Al2O3夹杂物在浸入式水口内衬材料上的成核与反应性研究

doi:10.11896/cldb.23080196

材料导报

2024, Vol. 38

Issue (24): 23080196-8 https://doi.org/10.11896/cldb.23080196

无机非金属及其复合材料

Al₂O₃夹杂物在浸入式水口内衬材料上的成核与反应性研究

殷彦菲^1,2, 顾强², 李红霞², 刘国齐^1,2,*, 李欣哲^1,2

1 郑州大学材料科学与工程学院,郑州 450001
2 中钢集团洛阳耐火材料研究院有限公司,河南洛阳 471000

Study on the Nucleation and Reactivity of Al₂O₃ Inclusions on the Liner of Submerged Entry Nozzle

YIN Yanfei^1,2, GU Qiang², LI Hongxia², LIU Guoqi^1,2,*, LI Xinzhe^1,2

1 School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
2 Luoyang Institute of Refractories Research Co., Ltd., Luoyang 471000, Henan, China

摘要
参考文献
相关文章
推荐阅读
Metrics

下载:

全文 ( PDF ) ( 9533KB )
输出: BibTeX | EndNote (RIS)

摘要浸入式水口复合无硅无碳内衬材料是减缓结瘤堵塞的重要措施。为深化研究Al₂O₃夹杂物在浸入式水口内衬表面的结瘤现象,采用晶格失配计算及高温模拟试验验证的方法研究了钢液中Al₂O₃夹杂物在氧化锆质、尖晶石质、刚玉质、莫来石质内衬材料上的成核趋势及反应;基于显微结构观察分析了异质形核机理和沉积过程。结果表明:Al₂O₃夹杂物与刚玉质、氧化锆质、尖晶石质、莫来石质内衬材料的二维失配度分别为0%,30.97%、8.43%、11.14%,表明Al₂O₃夹杂物易于在刚玉质内衬上成核,难以在氧化锆质内衬上成核,氧化锆基材料适宜作为浸入式水口防堵内衬材质。高温模拟试验结果与二维失配计算结果相一致,氧化锆基内衬不易与钢液发生反应且表面Al₂O₃结瘤程度较轻,仅为刚玉质、尖晶石质、莫来石质内衬上Al₂O₃结瘤厚度的1/2。本工作基于晶格失配理论提出了一种抗Al₂O₃结瘤内衬材料优选策略,可为开发高性能功能耐火材料提供科学指导。

	服务
	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	殷彦菲
	顾强
	李红霞
	刘国齐
	李欣哲

关键词: 浸入式水口 Al₂O₃结瘤沉积晶格失配异相成核

Abstract: To composite silicon-free and carbon-free liner in submerged entry nozzle is an important measure to slow down the clogging. In order to further study the clogging of Al₂O₃ inclusions on the liner surface, the nucleation trend and reactivity of Al₂O₃ inclusions on zirconia liner, MgO-Al₂O₃ spinel liner, corundum liner and mullite liner was studied by lattice mismatch calculation and high temperature simulation test, respectively. The heterogeneous nucleation mechanism and deposition process were also analyzed based on microstructure observation. The results showed that the two-dimensional mismatch between Al₂O₃ inclusions and corundum liner, zirconia liner, spinel liner and mullite liner is 0%, 30.97%, 8.43% and 11.14%, respectively, it indicated that Al₂O₃ inclusion was easy to nucleate on corundum liner and difficult to nucleate on zirconia liner. Zirconia-based material was suitable as anti-clogging materials for submerged entry nozzle. The results of high temperature simulation test were consistent with those of two-dimensional mismatch calculation. Zirconia liner was not easy to react with molten steel and the degree of Al₂O₃ clogging on its surface was the lightest in these four liners. The thickness of Al₂O₃ clogging on zirconia liner was only 0.20 mm, which is only half of that on corundum liner, spinel liner or mullite liner. Based on the lattice mismatch theory, this work proposed an optimization strategy for Al₂O₃ anti-clogging materials, which should provide a scientific guidance for the development of high-performance functional refractories.

Key words: submerged entry nozzle Al₂O₃ clogging deposition lattice mismatch heterogeneous nucleation

出版日期: 2024-12-25 发布日期: 2024-12-20

ZTFLH:

TQ175

基金资助: 国家自然科学基金(51932008;52302031);中原科技创新领军人才(204200510011);国家重点研发计划(2021YFB3701404)

通讯作者: * 刘国齐,工学博士,中钢集团洛阳耐火材料研究院高级技术专家,正高级工程师,硕士研究生导师。1997 年河北理工学院无机非金属专业本科毕业,2000 年洛阳耐火材料研究院无机非金属材料专业硕士毕业后在该院工作至今,2006 年北京科技大学材料学专业博士毕业,目前主要从事功能耐火材料等方面的研究,主持或参与了多项省部级以上科研课题的研究开发工作,获国家技术发明二等奖(排名第3)1 项,在 Ceramic International、Journal of Alloy and Compounds、《耐火材料》等期刊上发表学术论文 100 余篇,授权发明专利 18 件,主持修订《连铸用功能耐火制品》标准,获国务院政府特殊津贴。 liugq@lirrc.com

作者简介: 殷彦菲,2022 年6 月毕业于山东理工大学,获工学学士学位。现为郑州大学材料科学与工程学院硕士研究生,在刘国齐教授的指导下进行研究。目前主要从事耐火材料方向的研究。

引用本文:

殷彦菲, 顾强, 李红霞, 刘国齐, 李欣哲. Al₂O₃夹杂物在浸入式水口内衬材料上的成核与反应性研究[J]. 材料导报, 2024, 38(24): 23080196-8.
YIN Yanfei, GU Qiang, LI Hongxia, LIU Guoqi, LI Xinzhe. Study on the Nucleation and Reactivity of Al₂O₃ Inclusions on the Liner of Submerged Entry Nozzle. Materials Reports, 2024, 38(24): 23080196-8.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.23080196 或 http://www.mater-rep.com/CN/Y2024/V38/I24/23080196

1 Li H X. Functional refractories for modern metallurgy, Metallurgical Industry Press, China, 2019, pp.608 (in Chinese).
李红霞. 现代冶金功能耐火材料, 冶金工业出版社, 2019, pp.608.
2 Liu G Q, Li H X, Yuan L, et al. Refractories, 2021, 55(6), 533 (in Chinese).
刘国齐, 李红霞, 袁磊, 等. 耐火材料, 2021, 55(6), 533.
3 Cheng G, Zhang L F, Wang W B, et al. In: 10th International Sympo-sium on High-temperature Metallurgical Processing. Switzerland, 2019, pp.309.
4 Tian C, Yu J K, Jin E D, et al. Journal of Alloys and Compounds, 2019, 792(12), 1.
5 Hao X, Gu Q, Chen Z H, et al. Materials Reports, 2021, 35(Z1), 489 (in Chinese).
郝娴, 顾强, 陈子豪, 等. 材料导报, 2021, 35(Z1), 489.
6 Hua C J, Wang M, Senk D, et al. Metals, 2021, 11(4), 662.
7 Li G J, Tang H Y, Jiang X Y, et al. Ceramics International, 2022, 48(14), 19732.
8 Li H X, Liu G Q, Yang B, et al. Refractories, 2001, 35(1), 45(in Chinese).
李红霞, 刘国齐, 杨彬, 等. 耐火材料, 2001, 35(1), 45.
9 Zhu L L, Li S, Gao X X, et al. Journal of the Australian Ceramic Society, 2023, 59(1), 259.
10 Sambasivam R. Ironmaking & Steelmaking, 2006, 33(6), 439.
11 Tehovnik F, Burja J, Arh B, et al. Metallurgy, 2015, 54(2), 371.
12 Liang W, Li J, Lu B, et al. Journal of Iron and Steel Research International, 2022, 29(1), 34.
13 Koji M, Makoto N, Yukio O, et al. In:Iron and Steel Technology Confe-rence. USA, 2016, pp.1681.
14 Devi S, Singh R K, Sen N, et al. Materials Science Forum, 2020, 978(23), 12.
15 Cai X F, Bo Y P, Lin L, et al. Steel Research International, 2016, 87(9), 1168.
16 Yi W, Li W F, Yang W. Journal of Iron and Steel Research International, 2022, 29(11), 175.
17 Rajtora O J. The use of air plasma spray coatings in the reduction of alumina clogging in the continuous casting of steel. Master’s Thesis, Missouri University of Science and Technology, USA, 2004.
18 Zhang L F, Taniguchi S. International Materials Reviews. 2000, 45(2), 59.
19 Xu Z Y, Liu J H, He Z J, et al. Metalurgija, 2018, 57(1-2), 79.
20 Tian C, Yuan L, Wen T P, et al. Ceramics International, 2022, 48(5), 6799.
21 Yu J K, Yang X, Liu Z Y, et al. Ceramics International, 2017, 43(15), 13025.
22 Chen L M, Zhang L F, Ren Y, et al. Metallurgical and Materials Transactions B, 2021, 52(18), 1186.
23 Deng Z Y, Zhu M Y, Zhong B J, et al. ISIJ International, 2014, 54(12), 2813.
24 Zhu L L, Li S, Gao Z X, et al. Journal of the Australian Ceramic Society, 2023, 59(1), 259.
25 Chen D D, Zhang X, Lv J M, et al. Intermetallics, 2023, 162(23), 107996.
26 Yun J, Bae M S, Baek J S, et al. Nanomaterials, 2023, 13(1), 45.
27 Song P S, Li Y Q, Zhu T H, et al. Steel Research International, 2022, 94(21), 2200684.
28 Li Q P. Mechanism of intragranular ferrite precipitation induced by controllable inclusions. Master’s Thesis, North China University of Science and Technology, China, 2021 (in Chinese).
李秋平. 利用可控夹杂物诱发晶内铁素体析出机理. 硕士学位论文, 华北理工大学, 2021.
29 Koike K, Hama K, Nakashima I, et al. Japanese Journal of Applied Physics, 2004, 43(10B), 1372.
30 Sasa S, Hayafuji T, Kawasaki M, et al. Physica Status Solidi, 2008, 5, 115.
31 Tumbull D, Vonnegut B. Industrial & Engineering Chemistry, 1952, 44(6), 1292.
32 Bramfitt B L. Metallurgical Transactions, 1970, 1 (7), 1987.
33 Pan N, Song B X, Zhai Q J, et al. Chinese Journal of Engineering, 2010, 32(2), 179.
34 Meng F L, Tian S G, Wang M G, et al. Chinese Journal of Materials Research, 2007, 12(3), 225 (in Chinese).
孟凡来, 田素贵, 王明罡, 等. 材料研究学报, 2007, 12(3), 225.
35 Ru Q, Qiu X L. Materials Research and Application, 2009, 3(3), 162 (in Chinese).
汝强, 邱秀丽. 材料研究与应用, 2009, 3(3), 162.
36 Ou Y J. Preparation and properties of zirconia-based functional materials. Master’s Thesis, Central South University, China, 2012 (in Chinese).
欧阳静. 氧化锆基功能材料的制备与性能研究. 硕士学位论文, 中南大学, 2012.
37 Tian L P, Xue Q H, Ren W K. Journal of Synthetic Crystals, 2017, 46(2), 368.
田利萍, 薛群虎, 任伟康. 人工晶体学报, 2017, 46(2), 368.
38 Li M L. Theoretical study on the physical properties of magnesium aluminate spinel and other materials. Master’s Thesis, Northeastern University, China, 2011 (in Chinese).
李美玲. 镁铝尖晶石等材料物性的理论研究. 硕士学位论文, 东北大学, 2011.
39 Sawada H. Materials Research Bulletin, 1995, 30(3), 341.
40 Zhang J H, Preparation, growth mechanism of mullite whiskers and its application in ceramic toughening. Master’s Thesis, China University of Geosciences, China, 2012(in Chinese).
张锦化. 莫来石晶须的制备、生长机理及其在陶瓷增韧中的应用. 硕士学位论文, 中国地质大学, 2012.

[1]	田威, 云伟, 党可欣, 李腾. 不同钙源EICP溶液改良路基黄土动力特性研究[J]. 材料导报, 2024, 38(9): 22110275-9.
[2]	王子健, 孙舒蕾, 肖寒, 冉旭东, 陈强, 黄树海, 赵耀邦, 周利, 黄永宪. 搅拌摩擦固相沉积增材制造研究现状[J]. 材料导报, 2024, 38(9): 22100039-16.
[3]	杨晨光, 王秀峰. 硅基SiC薄膜制备与应用研究进展[J]. 材料导报, 2024, 38(7): 23010118-14.
[4]	黄留飞, 王小英, 孙耀宁, 陈亮, 王龙, 任聪聪, 杨晓珊, 王斗, 李晋锋. 激光熔化沉积Al_xCoCrFeNi系高熵合金的组织与性能[J]. 材料导报, 2024, 38(6): 22090238-6.
[5]	安博星, 王雅洁, 肖永厚, 楚飞鸿. 液态前驱体化学气相沉积法生长单层二硒化钨[J]. 材料导报, 2024, 38(24): 23120071-6.
[6]	邢欢欢, 胡萍, 罗政, 毛丽秋, 盛丽萍, 王珊珊. 低对称性二维层状过渡金属硫族化合物合金及异质结的化学气相沉积法制备研究进展[J]. 材料导报, 2024, 38(24): 23100004-13.
[7]	赵波, 柳俊. 原子层/分子层沉积技术及其在半导体先进工艺中的应用[J]. 材料导报, 2024, 38(20): 23030081-12.
[8]	苗立国, 邢飞, 史建军, 柴媛欣, 闫成鑫, 卞宏友, 孙海江. 基于边缘梯度搜索的激光定向能量沉积熔池尺寸提取方法[J]. 材料导报, 2024, 38(2): 22070278-7.
[9]	王婷, 胡斌, 王文琴, 王非凡. 微弧火花沉积Zr基非晶涂层的组织及性能[J]. 材料导报, 2024, 38(16): 22090308-6.
[10]	吴世伟, 杨雨萌, 段雪佳, 蓝世锋, 李舒铭, 朱本峰, 卫国英. Ni-CeO₂黑色防护镀层的光助动电位沉积及光热性能[J]. 材料导报, 2024, 38(14): 23030220-9.
[11]	王云鹏, 刘宇宁, 王同波, 张嘉凝, 莫永达, 娄花芬. 铜箔衬底对化学气相沉积法制备石墨烯的影响[J]. 材料导报, 2024, 38(13): 22110222-5.
[12]	朱杰, 凌敏, 马润东, 王瑞芬, 安胜利. 高活性BiOI/g-C₃N₄光催化剂的合成及性能提高机制[J]. 材料导报, 2024, 38(11): 23010115-7.
[13]	姜波, 焦欢, 郭新宇, 金永灿. 木质素熔融沉积式3D打印的分子结构-流变学响应关系研究进展[J]. 材料导报, 2024, 38(11): 22100182-8.
[14]	肖瑶, 邓华锋, 李建林, 熊雨, 程雷. 利用Triton X-100提升巴氏芽孢杆菌脲酶活性的效果[J]. 材料导报, 2024, 38(1): 23060069-7.
[15]	范舒瑜, 匡同春, 林松盛, 代明江. WC-Co硬质合金/CVD金刚石涂层刀具研究现状[J]. 材料导报, 2023, 37(8): 21110003-10.

[1]	Yanzhen WANG, Mingming CHEN, Chengyang WANG. Preparation and Electrochemical Properties Characterization of High-rate SiO₂/C Composite Materials[J]. Materials Reports, 2018, 32(3): 357 -361 .
[2]	Yimeng XIA, Shuai WU, Feng TAN, Wei LI, Qingmao WEI, Chungang MIN, Xikun YANG. Effect of Anionic Groups of Cobalt Salt on the Electrocatalytic Activity of Co-N-C Catalysts[J]. Materials Reports, 2018, 32(3): 362 -367 .
[3]	Qingshun GUAN,Jian LI,Ruyuan SONG,Zhaoyang XU,Weibing WU,Yi JING,Hongqi DAI,Guigan FANG. A Survey on Preparation and Application of Aerogels Based on Nanomaterials[J]. Materials Reports, 2018, 32(3): 384 -390 .
[4]	Lijing YANG,Zhengxian LI,Chunliang HUANG,Pei WANG,Jianhua YAO. Producing Hard Material Coatings by Laser-assisted Cold Spray:a Technological Review[J]. Materials Reports, 2018, 32(3): 412 -417 .
[5]	Zhiqiang QIAN,Zhijian WU,Shidong WANG,Huifang ZHANG,Haining LIU,Xiushen YE,Quan LI. Research Progress in Preparation of Superhydrophobic Coatings on Magnesium Alloys and Its Application[J]. Materials Reports, 2018, 32(1): 102 -109 .
[6]	Wen XI,Zheng CHEN,Shi HU. Research Progress of Deformation Induced Localized Solid-state Amorphization in Nanocrystalline Materials[J]. Materials Reports, 2018, 32(1): 116 -121 .
[7]	Xing LIANG, Guohua GAO, Guangming WU. Research Development of Vanadium Oxide Serving as Cathode Materials for Lithium Ion Batteries[J]. Materials Reports, 2018, 32(1): 12 -33 .
[8]	Hao ZHANG,Yongde HUANG,Yue GUO,Qingsong LU. Technological and Process Advances in Robotic Friction Stir Welding[J]. Materials Reports, 2018, 32(1): 128 -134 .
[9]	Laima LUO, Mengyao XU, Xiang ZAN, Xiaoyong ZHU, Ping LI, Jigui CHENG, Yucheng WU. Progress in Irradiation Damage of Tungsten and Tungsten AlloysUnder Different Irradiation Particles[J]. Materials Reports, 2018, 32(1): 41 -46 .
[10]	Fengsen MA,Yan YU,Jie ZHANG,Haibo CHEN. A State-of-the-art Review of Cytotoxicity Evaluation of Biomaterials[J]. Materials Reports, 2018, 32(1): 76 -85 .

Viewed

Full text

Abstract

Cited

Shared

Discussed