钢筋混凝土环境中负载型阻锈剂的研究进展

doi:10.11896/cldb.22050296

材料导报

2024, Vol. 38

Issue (2): 22050296-14 https://doi.org/10.11896/cldb.22050296

无机非金属及其复合材料

钢筋混凝土环境中负载型阻锈剂的研究进展

徐宁^1,2, 杨恒^1,2,*, 熊传胜³, 崔征^1,2,4, 蒋鹏^1,2, 刘璨^1,2

1 南京水利科学研究院,南京 210029
2 水文水资源与水利工程科学国家重点实验室,南京 210029
3 青岛理工大学土木工程学院,山东青岛 266033
4 南京瑞迪高新技术有限公司,南京 210024

Research Progress of Carrier-loaded Corrosion Inhibitor in Reinforced-Concrete Environments

XU Ning^1,2, YANG Heng^1,2,*, XIONG Chuansheng³, CUI Zheng^1,2,4, JIANG Peng^1,2, LIU Can^1,2

1 Nanjing Hydraulic Research Institute, Nanjing 210029, China
2 State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Nanjing 210029, China
3 School of Civil Engineering, Qingdao University of Technology, Qingdao 266033, Shandong, China
4 Nanjing R&D Hi-Tech Co., Ltd., Nanjing 210024, China

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摘要阻锈剂技术是抑制混凝土中钢筋锈蚀的重要途径,但传统阻锈剂的应用仍然面临功能单一、与混凝土的兼容性不佳、环保性和有效性难以兼顾等问题。将阻锈剂装载入载体中,以载体负载阻锈剂(Carrier-loaded corrosion inhibitor,CLCI)的形式将阻锈剂“间接”掺入混凝土,能够在避免阻锈剂原有缺陷的基础上,发挥载体的特有功能。本文围绕CLCI的离子固化、缓释效应、智能响应、pH自免疫系统、载体吸附效应等功能机制,结合CLCI对水泥基材料性能的影响,系统综述了CLCI的研究进展。最后,对其在混凝土中的研究和应用进行了展望,并提出了需要解决的问题,以期为CLCI在混凝土工程中的应用提供更多可能性。

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关键词: 负载型阻锈剂钢筋混凝土腐蚀智能响应缓释力学性能

Abstract: Corrosion inhibitors provide an important way of protecting concrete steel bars from corrosion, and they have always been a research hotspot in the field of corrosion inhibition. However, the application of corrosion inhibitors still faces several problems, e.g., single performance, poor compatibility with cement-based materials, and difficulty in balancing environmental protection and effectiveness. A corrosion inhibitor is ‘indirectly’ mixed into concrete in the form of a carrier-loaded corrosion inhibitor (CLCI), which not only avoids the original defects of corrosion inhibitors, but it also plays the unique function of the carrier. In this paper, we systematically summarize the research progress of CLCIs in reinforced-concrete environments from the perspectives of the action mechanism of ion curing, slow-release, intelligent response, the pH autoimmune system, and the carrier adsorption effect and its influence on the properties of cement-based materials. Finally, research and application prospects of CLCI in concrete are detailed, and the problems to be solved are put forward to illuminate more possibilities for the application of CLCI in concrete engineering.

Key words: carrier-loaded corrosion inhibitor corrosion of reinforced-concrete intelligent response slow-release mechanical property

出版日期: 2024-01-25 发布日期: 2024-01-26

ZTFLH:

TU528

基金资助: 江苏省自然科学基金(BK20230119);国家自然科学基金(51709253);中央级公益性科研院所基本科研业务费专项项目(Y422004)

通讯作者: *杨恒,南京水利科学研究院材料结构研究所工程师,博士毕业于河海大学。主要从事钢筋混凝土腐蚀、负载型阻锈剂方面的研究,在Construction and Building Materials、Materials Letters、Progress in Organic Coatings等期刊发表SCI论文10余篇,主持中央级公益性科研院所基本科研业务费专项项目1项,参与国家杰出青年科学基金、国家自然科学基金面上项目及青年项目等在内的国家级科研项目3项。hengyang@nhri.cn

作者简介: 徐宁,南京水利科学研究院材料结构研究所高级工程师,博士毕业于河海大学。江苏省“333高层次人才培养工程”中青年学术技术带头人。主持或部分主持包括国家重点研发项目、国家自然科学基金、科技支撑计划、交通部西部建设项目等在内的国家和省部级科研项目8项,负责完成10余项重大工程科研项目。主要从事钢筋阻锈剂、高性能混凝土、电化学修复技术等方面的研究。主/参编行业规范3部,发表论文20余篇,其中SCI/EI收录10余篇。

引用本文:

徐宁, 杨恒, 熊传胜, 崔征, 蒋鹏, 刘璨. 钢筋混凝土环境中负载型阻锈剂的研究进展[J]. 材料导报, 2024, 38(2): 22050296-14.
XU Ning, YANG Heng, XIONG Chuansheng, CUI Zheng, JIANG Peng, LIU Can. Research Progress of Carrier-loaded Corrosion Inhibitor in Reinforced-Concrete Environments. Materials Reports, 2024, 38(2): 22050296-14.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.22050296 或 https://www.mater-rep.com/CN/Y2024/V38/I2/22050296

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