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《材料导报》期刊社  2017, Vol. 31 Issue (8): 51-55    https://doi.org/10.11896/j.issn.1005-023X.2017.08.011
  材料研究 |
海洋硫酸盐还原菌对Q235钢腐蚀行为的影响*
谢飞1, 王丹1, 吴明1, 宗月1, 袁世娇1, 申红娟1, 李睿2
1 辽宁石油化工大学石油天然气工程学院, 抚顺 113001;
2 中石油辽宁抚顺销售分公司, 抚顺 113006
Effect of Sulfate Reducing Bacteria in Seawater on Corrosion Behavior of Q235 Steel
XIE Fei1, WANG Dan1, WU Ming1, ZONG Yue1, YUAN Shijiao1, SHEN Hongjuan1, LI Rui2
1 College of Petroleum Engineering, Liaoning Shihua University, Fushun 113001;
2 Petro China Liaoning Fushun Oil Marketing Company, Fushun 113006
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摘要 采用失重法、开路电位、电化学阻抗谱(EIS)、极化曲线等方法,通过在海洋环境中浸泡不同时间对比分析有无硫酸盐还原菌(SRB)条件下Q235钢的腐蚀电化学特征,研究SRB对Q235钢的腐蚀行为的影响。结果表明,在含SRB的海水中,随着浸泡时间延长,Q235钢的腐蚀电流密度先从7.49 mA·cm-2增加至9.77 mA·cm-2,然后逐渐减小至5.01 mA·cm-2,最终增加至12.6 mA·cm-2,且始终小于相同时间下无SRB海水中的腐蚀电流密度,表明SRB的存在抑制了Q235的腐蚀。在含SRB的海水中,Q235钢的腐蚀行为主要由Cl-和生物膜共同影响。在SRB稳定生长阶段,腐蚀以生物膜抑制为主;在SRB指数生长阶段和衰亡阶段,生物膜抑制作用较弱,以Cl-促进金属腐蚀为主。
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谢飞
王丹
吴明
宗月
袁世娇
申红娟
李睿
关键词:  Q235钢  海水  微生物腐蚀  硫酸盐还原菌  极化曲线    
Abstract: A comparative study focused on corrosion behavior of Q235 steel in seawater with the absence and presence of sulfate reducing bacteria (SRB) was carried out by using mass loss method, electrode open-circuit potential, electrochemical impedance spectroscopy (EIS) and polarization testing. The results showed that the corrosion current density of Q235 steel increased from 7.49 mA·cm-2 to 9.77 mA·cm-2, then gradually reduced to 5.01 mA·cm-2, and eventually increased to 12.6 mA·cm-2 as the immersion time passed in SRB-containing seawater. The corrosion current density of Q235 in SRB-containing seawater was lower than that of Q235 steel in sterile seawater, and the corrosion of Q235 steel was inhibited by SRB. In SRB-containing seawater, the corrosion behavior of Q235 steel was mainly influenced by Cl- and biofilm. During the stable growth stage of SRB, corrosion rate of the metal is mainly suppressed by biofilm. During exponential growth stage and decline stage of SRB, the effect of biofilm on Q235 steel is weak and corrosion rate of the metal is mainly promoted by Cl-.
Key words:  Q235 steel    seawater    microbiologically influenced corrosion    sulfate reducing bacteria (SRB)    polarization curve
               出版日期:  2017-04-25      发布日期:  2018-05-02
ZTFLH:  TG174  
基金资助: 国家自然科学基金(51574147;51604150);辽宁省博士启动资金(201601324);辽宁石油化工大学引进人才科研启动基金(2016XJJ-032)
通讯作者:  王丹:女,1984年生,博士,主要研究方向为微生物腐蚀机理 E-mail:wd841015@163.com   
作者简介:  谢飞:男,1983年生,博士,讲师,主要研究方向为油气管道腐蚀与防护技术 E-mail:370716026@qq.com
引用本文:    
谢飞, 王丹, 吴明, 宗月, 袁世娇, 申红娟, 李睿. 海洋硫酸盐还原菌对Q235钢腐蚀行为的影响*[J]. 《材料导报》期刊社, 2017, 31(8): 51-55.
XIE Fei, WANG Dan, WU Ming, ZONG Yue, YUAN Shijiao, SHEN Hongjuan, LI Rui. Effect of Sulfate Reducing Bacteria in Seawater on Corrosion Behavior of Q235 Steel. Materials Reports, 2017, 31(8): 51-55.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.08.011  或          http://www.mater-rep.com/CN/Y2017/V31/I8/51
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