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材料导报  2019, Vol. 33 Issue (z1): 499-504    
  高分子与聚合物基复合材料 |
无机纳米粒子协同无卤阻燃聚丙烯的研究进展
罗继永1,2, 张道海1,2, 田琴1,2, 魏柯1,2, 周密1,2, 杨胜都1
1 贵州大学材料与冶金学院,贵阳 550025
2 国家复合改性聚合物材料工程技术中心,贵阳 550014
Research Progress of Inorganic Nanoparticles Synergistic Halogen-free Flame Retardant Polypropylene
LUO Jiyong1,2, ZHANG Daohai1,2, TIAN Qin1,2, WEI Ke1,2, ZHOU Mi1,2, YANG Shengdu1
1 College of Material and Metallurgy , Guizhou University, Guiyang 550025
2 National Engineering Research Center for Compounding and Modification of Polymeric Materials, Guiyang 550014
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摘要 卤系阻燃剂对生态环境和人体健康有较大的危害,因此绿色环保的无卤阻燃剂得到了较为快速的发展。无卤阻燃剂主要包括无机阻燃剂、有机硅阻燃剂和无卤膨胀型阻燃剂等。用于聚丙烯无卤阻燃的主要有铝、镁等无机金属化合物类阻燃剂,以及利用聚磷酸铵为主体复配而成的一类无卤膨胀型阻燃剂。卤系阻燃剂存在阻燃效果低、添加量大等缺陷,严重损害基体的力学性能,而添加某些无机纳米粒子可在一定程度上提升其阻燃效果。
本文围绕无机纳米粒子与聚丙烯这两大类阻燃剂的阻燃协同效应,概述了改善无机纳米粒子与聚丙烯基体分散性的表面改性方法,并阐述了无机纳米粒子协同阻燃聚丙烯的机理与发展现状。主要介绍了蒙脱土、海泡石、碳基填料等无机纳米粒子协同聚丙烯无卤阻燃复合材料的研究进展,并展望了无机纳米粒子无卤阻燃剂填充改性阻燃聚丙烯的发展趋势。
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罗继永
张道海
田琴
魏柯
周密
杨胜都
关键词:  无机纳米粒子  聚丙烯  协同效应  无卤阻燃  复合材料    
Abstract: The use of halogen-based flame retardants has caused great damage to the ecological environment and human health, so the green halogen-free flame retardant has developed rapidly. Halogen-free flame retardants mainly include inorganic flame retardants, silicone flame retardants and halogen-free intumescent flame retardants. The halogen-free flame retardant for polypropylene mainly includes inorganic metal compound flame retardants such as aluminum and magnesium, and a type of halogen-free intumescent flame retardant which is compounded by ammonium polyphosphate. However, the flame retardant effect of the halogen-based flame retardant is low, and the addition amount and the like seriously impair the mechanical properties of the matrix. The addition of certain inorganic nanoparticles can enhance the flame retardant effect to some extent.
This paper summarizes the improvement of the dispersion of inorganic nanoparticles and polypropylene matrix by the flame retardant synergistic effect of inorganic nanoparticles and polypropylene. The surface modification method and the synergistic mechanism and development status of the inorganic nanoparticle flame retardant polypropylene. It mainly introduces the non-halogen flame retardant of inorganic nanoparticle synergistic polypropylene such as montmorillonite, sepiolite, and carbon-based filler. The research progress of composite materials and the development trend of inorganic nanoparticle halogen-free flame retardant filled modified flame retardant polypropylene
Key words:  inorganic nanoparticles    polypropylene    synergistic effect    halogen-free flame retardant    composite
               出版日期:  2019-05-25      发布日期:  2019-07-05
ZTFLH:  TQ314.24  
基金资助: 贵州省科技计划项目(黔科合人才 [2016]5630;黔科合平台人才[2017]5623;黔科合基础[2017]1091;黔科合成果[2016]2812、[2019]4022;黔科合支撑[2018]1012);贵阳市白云区科技计划项目(白科合同[2017]65)
作者简介:  罗继永,毕业于贵州大学,现为贵州大学材料与冶金学院研究生,现在从事高性能复合材料研发及应用。张道海,研究员,贵州大学材料学博士,现从事高性能复合材料的开发及应用。先后在国内外学术刊物上发表学术论文100余篇,申请专利50余件,已授权30余件。zhangdaohai6235@163.com
引用本文:    
罗继永, 张道海, 田琴, 魏柯, 周密, 杨胜都. 无机纳米粒子协同无卤阻燃聚丙烯的研究进展[J]. 材料导报, 2019, 33(z1): 499-504.
LUO Jiyong, ZHANG Daohai, TIAN Qin, WEI Ke, ZHOU Mi, YANG Shengdu. Research Progress of Inorganic Nanoparticles Synergistic Halogen-free Flame Retardant Polypropylene. Materials Reports, 2019, 33(z1): 499-504.
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http://www.mater-rep.com/CN/  或          http://www.mater-rep.com/CN/Y2019/V33/Iz1/499
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