不同离子对混凝土碱硅酸反应影响的研究进展

doi:10.11896/cldb.22060212

材料导报

2024, Vol. 38

Issue (2): 22060212-15 https://doi.org/10.11896/cldb.22060212

无机非金属及其复合材料

不同离子对混凝土碱硅酸反应影响的研究进展

龚青南, 王德辉^*

福州大学土木工程学院,福州 350108

Research Progress on the Effects of Different Ions on Alkali-Silica Reaction of Concrete

GONG Qingnan, WANG Dehui^*

College of Civil Engineering, Fuzhou University, Fuzhou 350108, China

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摘要混凝土的碱硅酸反应(Alkali-silica reaction,ASR)本质上是孔溶液中的离子、水分子与骨料中活性二氧化硅的反应。根据不同离子对ASR的影响效果,可将离子分为碱离子(Na⁺、K⁺和OH^-)、锂离子和铝离子、钙离子。碱离子(Na⁺、K⁺和OH^-)促进混凝土的碱硅酸反应,导致混凝土发生更严重的膨胀性破坏。Al³⁺和Li⁺减缓混凝土碱硅酸反应造成的膨胀性破坏;Ca²⁺起到的作用与n(Ca)/n(Si)(物质的量比)密切相关,当n(Ca)/n(Si)＜0.2时,Ca²⁺对ASR起促进作用;当n(Ca)/n(Si)≥0.2时,Ca²⁺对ASR起抑制作用。本文首先介绍了ASR反应产物的最新研究进展,包括ASR产物的种类、微观形貌、原子结构及水稳定性,综述了这些离子对ASR反应过程、ASR产物组成、ASR产物结晶性能及膨胀性的影响,展望了不同离子对混凝土ASR影响的未来研究方向。

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	龚青南
	王德辉

关键词: 碱硅酸反应碱离子锂离子铝离子钙离子 ASR产物

Abstract: Alkali-silica reaction (ASR) of concrete is essentially the reaction of ions and water molecules in the pore solution with active silica in the aggregate. According to the influence of different ions on ASR, ions can be divided into alkali ions (Na⁺, K⁺and OH^-), lithium ion and aluminum ion, calcium ion. Alkali ions promote the alkali-silica reaction of concrete, resulting in more severe expansive damage to concrete. Lithium and aluminum ions slow down the expansive damage caused by alkali-silica reaction of concrete. The role of Ca²⁺ is closely related to n(Ca)/n(Si) (molar ratio). When the n(Ca)/n(Si)＜0.2, Ca²⁺ promotes ASR. When the n(Ca)/n(Si)≥0.2, Ca²⁺ inhibits ASR. Firstly, the latest research progresses of ASR products are introduced, including the types, micro morphology, atomic structure and water stability of ASR pro-ducts. Then, influences of these ions on the ASR process, the composition of ASR products, the crystallization properties and expansion of ASR products are reviewed. Finally, the future research direction of the influence of different ions on ASR is prospected.

Key words: alkali-silica reaction alkali ions lithium ion aluminum ion calcium ion ASR products

出版日期: 2024-01-25 发布日期: 2024-01-26

ZTFLH:

TU528.04

基金资助: 国家自然科学基金(51608187)

通讯作者: *王德辉,博士,福州大学土木工程学院副研究员,旗山学者,国家自然科学基金委函评专家。2004年本科毕业于华北水利水电大学土木工程专业,2009年硕士毕业于中南大学土木工程材料专业,2015年博士毕业于湖南大学土木工程专业,主要从事超高性能混凝土的凝结硬化特性、石灰石粉对水泥基材料微观结构和性能的影响、腐蚀性物质在FRP筋海水海砂混凝土中的传输特性和腐蚀机理、3D打印混凝土等研究工作。作为项目负责人主持了国家重点研发计划项目子课题、国家自然科学基金青年科学基金、中国博士后科学基金面上项目、清华大学水沙科学与水利水电工程国家重点实验室开放基金、建筑安全与环境重点实验室开放基金等10余项课题。以第一作者或通信作者发表SCI论文12篇、EI论文5篇、ESI论文2篇,参编会议论文集1部。多篇SCI论文在TOP期刊成为“The Most Downloaded Article”,并得到多次引用。dhwang@fzu.edu.cn

作者简介: 龚青南,2022年本科毕业于莆田学院土木工程专业,现为福州大学土木工程学院硕士研究生,在王德辉副教授的指导下进行研究。目前主要研究领域为混凝土的碱硅酸反应,发表1篇SCI论文和1篇北大核心兼WJCI收录论文。

引用本文:

龚青南, 王德辉. 不同离子对混凝土碱硅酸反应影响的研究进展[J]. 材料导报, 2024, 38(2): 22060212-15.
GONG Qingnan, WANG Dehui. Research Progress on the Effects of Different Ions on Alkali-Silica Reaction of Concrete. Materials Reports, 2024, 38(2): 22060212-15.

链接本文:

http://www.mater-rep.com/CN/10.11896/cldb.22060212 或 http://www.mater-rep.com/CN/Y2024/V38/I2/22060212

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