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《材料导报》期刊社  2017, Vol. 31 Issue (16): 94-97    https://doi.org/10.11896/j.issn.1005-023X.2017.016.019
  材料研究 |
氢气气氛中热处理对Ni-W合金镀层组织和性能的影响*
谢蔚1, 张亚东1, 周琼宇1,2,3, 成祥1, 胡安伟1, 张路1
1 江西理工大学材料科学与工程学院, 赣州 341000;
2 上海大学材料科学与工程学院, 上海 200072;
3 江西省科学院应用物理研究所, 南昌 330029
Effect of Heat Treatment in Hydrogen Atmosphere on Microstructure and Properties of Ni-W Alloy Coating
XIE Wei1, ZHANG Yadong1, ZHOU Qiongyu1,2,3, CHENG Xiang1, HU Anwei1, ZHANG Lu1
1 School of Material Science and Engineering, Jiangxi University of Science and Technology, Ganzhou 341000;
2 College of Material Science and Engineering, Shanghai University, Shanghai 200072;
3 Institute of Applied Physics, Jiangxi Academy of Sciences, Nanchang 330029
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摘要 研究了在氢气气氛中,不同的热处理温度对Ni-W合金镀层表面状态、相结构及显微硬度和耐蚀性的影响。结果表明,镀态的Ni-W合金镀层存在一种未知相(2θ≈41.4°),热处理过程中这一未知相消失,同时镀层中析出NiW、Ni4W等沉淀相。随着热处理温度的升高,镀层的晶粒度逐渐增大,镀层在热处理过程中形成的孔隙逐渐增多。当热处理温度达到1 000 ℃后,镀层表面出现明显的裂纹,同时镀层中可还原形成单质W。Ni-W合金镀层的显微硬度经热处理后显著增大,热处理温度为500 ℃时镀层的显微硬度最大,同时镀层具有与镀态Ni-W合金相近的耐蚀性,热处理温度进一步升高后镀层的耐蚀性降低。
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谢蔚
张亚东
周琼宇
成祥
胡安伟
张路
关键词:  Ni-W合金  镀层  氢气气氛  热处理  显微硬度  耐蚀性    
Abstract: The effect of annealing temperature on the morphology, phase composition, micro-hardness and corrosion resistance of Ni-W coating were investigated. The results show that an unidentified phase(2θ ≈41.4°) was presented in the as-plated Ni-W coating and then disappeared after annealing treatment. Meanwhile, NiW and Ni4W were precipitated in the annealed coating. As the annealing temperature increased, the grain size and porosity of coating gradually increased. Significant cracks were observed and W was found in the Ni-W coating annealed at 1 000 ℃.The micro-hardness of annealed Ni-W coatings were much higher than that of as-deposited coating, while an adverse corrosion performance was observed for the annealed Ni-W coatings. The corrosion resistance became worse with the increasing annealing temperature. The coating annealed at 500 ℃ showed a biggest micro-hardness value and a fairly acceptable corrosion resistance.
Key words:  Ni-W alloy    electrodeposited coating    hydrogen atmosphere    annealing treatment    micro-hardness    corrosion resistance
               出版日期:  2017-08-25      发布日期:  2018-05-07
ZTFLH:  TG147  
基金资助: 国家自然科学基金(51504104);江西省自然科学基金(20151BAB216012;20161BAB206141);江西理工大学博士启动基金(jxxjbs15006)
通讯作者:  周琼宇:通讯作者,男,1986年生,博士,讲师,研究方向为金属腐蚀与防护和材料物理化学 E-mail:zhouzhouqiongyuxf@126.com   
作者简介:  谢蔚:男,1992年生,硕士研究生,研究方向为金属腐蚀与防护 E-mail:214939760@qq.com
引用本文:    
谢蔚, 张亚东, 周琼宇, 成祥, 胡安伟, 张路. 氢气气氛中热处理对Ni-W合金镀层组织和性能的影响*[J]. 《材料导报》期刊社, 2017, 31(16): 94-97.
XIE Wei, ZHANG Yadong, ZHOU Qiongyu, CHENG Xiang, HU Anwei, ZHANG Lu. Effect of Heat Treatment in Hydrogen Atmosphere on Microstructure and Properties of Ni-W Alloy Coating. Materials Reports, 2017, 31(16): 94-97.
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http://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.016.019  或          http://www.mater-rep.com/CN/Y2017/V31/I16/94
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