氧化石墨烯/金属-有机框架复合材料在光催化中的应用

材料导报

2021, Vol. 35

Issue (Z1): 315-321

金属与金属基复合材料

氧化石墨烯/金属-有机框架复合材料在光催化中的应用

朱家乐^1,2, 白羽婷¹, 冯思思¹

1 山西大学分子科学研究所,太原 030006
2 山西大学化学化工学院,太原 030006

Applications of Graphene Oxide/Metal-Organic Framework Composites in Photocatalysis

ZHU Jiale^1,2, BAI Yuting¹, FENG Sisi¹

1 Institute of Molecular Science, Shanxi University, Taiyuan 030006, China
2 School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006,China

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摘要光催化因其绿色安全、环境友好、成本低廉等优势,被认为是解决当前世界范围内环境问题和能源危机的有效方法。光催化技术的核心之一是光催化材料的研发,制备光催化活性高、组成稳定、可回收再利用的光催化剂是许多研究者的共同追求。
近年来,金属-有机框架(MOFs)作为一类新型光催化材料已被广泛关注,但是由于结构不稳定、容易聚集、光生电子空穴对极易复合等缺点,其光催化效果受到严重影响,限制了MOFs在实际生产生活中的应用。因此,找到一种简便实用的方法来改善MOFs的光催化性能具有十分重要的意义。
经实验证实,将氧化石墨烯(GO)与MOFs复合是有效方法之一。GO表面丰富的含氧基团使其易与MOFs复合,GO稳定的二维平面结构能增强MOFs的结构稳定性,同时GO极强的亲水能力还使MOFs容易分散在溶剂中。此外,更值得一提的是GO/MOF复合材料的电子-空穴复合速率得到有效降低,相比于母体组分其光催化活性显著提升。该方法易于操作、成本低廉,且对多种MOFs都有较好的适用性。
本文综述了GO/MOF复合材料的最新进展,重点介绍了此类复合材料作为光催化剂在去除环境污染物中的应用,包括去除气态污染物、还原重金属离子、降解抗生素类药物、降解有机染料和降解其他有机污染物等方面。最后对GO/MOF复合材料未来的发展趋势作出预测,以期推动MOFs新型复合材料应用于环境修复。

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	朱家乐
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关键词: 氧化石墨烯金属-有机框架复合材料光催化环境修复

Abstract: Photocatalysis is considered as an effective method to solve currently environmental problems and energy crises around the world due to its advantages of safe, environment-friendly, and inexpensive. Research and development of photocatalytic materials are critical for photocatalysis, and it is the common pursuit of many researchers to prepare photocatalytic catalysts with high photocatalytic activity, stable composition, and excellent recyclability.
In recent years, metal-organic frameworks (MOFs), as a new kind of photocatalytic materials, have been widely concerned. However, due to their disadvantages such as the unstable structure, the tendency to cluster, and the easy combination of photogenerated electron-hole pairs, their photocatalytic performances have been seriously affected, which limits the applications of MOFs in actual production and life. Therefore, it is of great significance to find a simple and practical method to improve the photocatalytic performance of MOFs.
It has been verified that the combination of graphene oxide (GO) and MOFs is one of the effective methods. The abundant oxygenic functional groups on the surface of GO can facilitate the hybridization of GO with MOFs. The stable two-dimensional planar structure of GO can enhance the structural stability of MOFs. Meanwhile, the extremely strong hydrophilic ability of GO can also make MOFs easy to disperse in the solvent. In addition, it is worth mentioning that the recombination rate of the photogenerated electron-hole pairs of GO/MOF composites is efficiently reduced, and their photocatalytic performance can be significantly improved compared with that of the parent component. Moreover, the technique is easy to operate and low in cost, and it has good applicability to a variety of MOFs.
In this paper, the recent progress of GO/MOF composites is reviewed, and the application of the composites as photocatalysts in the removal of environmental pollutants is highlighted, including removal of gaseous pollutants, reduction of heavy metal ions, degradation of antibiotic drugs, degradation of organic dyes and other organic pollutants. Finally, future perspectives on the development and application of GO/MOF composites for pollution remediation are presented.

Key words: graphene oxide metal-organic frameworks composites photocatalysis environmental remediation

发布日期: 2021-07-16

ZTFLH:

TB34

基金资助: 山西省自然科学基金(201701D121039)

通讯作者: ssfeng@sxu.edu.cn

作者简介: 朱家乐,化学专业,2020年7月毕业于山西大学,获得理学学士学位。冯思思,教授,硕士研究生导师。2008年7月毕业于山西大学,获理学博士学位,同年加入山西大学分子科学研究所工作至今,主要从事多功能金属-有机杂化材料的制备及性质研究,作为访问学者先后赴南开大学(2012—2013)和美国南佛罗里达大学(2018—2019)访学。主持并完成国家自然科学青年基金、高等学校博士学科点专项科研基金、以及山西省自然科学基金等项目,已发表SCI论文50余篇,授权国家发明专利13项。

引用本文:

朱家乐, 白羽婷, 冯思思. 氧化石墨烯/金属-有机框架复合材料在光催化中的应用[J]. 材料导报, 2021, 35(Z1): 315-321.
ZHU Jiale, BAI Yuting, FENG Sisi. Applications of Graphene Oxide/Metal-Organic Framework Composites in Photocatalysis. Materials Reports, 2021, 35(Z1): 315-321.

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http://www.mater-rep.com/CN/ 或 http://www.mater-rep.com/CN/Y2021/V35/IZ1/315

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