硒提取与纯化工艺研究进展

doi:10.11896/cldb.22080188

材料导报

2024, Vol. 38

Issue (5): 22080188-14 https://doi.org/10.11896/cldb.22080188

无机非金属及其复合材料

硒提取与纯化工艺研究进展

杨政^1,2,3, 代林晴^1,2,3,*, 张利波^1,2,3, 张辉⁴, 程越^1,2,3, 周亮^1,2,3, 苏文婷^1,2,3

1 昆明理工大学冶金与能源工程学院,昆明 650093
2 昆明理工大学非常规冶金教育部重点实验室,昆明 650093
3 昆明理工大学云南省特种冶金重点实验室,昆明 650093
4 云南铜业科技发展股份有限公司,昆明 650033

Research Progress on Extraction and Purification of Selenium

YANG Zheng^1,2,3, DAI Linqing^1,2,3,*, ZHANG Libo^1,2,3, ZHANG Hui⁴, CHENG Yue^1,2,3, ZHOU Liang^1,2,3, SU Wenting^1,2,3

1 Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
2 Key Laboratory of Unconventional Metallurgy, Ministry of Education, Kunming University of Science and Technology, Kunming 650093, China
3 Yunnan Provincial Key Laboratory of Special Metallurgy, Kunming University of Science and Technology, Kunming 650093, China
4 Yunnan Copper Technology Development Co., Ltd., Kunming 650033, China

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摘要硒作为地壳中含量稀少且分散的非金属元素,因具备优异的物化性能,被广泛应用于冶金、玻璃和电子工业等领域。随着新材料和新能源行业的快速发展,电子工业对各种硒产品,特别是高端硒产品的需求不断攀升,如何清洁、高效、经济地从阳极泥等原料中提取粗硒并将其纯化,成为新能源等行业发展亟待解决的问题。本文综述了硒提取与纯化技术的研究进展,介绍了硒资源的储量、应用和消费概况,将硒提取工艺分为火法、半湿法、全湿法和其他回收工艺四大类,重点阐述了各种提取与纯化工艺的技术现状,详尽介绍了各主流工艺的优缺点、原料适用性以及应用情况,最后对硒提取与纯化工艺未来发展方向进行了展望。

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	杨政
	代林晴
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	程越
	周亮
	苏文婷

关键词: 粗硒提取技术纯化技术高纯硒

Abstract: As a rare and dispersed non-metallic element in the earth's crust, selenium is widely used in metallurgy, glass and electronic industry because of its excellent physical and chemical properties. With the rapid development of new materials and new energy industry, the demand for various selenium products, especially high-end selenium products, is rising. How to extract crude selenium from anode mud and other raw materials cleanly, efficiently and economically and purify it has become an urgent problem to be solved in the development of new energy and other industries. In this paper, the research progress of selenium extraction and purification technology is reviewed, and the reserves, application and consumption of selenium resources are introduced. The selenium extraction technology is categorized into four categories: fire method, semi-wet method, full wet method and other recovery processes. The technical status of various extraction and purification processes is emphasized, and the advantages and disadvantages, applicability of raw materials and application of each mainstream process are introduced in detail. Finally, the future development direction of selenium extraction and purification technology is prospected.

Key words: crude selenium extraction technology purification technology high purity selenium

出版日期: 2024-03-10 发布日期: 2024-03-18

ZTFLH:

TQ125.2

基金资助: 云南省重大科技专项计划(202102AB080014)

通讯作者: *代林晴,昆明理工大学冶金与能源工程学院副教授。2005年中南大学矿物加工工程专业本科毕业,2008年中南大学钢铁冶金专业硕士毕业后到昆明理工大学工作至今,2019年昆明理工大学有色金属冶金专业博士毕业。目前主要从事微波冶金、超声波冶金等方面的研究工作。发表论文20余篇,包括Crystals、Arch.Metall.Mater.、ACS Omega等。 linqingdai@163.com

作者简介: 杨政,2019年7月于陕西理工大学获得工学学士学位。现为昆明理工大学冶金与能源工程学院硕士研究生,在代林晴副教授的指导下进行研究。目前主要研究领域为硒资源综合回收利用。

引用本文:

杨政, 代林晴, 张利波, 张辉, 程越, 周亮, 苏文婷. 硒提取与纯化工艺研究进展[J]. 材料导报, 2024, 38(5): 22080188-14.
YANG Zheng, DAI Linqing, ZHANG Libo, ZHANG Hui, CHENG Yue, ZHOU Liang, SU Wenting. Research Progress on Extraction and Purification of Selenium. Materials Reports, 2024, 38(5): 22080188-14.

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http://www.mater-rep.com/CN/10.11896/cldb.22080188 或 http://www.mater-rep.com/CN/Y2024/V38/I5/22080188

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