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《材料导报》期刊社  2017, Vol. 31 Issue (6): 16-20    https://doi.org/10.11896/j.issn.1005-023X.2017.06.004
  材料研究 |
纳米氧化镁表面修饰制备荷正电微孔陶瓷膜及其性能研究
孟仙1, 2, 邓橙2, 朱孟府2, 李奎1, 邓宇1
1 天津科技大学化工与材料学院, 天津 300457;
2 军事医学科学院卫生装备研究所, 天津 300161
Preparation and Performance of Positively Charged Microporous Ceramic
Membrane Modified by Nano-MgO
MENG Xian1,2, DENG Cheng2, ZHU Mengfu2, LI Kui1, DENG Yu1
1 College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457;

2 Institute of Medical Equipment, Academy of Military Medical Sciences, Tianjin 300161
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摘要 以硅藻土陶瓷膜为基膜,氯化镁和尿素为原料合成含镁先驱体溶胶,通过浸渍-热分解法对硅藻土基膜进行表面改性制得纳米MgO/SiO2荷正电微孔陶瓷膜,并对其组成结构及水中四环素去除性能进行研究。结果表明,荷正电的纳米MgO涂层呈现立方型晶粒,并均匀地附着在基膜表面,因此使得荷正电微孔陶瓷膜具有较高的电性能,并且在较宽的pH值范围内带正电,其等电点为10.8。最后对水中四环素的去除性能进行研究,结果表明荷正电微孔陶瓷膜对水中四环素具有很好的去除效果,在室温、常压条件下,其对四环素的COD去除率高达98.8%,色度去除率为99.7%。
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孟仙
邓橙
朱孟府
李奎
邓宇
关键词:  纳米氧化镁  荷正电陶瓷膜  四环素  膜分离    
Abstract: Using diatomite ceramic membrane as base membrane, the nano-MgO/SiO2 microporous ceramic membranes with positive surface charge was prepared by impregnation-thermal decomposition method for surface modification of the base membrane. Composition structure of the positively charged microporous ceramic membrane and removal performance for tetracycline in water were analyzed. Research results showed that the positively charged nano-MgO coating exhibits a cubic crystal and uniformly attached to the base membrane surface, as a result the positively charged microporous ceramic membrane possesses high electrical properties. It behaves positive surface charge within a wide pH range, and its isoelectric point is up to 10.8. Finally, the removal performance of tetracycline confirmed a satisfactory removal effect for tetracycline of the positively charged microporous ceramic membrane, as the COD removal rate and chroma removal rate were 98.8% and 99.7%, respectively at room temperature and under atmospheric pressure.
Key words:  nano-MgO    positively charged ceramic membrane    tetracycline    membrane separation
               出版日期:  2017-03-25      发布日期:  2018-05-02
ZTFLH:  TQ174  
基金资助: 国家自然科学基金(51202292;51478461)
通讯作者:  邓橙:男,1981年生,博士,助理研究员,研究方向为膜分离水处理技术,E-mail:dcnudt@163.com   
作者简介:  孟仙:女,1991年生,硕士研究生,研究方向为微孔陶瓷膜制备及应用,E-mail:mengxian26@126.com
引用本文:    
孟仙, 邓橙, 朱孟府, 李奎, 邓宇. 纳米氧化镁表面修饰制备荷正电微孔陶瓷膜及其性能研究[J]. 《材料导报》期刊社, 2017, 31(6): 16-20.
MENG Xian, DENG Cheng, ZHU Mengfu, LI Kui, DENG Yu. Preparation and Performance of Positively Charged Microporous Ceramic
Membrane Modified by Nano-MgO. Materials Reports, 2017, 31(6): 16-20.
链接本文:  
http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.06.004  或          http://www.mater-rep.com/CN/Y2017/V31/I6/16
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