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材料导报  2019, Vol. 33 Issue (18): 3016-3020    https://doi.org/10.11896/cldb.18080015
  无机非金属及其复合材料 |
铋掺杂二氧化锡/炭膜电催化膜的制备及表征
王鹏飞1, 2, 邓宇1, 郝丽梅2, 邓橙2, 赵蕾2, 张新奇2, 朱孟府2,
1 天津科技大学化工与材料学院,天津 300457
2 军事科学院卫勤保障技术研究所,天津 300161
Preparation and Characterization of Bi-SnO2/Carbon Membrane Electrocatalytic Membrane
WANG Pengfei1,2, DENG Yu1, HAO Limei2, DENG Cheng2, ZHAO Lei2, ZHANG Xinqi2, ZHU Mengfu2
1 College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457
2 Institute of Medical Support Technology, Academy of Military Science of Chinese PLA, Tianjin 300161
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摘要 采用电还原-水热法,以炭膜为基膜制备Bi掺杂的SnO2(Bi-SnO2/CM)电催化膜,并采用SEM、XRD、线性伏安法(LSV)、循环伏安法(CV)等表征手段对电催化膜的组成结构及性能进行分析。研究结果表明,Bi-SnO2通过化学键与炭膜紧密结合,可以增加电催化膜的活性位点数量,使电催化膜对大肠杆菌表现出优异的去除性能。当Bi与Sn的物质的量比为0.15,电还原时间为60 min,电流为0.2 mA时,制得的电催化膜的析氧电势达到1.74 V,电化学腐蚀时间可以达到44.5 h,且连续运行5 h后对大肠杆菌的去除率仍高于96.1%。这表明Bi-SnO2/CM电催化膜在水中污染去除方面具有很好的应用前景。
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王鹏飞
邓宇
郝丽梅
邓橙
赵蕾
张新奇
朱孟府
关键词:  Bi-SnO2/CM  电催化膜  大肠杆菌  电催化氧化  析氧电势    
Abstract: The Bi-SnO2/CM electrocatalytic membrane of Bi-doped SnO2 was prepared by electrothermal reduction-hydrothermal oxidation method using carbon membrane as the substrate membrane. The structure and properties of the electrocatalytic membrane were characterized by XRS, LSV and CV. The removal performance of the electrocatalytic membrane was evaluated by the removal rate of E. coli. The results show that Bi-SnO2 can increase the active site of the electrocatalytic membrane. When the molar ratio of Bi/Sn is 0.15, the redox time is 60 min, and the current is 0.2 mA, the performance of the prepared electrocatalytic membrane is the best, the oxygen evolution potential reaches 1.74 V, the electrochemical corrosion time can reach 44.5 h, and the continuous treatment is 5 h. The removal rate of E. coli is still more than 96.1%. The chemical bond with the carbon membrane is combined with the carbon membrane. In addition, the electrocatalytic membrane treatment of E. coli shows superior removal performance. It is indicated that Bi-SnO2/CM electrocatalytic membrane has a good application prospect in wastewater treatment.
Key words:  Bi-SnO2/carbon membrane    electrocatalytic membrane    E. coli    electrocatalytic oxidation    oxygen evolution potential
               出版日期:  2019-09-25      发布日期:  2019-07-31
ZTFLH:  TQ150.7  
基金资助: 国家自然科学基金(51878659); 军事医学创新工程专项(16CXZ037)
作者简介:  王鹏飞,出生于1993年,男,山西,硕士研究生,就读于天津科技大学化工与材料学院,化学工程专业,研究方向为功能材料。
朱孟府,军事科学院卫勤保障技术研究所研究员、博士、博士生导师。主要从事分离工程技术与装备研究,特别是分离膜材料的研究,近年来主持及参加国家、军队及天津市重大重点项目多项,获军队及天津市科技进步奖10项,发表研究论文60余篇,获国家专利10多项,担任多个学术期刊编委和学术组织委员,以及国家、军队和天津市科技计划和科技成果评审专家,获全国优秀科技工作者。
引用本文:    
王鹏飞, 邓宇, 郝丽梅, 邓橙, 赵蕾, 张新奇, 朱孟府. 铋掺杂二氧化锡/炭膜电催化膜的制备及表征[J]. 材料导报, 2019, 33(18): 3016-3020.
WANG Pengfei, DENG Yu, HAO Limei, DENG Cheng, ZHAO Lei, ZHANG Xinqi, ZHU Mengfu. Preparation and Characterization of Bi-SnO2/Carbon Membrane Electrocatalytic Membrane. Materials Reports, 2019, 33(18): 3016-3020.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.18080015  或          http://www.mater-rep.com/CN/Y2019/V33/I18/3016
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