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材料导报  2026, Vol. 40 Issue (5): 24120070-15    https://doi.org/10.11896/cldb.24120070
  无机非金属及其复合材料 |
废轮胎油定向转化制备碳基储能电极材料研究进展
杨崟, 李宇龙, 肖婷, 张琛, 高金森, 徐春明, 马新龙*
中国石油大学(北京)重质油全国重点实验室,北京 102249
Research Progress on the Directed Preparation of Carbon-based Energy Storage Electrode Materials from Waste Tire Oil
YANG Yin, LI Yulong, XIAO Ting, ZHANG Chen, GAO Jinsen, XU Chunming, MA Xinlong*
State Key Laboratory of Heavy Oil, China University of Petroleum (Beijing), Beijing 102249, China
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摘要 电化学储能器件的性能边界本质上取决于电极材料的微观结构特征,碳材料因其可调控的电子能带结构和丰富的孔道拓扑形态已成为储能领域的核心材料。废轮胎油作为全球大宗固体废弃物的热解主产物,因其独特的分子构型优势而备受关注,但其向储能材料的定向转化仍面临多组分协同转化的分子机理、微观结构与宏观性能的构效关系、多尺度传递过程的工程科学等关键科学问题亟待突破。本文系统阐述了废轮胎油的原料特性,深入分析了其分子组成特征及转化行为对储能性能的影响机制;梳理了各类制备工艺的结构调控原理与技术演进;全面评价了废轮胎油基碳材料在储能器件中的性能表现,阐明了其电荷存储机制和界面动力学;通过与传统碳源的系统对比,论证了废轮胎油在原料特性和商业化前景方面的显著优势。针对关键科学问题,提出了理论构建、技术创新和工程化集成的解决策略,为该领域的基础理论创新和产业化发展提供了系统性科学指导。
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杨崟
李宇龙
肖婷
张琛
高金森
徐春明
马新龙
关键词:  废轮胎热解油  碳基材料  储能  高值化利用    
Abstract: The performance boundaries of electrochemical energy storage devices are fundamentally governed by the microstructural characteristics of electrode materials, with carbon materials establishing themselves as indispensable components owing to their tunable electronic band structures and diverse pore topologies. Waste tire pyrolysis oil (WTPO), as the predominant product derived from the thermal decomposition of massive global tire waste, has garnered significant attention due to its distinctive molecular architecture advantages. However, the directed conversion of WTPO into energy storage materials remains constrained by critical scientific challenges, including the molecular mechanisms governing multi-component synergistic transformation, the structure-property relationships linking microscopic features to macroscopic performance, and the engineering science of multi-scale transport phenomena. This review systematically elucidates the fundamental material chemistry of WTPO, providing in-depth analysis of how its molecular composition characteristics and transformation behaviors influence energy storage performance. The structural regulation principles and technological evolution of various synthesis methodologies are comprehensively reviewed. The electrochemical performance of WTPO-derived carbon materials across different energy storage devices is thoroughly evaluated, with particular emphasis on elucidating charge storage mechanisms and interfacial dynamics. Through systematic comparison with conventional carbon precursors, the remarkable advantages of WTPO in terms of feedstock properties and commercialization prospects are demonstrated. Addressing the identified key scientific challenges, strategic solutions encompassing theoretical framework construction, technological innovation, and engineering integration are proposed, providing systematic scientific guidance for fundamental theoretical breakthroughs and industrial development in this interdisciplinary field.
Key words:  waste tire pyrolysis oil    carbon-based materials    energy storage    high-value utilization
出版日期:  2026-03-10      发布日期:  2026-03-10
ZTFLH:  TQ152  
基金资助: 国家自然科学基金青年科学基金 (21706283)
通讯作者:  *马新龙,博士,中国石油大学(北京)化学工程与环境学院副教授、博士研究生导师。目前主要从事高质量化学气相沉积石墨烯、电化学储能用关键电极材料、石油基碳材料的可控及规模化制备等方面的研究。maxl@cup.edu.cn   
作者简介:  杨崟,中国石油大学(北京)化学工程与环境学院博士研究生,在马新龙教授的指导下进行研究。目前主要从事高性能碳基储能材料的研发及其复合材料的应用基础研究。
引用本文:    
杨崟, 李宇龙, 肖婷, 张琛, 高金森, 徐春明, 马新龙. 废轮胎油定向转化制备碳基储能电极材料研究进展[J]. 材料导报, 2026, 40(5): 24120070-15.
YANG Yin, LI Yulong, XIAO Ting, ZHANG Chen, GAO Jinsen, XU Chunming, MA Xinlong. Research Progress on the Directed Preparation of Carbon-based Energy Storage Electrode Materials from Waste Tire Oil. Materials Reports, 2026, 40(5): 24120070-15.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24120070  或          https://www.mater-rep.com/CN/Y2026/V40/I5/24120070
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