, 2022, 74(1), 103.
66 Wang J, Zhao H, Song J, et al.Catalysts, 2019, 9(9), 726.
67 Dai Q, Wu J, Deng W, et al.Applied Catalysis B: Environmental, 2019, 249, 9.
68 Li N, Cheng J, Xing X, et al.Journal of Hazardous Materials, 2020, 393, 122412.
69 Zou L, Yan P, Lu P, et al.Royal Society Open Science, 2020, 7(8), 192248.
70 Strelko V V, Kuts V S, Thrower P A.Carbon, 2000, 38(10), 1499.
71 Che Y, Zhou J, Wang Z.Plasma Science and Technology, 2013, 15(10), 1047.
72 Bai B C, Lee H U, Lee C W, et al.Chemical Engineering Journal, 2016, 306, 260.
73 Chen P.International Journal of Humanities and Social Sciences, 2019, 2, 466.
74 Yao Q, Yang Z, Nie C, et al.Chemical Engineering Journal, 2024, 499, 156565.
75 Zhou J Y.Plasma modification of activated carbon fiber for the adsorption of SO2 and NO.Ph.D.Thesis, Wuhan University, China, 2012 (in Chinese).
周家勇.等离子体改性活性炭纤维脱硫脱氮研究.博士学位论文, 武汉大学.
76 Zhang Q Z, Bogaerts A.Plasma Sources Science and Technology, 2018, 27(3), 35009.
77 Wang T, Liu H, Zhang X, et al.Applied Surface Science, 2018, 457, 187.
78 Chen K, Chen R, Cang H, et al.Environmental Technology, 2018, 39(14), 1753.
79 Tang X, Gao F, Xiang Y, et al.Catalysis Communications, 2015, 64, 12.
80 Wan Y, Zhao W, Tang Y, et al.Applied Catalysis B: Environmental, 2014, 148, 114.
81 Chang L, Li X, Hong H, et al.Acta Physico-Chimica Sinica, 2009, 25(6), 1033.
82 Liu L, Zheng C, Wu S, et al.Applied Surface Science, 2017, 416, 78.
83 Sheng X H.Preparation of the Mo-based denitrification catalyst enhanced by low-temperature plasma and its SCR denitrification performance.Master’s Thesis, Chongqing University of Technology, China, 2023(in Chinese).
盛小红.低温等离子体协同增强Mo基脱硝催化剂的制备及其SCR脱硝性能研究.硕士学位论文, 重庆理工大学, 2023.
84 Shen H.Preparation and structure-performance relationship of the Mn-based C3H6-SCR catalysts by plasma.Master’s Thesis, Chongqing University of Technology, China, 2024(in Chinese).
沈洪.等离子体增强型C3H6-SCR Mn基催化剂的制备及构效关系研究.硕士学位论文, 重庆理工大学, 2024.
85 Xiang Y.Research on catalysts treated by non-thermal plasma for nitrogen oxide reduction.Master’s Thesis, Kunming University of Science and Technology, China, 2013(in Chinese).
向瑛.低温等离子体改性催化剂脱除氮氧化物研究.硕士学位论文, 昆明理工大学, 2013.
86 Yin Y.Chemical Engineering Journal, 2024, 499, 156141.
87 Zhang X, Tang Y, Qu S, et al.ACS Catalysis, 2015, 5(2), 1053.
88 Wu J, Chen W, Chen L, et al.Journal of Hazardous Materials, 2022, 424, 127648.
89 Liu S J.Research on the removal of H2S on carbon base catalysts modified by dielectric barrier discharge plasma.Master’s Thesis, Kunming University of Science and Technology, China, 2017(in Chinese).
刘思健.介质阻挡放电等离子体表面修饰碳基催化剂脱除硫化氢研究.硕士学位论文, 昆明理工大学, 2017.
90 Ning P, Liu S, Wang C, et al.Journal of Environmental Sciences, 2018, 64, 216.
91 Li S, Li K, Hao J, et al.Chemical Engineering Journal, 2016, 302, 69.
92 Feng J, Wang F, Wang C, et al.ACS Applied Materials & Interfaces, 2021, 13(21), 24670.
93 Yang X, Li K, Wang C, et al.Journal of Environmental Sciences, 2023, 127, 641.
94 Yan Y, Yang X, Ning P, et al.Journal of Environmental Sciences, 2025, 148, 476.
95 Fu Y, Zhang Y, Xin Q, et al.Catalysts, 2020, 10(12), 1456.
96 Wang B, Wang N, Sun Y, et al.Applied Surface Science, 2023, 614, 156162.
97 Su G, Xiong J, Li Q, et al.Chemical Engineering Journal, 2023, 455, 140686.
98 Beykmohamadloo P, Yarahmadi R.Iran Occupational Health, 2019, 16(4), 1.
99 Sumitsawan S, Cho J, Sattler M L, et al.Environmental Science & Technology, 2011, 45(16), 6970.
100 Tan Y, Zhao W, Sun L, et al.Journal of Cleaner Production, 2022, 369, 133280.
101 Sun R, Zhu H, Shi M, et al.Fuel, 2020, 266, 116936.
102 Zhang J, Duan Y, Zhou Q, et al.Chemical Engineering Journal, 2016, 294, 281.
103 Hu P, Duan Y, Ding W, et al.Energy & Fuels, 2017, 31(12), 13852.
104 Luo J, Jin M, Ye L, et al.Journal of Hazardous Materials, 2019, 377, 132.
105 Wang T, Liu J, Zhang Y, et al.Chemical Engineering Journal, 2018, 331, 536.
106 Shi M, Luo G, Xu Y, et al.Fuel, 2019, 254, 115549.
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