Research and Application of Phase Change Composite Nanofibers
SUN Zongxu1, ZHANG Huanzhi1,2,*, JING Rui1, WU Bojing1, XU Fen1,2, XIA Yongpeng1,2, SUN Lixian1,2,*
1 School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, Guangxi, China 2 Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin 541004, Guangxi,China
Abstract: Organic phase change materials(PCMs) are considered to be ideal thermal energy-storage materials due to their high energy-storage capacity, good compatibility and low cost. And polymer nanofibers display broad prospect for applications in textiles, energy sources and so on, because of their advantages of large specific surface area, regulated diameter and good flexibility. Therefore, organic PCMs and polymer nanofibers are combined to fabricate phase-change composite nanofibers with good structural-stability through various composite technologies. The composite nanofibers show potential applications in smart temperature-controlling clothing, medical care, and flexible wearable devices. In order to comprehensively utilize the advantages of PCMs and nanofibers, and solve the leakage problem of organic PCMs in composite nanofibers, encapsulation technology of PCMs (including physical mixing method, graft co-polymerization method and nano-confinement techno-logy) and preparation methods of composite nanofibers (including hollow fiber filling method, coating method, composite spinning method and microcapsule hybrid spinning method) are compared and analyzed. Among them, the nano-constraint technology shows a variety of encapsulation types and excellent encapsulation effects. The composite spinning method has a good advantage in fiber size controllability, while the microcapsules included spinning method is quite agile for nanofibers preparation. Most researches further introduce thermally conductive fillers into fiber matrix to overcome the low thermal conductivity of phase change composite nanofibers. The fillers form an interconnected thermally conductive path in the composite material to improve the overall thermal conductivity. In addition, the application of phase-change composite nanofibers in flexible wearable devices and drugs’ delivery and controlled release is further introduced according with the frontier information of science and technology, and the expansion of its application fields is proposed. In a word, this article summarizes the characteristics and preparation methods of phase change composite nanofibers, and it is pointed out that composite spinning method can solve the problem of leakage of phase change materials to some extent at the same time. And we clarify the research progress and shortcomings of the method to improve the low thermal conductivity of phase change composite nanofibers by adding high thermal conductivity fillers. We also have focused on the applications of phase change composite nanofibers in flexible wearable devices and drugs’ delivery and controlled release. At last, we prospect the research direction of the phase-change composite nanofibers. This review provides a reference for the preparation, exploration and application of new phase-change composite nanofibers.
1 Lu L, Cao X Q, Shen Z Y, et al. Sustainable Materials and Technologies, 2020, 26, e00221. 2 Wang Y, Yuan A Q, Zhao Y Y, et al. Journal of Applied Polymer Science, 2019, 137(13), 48497. 3 Xia Y P, Cui W W, Zhang H Z, et al. Modern Chemical Industry, 2017, 37(6), 15 (in Chinese). 夏永鹏, 崔韦唯, 张焕芝, 等. 现代化工, 2017, 37(6), 15. 4 Wang X, Fang J H, Liu P, et al. Journal of Functional Materials, 2019, 50(2), 2070 (in Chinese). 王鑫, 方建华, 刘坪, 等. 功能材料, 2019, 50(2), 2070. 5 Khajavi R, Abbasipourb M. Scientia Iranica F, 2012, 19 (6), 2029. 6 Li L, Zhang X, Qu Y, et al. Materials Reports, 2019, 33(Z1), 89 (in Chinese). 李霖, 张旭, 曲飏, 等. 材料导报, 2019, 33(Z1), 89. 7 Liu Z, Ju K Y, Wang Z Q, et al. Nanoscale Research Letters, 2019, 14, 310. 8 Ding H, Lei X, Wang Y L, et al. Liaoning Silk, 2018(3), 36 (in Chinese). 丁洪, 雷雪, 王祎隆, 等. 辽宁丝绸, 2018(3), 36. 9 Xia X, Xie T T. Materials Review, 2016, 30(27), 87 (in Chinese). 夏鑫, 谢婷婷. 材料导报, 2016, 30(27), 87. 10 Graham M, Coca-Clemente J A, Shchukina E, et al. Journal of Materials Chemistry A, 2017, 5(26), 13683. 11 Huang X, Xia W, Zou R. Journal of Materials Chemistry A, 2014, 2(47), 19963. 12 Xia Y P, Zhang H Z, Huang P R, et al. Chemical Engineering Journal, 2019, 362, 909. 13 Hyun D C, Levinson N S, Jeong U, et al. Angewandte Chemie International Edition, 2014, 53(15), 3780. 14 Uemura T, Yanai N, Watanabe S, et al. Nature Commun, 2010, 1(7), 1. 15 Liu C, Rao Z, Zhao J, et al. Nano Energy, 2015, 13, 814. 16 Adeel A, Mark J, Yan Y Y, et al. International Journal of Energy Research, 2019, 43(11), 5572. 17 Aftab W, Huang X, Wu W, et al. Energy and Environmental Science. 2018, 11(6), 1392. 18 Zou Y H, Ke H Z, Xiao G G, et al. Polymer Materials Science and Engineering, 2018, 34(12), 59 (in Chinese). 邹雨航, 柯惠珍, 肖港归, 等. 高分子材料科学与工程, 2018, 34(12), 59. 19 Wang S D, He Y F, Liu H, et al. Textile Industry and Technology, 2014, 2(1), 26 (in Chinese). 王曙东, 何远方, 刘华, 等. 轻纺工业与技术, 2014, 2(1), 26. 20 Ke H Z, Li Y G. Polymer Materials Science and Engineering, 2017, 33(4), 81 (in Chinese). 柯惠珍, 李永贵. 高分子材料科学与工程, 2017, 33(4), 81. 21 Sun D B. Melliand China, 2013(8), 10 (in Chinese). 苏德保. 国际纺织导报, 2013(8), 10. 22 Onder E, Sarier N, Cimena E. Thermochimica Acta, 2008, 467, 63. 23 Wang X, Fang J H, Jiang Z Q, et al. Synthetic Fiber in China, 2018, 47(8), 10 (in Chinese). 王鑫, 方建华, 江泽琦, 等. 合成纤维, 2018, 47(8), 10. 24 Faerevik H, Gersching D, Hagstr B. Melliand China, 2013(11), 11 (in Chinese). Faerevik H, Gersching D, Hagstr B. 国际纺织导报, 2013(11), 11. 25 Zhao X J, Yu M. Journal of Functional Materials, 2022, 53(4), 4039(in Chinese). 赵肖娟, 于嫚. 功能材料, 2022, 53(4), 4039. 26 Li J J, Lu Y C, Ye G D, et al. Acta Materiae Compsetae Sinica, 2012, 29(3), 79 (in Chinese). 李佳佳, 陆艺超, 叶光斗, 等. 复合材料学报, 2012, 29(3), 79. 27 Li Z, Ye G D, Xu J J, et al. Synthetic Fiber in China, 2015, 44(7), 14 (in Chinese). 李昭, 叶光斗, 徐建军, 等. 合成纤维, 2015, 44(7), 14. 28 Zhang H, Wang Q Q, Xiang H X. China Synthetic Fiber Industry, 2011, 34(3), 39 (in Chinese). 张鸿, 王倩倩, 相恒学. 合成纤维工业, 2011, 34(3), 39. 29 Hua J B, Zou L M, Ni J H, et al. China Synthetic Fiber Industry, 2016, 39(6), 11 (in Chinese). 花建兵, 邹黎明, 倪建华, 等. 合成纤维工业, 2016, 39(6), 11. 30 Zhang H, Liu H, Yang S R, et al. China Synthetic Fiber Industry, 2012, 35(3), 10 (in Chinese). 张鸿, 刘辉, 杨淑瑞, 等. 合成纤维工业, 2012, 35(3), 10. 31 Fang J, Niu H T, Lin T, et al. Chinese Science Bulletin, 2008, 53(15), 2265. 32 Subbiah T, Bhat G S, Tock R W, et al. Journal of Applied Polymer Science, 2005, 96(2), 557. 33 Greiner A, Wendorff J H. Angewandte Chemie International Edition, 2007, 46(30), 5670. 34 Xia C L. Synthetic Fiber in China, 2019, 48(8), 19 (in Chinese). 夏长林. 合成纤维, 2019, 48(8), 19. 35 Zhang S M, Hao Y G, Hu K, et al. Guangzhou Chemical Industry, 2015, 43(24), 72 (in Chinese). 张凇铭, 郝勇敢, 胡凯, 等. 广州化工, 2015, 43(24), 72. 36 Zhu W T, Wang Y Q, Song S K, et al. Solar Energy Materials and Solar Cells, 2021, 222, 1110939. 37 Sun S X, Xie R, Ju X J, et al. New Chemical Materials, 2016, 44(8), 59 (in Chinese). 孙少兴, 谢锐, 巨晓洁, 等. 化工新型材料, 2016, 44(8), 59. 38 Cai L H, Zhang X X. Materials Review, 2002, 16(12), 61 (in Chinese). 蔡利海, 张兴祥. 材料导报, 2002, 16(12), 61. 39 Wang G X, Ding N, Qiu G X, et al. China Plastic Industry, 2019, 47(2), 147 (in Chinese). 王固霞, 丁娜, 丘管先, 等. 塑料工业, 2019, 47(2), 147. 40 Kong L X, Wei C Y. Cotton Textile Technology, 2020, 48(7), 7 (in Chinese). 孔令训, 魏春艳. 棉纺织技术, 2020, 48(7), 7. 41 Yu H F, Wei J, Liu L, et al. Journal of Dalian Polytechnic University, 2012, 31(3), 215 (in Chinese). 于海飞, 魏菊, 刘玲, 等. 大连工业大学学报, 2012, 31(3), 215. 42 Kibria M A, Anisur M R, Mahfuz M H, et al. Energy Conversion and Management, 2015, 95, 69. 43 Zhao J Q, Meng F C, Shen J B, et al. Chemical Industry and Engineering, 2020, 37(3), 67 (in Chinese). 赵敬棋, 孟凡成, 申景博, 等. 化学工业与工程, 2020, 37(3), 67. 44 Wang D W, Yu R S, Yan H, et al. Materials Reports, 2014, 28(12), 70 (in Chinese). 王大伟, 余荣升, 晏华, 等. 材料导报, 2014, 28(12), 70. 45 Yang L, Zhang L, Li C Z. Composites Science and Technology, 2020, 200, 108429. 46 Guo Y Q, Yang X T, Ruan K P, et al. ACS Applied Materials & Interfaces, 2019, 11, 25465. 47 Wen G Q, Xie R, Ju X J, et al. Chemical Industry and Engineering Progress, 2015, 34(10), 3688 (in Chinese). 温国清, 谢锐, 巨晓洁, 等. 化工进展, 2015, 34(10), 3688. 48 Zhang X, Xie R, Wang W, et al. Chemical Industry and Engineering Progress, 2019, 38(2), 993 (in Chinese). 张秀, 谢锐, 汪伟, 等. 化工进展, 2019, 38(2), 993. 49 Fang L L, He H Z, Zhai M, et al. Journal of Materials Science and Engineering, 2020, 38(2), 325 (in Chinese). 方丽莉, 柯惠珍, 翟敏, 等. 材料科学与工程学报, 2020, 38(2), 325. 50 Zhao Y X, Chen Y J, Pan G X, et al. Chemical Journal of Chinese Universities, 2019, 40(4), 824 (in Chinese). 赵宇轩, 陈艳君, 潘顾鑫, 等. 高等学校化学学报, 2019, 40(4), 824. 51 Wan Y F, Zhou P C, Liu Y D, et al. RSC Advances, 2016, 6, 21204. 52 Niu Z X, Yuan W Z. ACS Applied Materials Interfaces, 2021, 13, 4508. 53 Zhu C L, Huo D, Chen Q S, et al. Advanced Materials, 2017, 29(40), 1703702. 54 Xue J J, Zhu C L, Li J H, et al. Advanced Functional Materials, 2018, 28(15), 1705563. 55 Qiu J C, Huo D, Xia Y N. Advanced Materials, 2020, 32(25), 2000660. 56 Qiu J C, Xu J C, Xia Y N. Advanced Healthcare Materials, 2020, 10(4), 2000587. 57 Xue J J, Wu T, Qiu J C, et al. Small Methods, 2020, 4(9), 2000125.
渝公网安备50019002502923号 版权所有：《材料导报》编辑部
2023, Vol. 37 
