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材料导报  2025, Vol. 39 Issue (23): 24120201-8    https://doi.org/10.11896/cldb.24120201
  无机非金属及其复合材料 |
高性能钙钛矿单晶太阳电池研究进展
苏航*, 薛静炜, 杨元博, 李田田, 李立伟, 蒋龙*
中国石油集团工程材料研究院有限公司,西安 710000
Research Progress of High-performance Perovskite Single-crystal Solar Cells
SU Hang*, XUE Jingwei, YANG Yuanbo, LI Tiantian, LI Liwei, JIANG Long*
CNPC Tubular Goods Research Institute, Xi’an 710000, China
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摘要 得益于有机无机杂化钙钛矿材料优异的光电特性,在过去十几年中,钙钛矿太阳电池的认证效率已提高到26.7%,是当今光伏领域发展最为迅速的技术。与广泛研究的多晶薄膜相比,无晶界的单晶钙钛矿具有更低的缺陷密度、更优异的光电特性和更好的稳定性,在制备更高效率、更长寿命的光伏器件方面展现出巨大潜力。此外,单晶钙钛矿太阳电池还是深入研究钙钛矿材料表面和晶界相关机理的绝佳模型。遗憾的是,受限于三维单晶薄片生长的极高难度,目前全球仅有少数研究组进行了单晶钙钛矿太阳电池的开发,导致这一领域的发展速度远落后于多晶薄膜电池。鉴于此,本综述首先介绍了钙钛矿单晶薄片生长的方法,并总结了近期钙钛矿单晶电池的最新研究进展,最后详细讨论了单晶钙钛矿太阳电池面临的挑战和发展前景。
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苏航
薛静炜
杨元博
李田田
李立伟
蒋龙
关键词:  钙钛矿  单晶薄片  太阳电池  高效率    
Abstract: In the past decade or so, thanks to the excellent photovoltaic properties of organic-inorganic hybrid perovskite materials, the certified efficiency of perovskite solar cells has increased to 26.7%, which is the most rapidly developing technology in photovoltaics. With a less trap-state density, superior photovoltaic properties and better stability than the widely studied polycrystalline thin films, single-crystal perovskite without grain boundaries shows a greater potential for the preparation of higher efficiency and longer lifetime photovoltaic devices. In addition, single-crystal perovskite solar cells are excellent models for further mechanism studies related to the surface and grain boundaries of perovskite materials. Unfortunately, limited by the high difficulty of growing 3D single-crystal thin films, only a few groups have carried out the development of single-crystal perovskite solar cells, resulting in the development of this field lagging far behind that of polycrystalline film counterparts. Therefore, this review introduces the methods of single-crystal perovskite thin films growth and summarizes the recent research progress in perovskite single-crystal solar cells. Finally, the challenges and development prospects of single-crystal perovskite solar cells are discussed in detail.
Key words:  perovskite    single-crystal thin film    solar cell    high efficiency
出版日期:  2025-12-10      发布日期:  2025-12-03
ZTFLH:  TM914.4  
基金资助: 国家重点研发计划(2022YFB4200305);中国石油集团关键核心技术攻关项目(2024ZG50)
通讯作者:  *苏航,博士。主要研究领域包括高效钙钛矿单结及叠层太阳电池开发、钙钛矿单晶生长及器件应用。suhang011@cnpc.com.cn;蒋龙,博士,正高级工程师。从事余热利用热电转化、光伏和电化学储能等新能源材料与器件研发方面的研究。jianglong003@cnpc.com.cn   
引用本文:    
苏航, 薛静炜, 杨元博, 李田田, 李立伟, 蒋龙. 高性能钙钛矿单晶太阳电池研究进展[J]. 材料导报, 2025, 39(23): 24120201-8.
SU Hang, XUE Jingwei, YANG Yuanbo, LI Tiantian, LI Liwei, JIANG Long. Research Progress of High-performance Perovskite Single-crystal Solar Cells. Materials Reports, 2025, 39(23): 24120201-8.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24120201  或          https://www.mater-rep.com/CN/Y2025/V39/I23/24120201
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