碳酸钙类石粉在混凝土材料中的再利用研究综述

doi:10.11896/cldb.24040100

材料导报

2025, Vol. 39

Issue (10): 24040100-15 https://doi.org/10.11896/cldb.24040100

无机非金属及其复合材料

碳酸钙类石粉在混凝土材料中的再利用研究综述

张巧¹, 张艺欣^1,2,3, 陈茜⁴, 侯炜^1,2,3,*, 涂兵雄^1,2,3

1 华侨大学土木工程学院,福建厦门 361021
2 福建省结构工程与防灾重点实验室,福建厦门 361021
3 南安华大石材产业技术研究院,福建泉州 362342
4 中交三航局第六工程(厦门)有限公司,福建厦门 361006

Recycling Calcium Carbonate Stone Powder in Concrete Material:a Review

ZHANG Qiao¹, ZHANG Yixin^1,2,3, CHEN Xi⁴, HOU Wei^1,2,3,*, TU Bingxiong^1,2,3

1 College of Civil Engineering, Huaqiao University, Xiamen 361021, Fujian, China
2 Key Laboratory for Structural Engineering and Disaster Prevention of Fujian Province, Xiamen 361021, Fujian, China
3 Nan’an-HQU Institute of Stone Industry Innovations Technology, Quanzhou 362342, Fujian, China
4 CCCC Third Harbor Engineering No.6 Co., Ltd.,(Xiamen), Xiamen 361006, Fujian, China

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摘要石粉在混凝土材料中的再利用可为石材行业中的废弃微粉提供规模化消纳途径,诸多学者对石粉混凝土的性能开展了试验研究。本文以碳酸钙类石粉为研究对象,主要包括大理石粉(Marble powder,MP)和石灰石粉(Limestone powder,LP),分析了二者的理化性质与微观形貌特征;系统梳理了国内外学者对掺入MP、LP的水泥基材料性能的研究,分别分析了二者对混凝土水化过程、微细观结构的影响和作用机理,进而分析了不同替代方式、水灰比(w/c)等关键参数对石粉混凝土流变性能、力学性能和耐久性能的影响,并对石粉混凝土的强度预测模型、环境和经济效益、结构应用进行了总结。研究结果表明充分利用MP和LP的细度和组分特性,基于适当的配合比设计,石粉能够起到加速水泥水化、细化孔隙结构的作用,可表现出填充效应、成核效应、化学效应作用机理,从而稳定提升混凝土材料的流变、力学和耐久性能。此外,在强度预测模型方面,机器学习技术能够较好地预测石粉混凝土的强度。在环境和经济评价方面,适量石粉替代水泥或者细骨料能够提升混凝土的环境、经济效益。在结构应用方面,适宜掺量的石粉混凝土能够保证混凝土梁的承载能力。最后对国内外相关技术标准与规范现状进行了总结。

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关键词: 大理石粉石灰石粉碳酸钙混凝土微细观结构宏观性能

Abstract: Stone powder can be recycled in concrete materials, offering a large-scale solution for utilizing waste micropowder from the stone industry. There are a lot of experimental studies on the performance of concrete incorporating stone powder. This article focuses on calcium carbonate stone powder, mainly referred to marble powder (MP) and limestone powder (LP) as addition of concrete. Firstly, the physical and chemical properties, and microscopic morphological characteristics of both are analyzed. Then, systematically reviews the researches on properties of cement materials with the addition of MP and LP, analyzes the effects and mechanisms of MP and LP on the hydration process and microstructure of concrete, and investigates the impacts of key parameters, such as various substitution methods, water-cement ratio (W/C), etc, on stone powder concrete performance, including rheological properties, mechanical properties, and durability. Furthermore, strength prediction model, environmental and economic benefits, and structural applications of stone powder concrete were summaried. The research indicates that by fully utilizing the fineness and component characteristics of MP and LP, along with appropriate mix ratio design, stone powder can accelerate cement hydration, refine the pore structure, and demonstrate filling effect, nucleation effect and chemical effect. This process stably improves the rheological, mechanical, and durability properties of concrete materials. Additionally, in terms of strength prediction model, machine learning techno-logy can accurately predict the strength of stone powder concrete. In terms of environmental and economic evaluations, replacing cement or fine aggregate with an appropriate amount of stone powder can enhance the environmental and economic benefits of concrete. In terms of structural applications, suitable amounts of stone powder concrete can ensure the load-bearing capacity of concrete beams. Finally, the status quo of relevant technical standards and specifications at home and abroad are summarized.

Key words: marble powder limestone powder calcium carbonate concrete microstructures macroscopic property

出版日期: 2025-05-25 发布日期: 2025-05-13

ZTFLH:

TB332

基金资助: 国家自然科学基金(52208313;52178210);福厦泉国家自主创新示范区协同创新平台项目(3502ZCQXT2022002);华侨大学中青年教师科技创新资助计划(ZQN-1116)

通讯作者: *侯炜,华侨大学土木工程学院教授、博士研究生导师,华侨大学海洋土木工程综合防灾及智能监测研究中心主任。主要研究方向包括创新海洋工程结构及新材料、超高性能混凝土(UHPC/ECC等)及其结构应用、固废(石粉)资源化综合利用、高性能组合结构等。houwei@hqu.edu.cn

作者简介: 张巧,华侨大学土木工程学院硕士研究生,在侯炜教授和张艺欣副教授的指导下进行研究。目前主要研究领域为轻质超高性能混凝土设计方法与力学性能。

引用本文:

张巧, 张艺欣, 陈茜, 侯炜, 涂兵雄. 碳酸钙类石粉在混凝土材料中的再利用研究综述[J]. 材料导报, 2025, 39(10): 24040100-15.
ZHANG Qiao, ZHANG Yixin, CHEN Xi, HOU Wei, TU Bingxiong. Recycling Calcium Carbonate Stone Powder in Concrete Material:a Review. Materials Reports, 2025, 39(10): 24040100-15.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24040100 或 https://www.mater-rep.com/CN/Y2025/V39/I10/24040100

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