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材料导报  2021, Vol. 35 Issue (17): 17010-17018    https://doi.org/10.11896/cldb.21020106
  高熵合金 |
AlCoCrFeNi系高熵合金的强化方法研究
李洪超1, 王军1,2, 袁睿豪1, 王毅1, 寇宏超1, 李金山1
1 西北工业大学凝固技术国家重点实验室,西安 710072
2 西北工业大学重庆科创中心,重庆 401135
Study on Strengthening Methods of AlCoCrFeNi High-Entropy Alloys
LI Hongchao1, WANG Jun1,2, YUAN Ruihao1, WANG Yi1, KOU Hongchao1, LI Jinshan1
1 State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072, China
2 Innovation Center, NPU Chongqing, Chongqing 401135, China
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摘要 高熵合金又称多主元合金,相比以一种或两种元素为主的传统合金,高熵合金多主元合金设计理念使其具有独特的成分和结构特征,并展示了一系列优异的力学性能。尤其是近几年,拥有高强度、高延性的高熵合金纷纷涌现,这对高熵合金的工程化应用具有重要意义。合金的力学性能与其强化方法息息相关,如细晶强化、共格第二相强化、非共格第二相强化、异质结构强化等强化机制都在不同程度上促进了高熵合金力学性能的提升,因此了解高熵合金的强化方法和机制对于提高高熵合金的力学性能、探索新的高强高韧高熵合金意义重大。AlCoCrFeNi系高熵合金是目前研究最多的高熵合金体系之一,而且该体系高熵合金还可以通过成分调节和热机械处理工艺产生不同的组织结构,进而引入不同的强化机制,合金的力学性能可以在大范围内进行调控,是研究高熵合金强化方法的理想材料。
基于此,本文以AlCoCrFeNi合金体系为对象,回顾了近几年高熵合金的强化方法,包括细晶强化、共格第二相强化、非共格第二相强化和异质结构强化,进一步阐述了成分和组织调控对高熵合金强化方法和力学性能的影响。不仅如此,本文还通过总结复合强化机制,发现必须借助多种强化机制才能使合金达到更高的强度,最后对高熵合金的强化方法研究进行了简单的总结和展望。
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李洪超
王军
袁睿豪
王毅
寇宏超
李金山
关键词:  高熵合金  强化方法  力学性能  复合强化    
Abstract: High-entropy alloys (HEAs) is also called multi-principal element alloys. Compared with traditional alloys with one or two elements as the principal constituents, the multiple constituent elements design concept of HEAs grants them the unique constituent, phase structure and a series of excellent mechanical properties. Especially in recent years, there are a lot of HEAs with high strength and ductility, which is of great significance to their engineering application. The excellent mechanical performance is closely related to the strengthening mechanism of the alloys, such as grain-boundary strengthening, coherent second phase strengthening and heterogeneous structure strengthening mechanism, which all promote the improvement of the performance of HEAs in various degrees. Therefore, it is crucial to understand the strengthening mechanism of the HEAs in order to improve the mechanical properties of the HEAs and explore new high-strength and high-ductility HEAs. AlCoCrFeNi HEAs is currently one of the most studied HEAs, which can produce different structure through composition adjustment and different thermo-mechanical treatment process, thus inducing different strengthening mechanism. The mechanical properties of AlCoCrFeNi HEAs can be adjusted in a wide range, making it an ideal material to study the strengthening mechanism of HEAs. Based on this, this article focuses on the subject of the strengthening mechanism of AlCoCrFeNi HEAs.
In this article, the strengthening mechanism of HEAs in recent years are reviewed, including grain-boundary strengthening, coherent second phase strengthening, incoherent second phase strengthening and heterogeneous structure strengthening. The composition and structure control for HEAs strengthening mechanism and mechanical properties is further expounded. In addition, this paper proposes that the single strengthening mechanism cannot greatly improve the strength of the alloy. By summarizing the multiple strengthening mechanism, it is proposed that the higher strength can be achieved by combining multiple strengthening mechanisms. At last, the future perspective of strengthening mechanism in HEAs is also discussed.
Key words:  high-entropy alloys    strengthening mechanism    mechanical property    multiple strengthening
                    发布日期:  2021-09-26
ZTFLH:  TG146  
基金资助: 国家自然科学基金(51774240);重庆市自然科学基金(cstc2020jcyj-msxmX0976);陕西省创新能力支撑计划(2020KJXX-073);中央高校基础研究经费
通讯作者:  nwpuwj@nwpu.edu.cn; ljsh@nwpu.edu.cn   
作者简介:  李洪超,2015年6月毕业于西北工业大学,获得工学学士学位。现为西北工业大学材料学院博士研究生,在王军教授的指导下进行研究。目前主要研究领域为热机械处理对高熵合金的组织和力学性能调控。
王军,博士,西北工业大学材料学院/凝固技术国家重点实验室教授、博士生导师,陕西省青年科技新星,《中国材料进展》《China Foundry》《特种铸造及有色合金》等期刊青年编委。主要从事高熵合金及凝固科学与技术等研究工作,以第一或通讯作者发表学术论文70余篇,授权发明专利26项。
李金山,博士,教授,博导,西北工业大学材料学院院长,凝固技术国家重点实验室主任,国家万人计划领军人才,担任中国材料研究学会凝固科学与技术分会理事长,中国机械工程学会铸造分会副理事长,《中国有色金属学报》《金属学报》《中国材料进展》等期刊编委。主要从事先进金属结构材料及其精确热成形技术研究工作,已发表论文300余篇,授权发明专利50余项。
引用本文:    
李洪超, 王军, 袁睿豪, 王毅, 寇宏超, 李金山. AlCoCrFeNi系高熵合金的强化方法研究[J]. 材料导报, 2021, 35(17): 17010-17018.
LI Hongchao, WANG Jun, YUAN Ruihao, WANG Yi, KOU Hongchao, LI Jinshan. Study on Strengthening Methods of AlCoCrFeNi High-Entropy Alloys. Materials Reports, 2021, 35(17): 17010-17018.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.21020106  或          http://www.mater-rep.com/CN/Y2021/V35/I17/17010
1 Cantor B, Chang I T H, Knight P, et al. Materials Science and Enginee-ring A, 2004, A375-377, 213.
2 Yeh J W, Chen S K, Lin S J, et al. Advanced Engineering Materials, 2004, 6, 99.
3 Jin K, Lu C, Dou Y, et al. Materials Reports A:Review Papers, 2020, 34(9), 22(in Chinese).
靳柯, 卢晨阳, 豆艳坤, 等. 材料导报:综述篇, 2020, 34(9), 22.
4 Lu Z, Lei Z, Huang H, et al. Acta Metallurgica Sinica, 2018, 54(11), 85(in Chinese).
吕昭平, 雷智锋, 黄海龙, 等. 金属学报, 2018, 54(11), 85.
5 Li T, Lu Y, Cao Z, et al. Acta Metallurgica Sinica, 2021, 57(1), 44(in Chinese).
李天昕, 卢一平, 曹志强, 等. 金属学报, 2021, 57(1), 44.
6 Gludovatz B, Hohenwarter A, Thurston K V, et al. Nature Communications, 2016, 7, 10602.
7 Yao H, Lu Y, Cao Z, et al. Materials Reports A:Review Papers, 2020, 34(9), 45(in Chinese).
姚宏伟, 卢一平, 曹志强, 等. 材料导报:综述篇,2020,34(9),45.
8 Gludovatz B, Hohenwarter A, Catoor D, et al. Science,2014,345,1153.
9 Deng Y, Tasan C C, Pradeep K G, et al. Acta Materialia,2015,94,124.
10 Munitz A, Salhov S, Hayun S, et al. Journal of Alloys and Compounds, 2016, 683, 221.
11 Schneider M, George E P, Manescau T J, et al. International Journal of Plasticity, 2020, 124, 155.
12 Gwalani B, Choudhuri D, Liu K, et al. Materials Science and Enginee-ring A, 2020, A771, 138620.
13 Zhao Y Y, Chen H W, Lu Z P, et al. Acta Materialia, 2018, 147, 184.
14 Zhao Y L, Yang T, Tong Y, et al. Acta Materialia, 2017, 138, 72.
15 Zhao Y L, Yang T, Li Y R, et al. Acta Materialia, 2020, 188, 517.
16 Yang H, Li J, Guo T, et al. Metals and Materials International, 2019, 25, 1145.
17 Chen R, Qin G, Zheng H, et al. Acta Materialia, 2018, 144, 129.
18 Ma Y, Wang Q, Jiang B B, et al. Acta Materialia, 2018, 147, 213.
19 Jin X, Bi J, Zhang L, et al. Journal of Alloys and Compounds, 2019, 770, 655.
20 Choudhuri D, Gwalani B, Gorsse S, et al. Acta Materialia, 2019, 165, 420.
21 Slone C E, Miao J, George E P, et al. Acta Materialia, 2019, 165, 496.
22 Chen G, Qiao J W, Jiao Z M, et al. Scripta Materialia, 2019, 167, 95.
23 Miracle D B, Senkov O N A. Acta Materialia, 2017, 122, 448.
24 Kao Y F, Chen T J, Chen S K, et al. Journal of Alloys and Compounds, 2009, 488, 57.
25 Gwalani B, Gorsse S, Choudhuri D, et al. Scripta Materialia, 2019, 162, 18.
26 Yang J, Qiao J W, Ma S G, et al. Journal of Alloys and Compounds, 2019, 795, 269.
27 Lu Y, Dong Y, Guo S, et al. Scientific Reports, 2014, 4, 6200.
28 Dong Y, Gao X, Lu Y, et al. Materials Letters, 2016, 169, 62.
29 Li D, Zhang Y. Intermetallics, 2016, 70, 24.
30 Yang H, Li J, Pan X, et al. Journal of Materials Science & Technology, 2020, 72, 1.
31 Guo T, Li J, Wang J, et al. Materials Science and Engineering A, 2018, A729, 141.
32 Gwalani B, Soni V, Choudhuri D, et al. Scripta Materialia,2016,123,130.
33 Gwalani B, Gangireddy S, Zheng Y, et al. Scientific Reports, 2019, 9, 6371.
34 Sourav A, Yebaji S, Thangaraju S, et al. Materials Science and Enginee-ring A, 2020, A793, 139877.
35 Guo S, Ng C, Lu J, et al. Journal of Applied Physics, 2011, 109, 103505.
36 Qin G, Xue W, Fan C, et al. Materials Science and Engineering A, 2018, A710, 200.
37 Kang M, Lim K R, Won J W, et al. Journal of Alloys and Compounds, 2018, 769, 808.
38 Wani I S, Bhattacharjee T, Sheikh S, et al. Materials Research Letters, 2016, 4, 174.
39 Gao X, Lu Y, Zhang B, et al. Acta Materialia, 2017, 141, 59.
40 Zhang Y, Wang X, Li J, et al. Materials Science and Engineering A, 2018, A724, 148.
41 Bhattacharjee T, Wani I S, Sheikh S, et al. Scientific Reports, 2018, 8, 3276.
42 Shi P, Ren W, Zheng T, et al. Nature Communications, 2019, 10, 489.
43 Wani I S, Bhattacharjee T, Sheikh S, et al. Intermetallics,2017,84,42.
44 Jin X, Zhou Y, Zhang L, et al. Materials Letters, 2018, 216, 144.
45 Chen C, Pang S, Cheng Y, et al. Journal of Alloys and Compounds, 2016, 659, 279.
46 Liu D, Yu P, Li G, et al. Materials Science and Engineering A, 2018, A724, 283.
47 Wu S W, Wang G, Yi J, et al. Materials Research Letters,2016,5,276.
48 Yoshida S, Bhattacharjee T, Bai Y, et al. Scripta Materialia, 2017, 134, 33.
49 He Y, Yang H, Zhao C, et al. Journal of Alloys and Compounds, 2020, 830, 154645.
50 Otto F, Dlouhý A, Somsen C, et al. Acta Materialia, 2013, 61, 5743.
51 Yang H X, Li J S, Guo T, et al. Rare Metals, 2020, 39, 156.
52 Hou J, Shi X, Qiao J, et al. Materials & Design, 2019, 180, 107910.
53 Wang J, Niu S, Guo T, et al. Journal of Alloys and Compounds, 2017, 710, 144.
54 Wang J, Yang H, Guo T, et al. Entropy, 2018, 20, 917.
55 Niu S Z, Kou H C, Wang J, et al. Rare Metals, 2017, DOI:10.1007/s12598-016-0860-y.
56 Zhao C, Li J, He Y, et al. Journal of Alloys and Compounds, 2020, 820, 153407.
57 Zhao C, Li J, Liu Y, et al. Journal of Materials Science & Technology, 2021, 73, 83.
58 Niu S, Kou H, Guo T, et al. Materials Science and Engineering: A, 2016, 671, 82.
59 Gwalani B, Soni V, Lee M, et al. Materials & Design, 2017, 121, 254.
60 Chen D, He F, Han B, et al. Intermetallics, 2019, 110, 106476.
61 He J Y, Wang H, Huang H L, et al. Acta Materialia, 2016, 102, 187.
62 He J Y, Wang H, Wu Y, et al. Intermetallics, 2016, 79, 41.
63 Lee D H, Park J M, Yang G, et al. Scripta Materialia, 2019, 163, 24.
64 Li C, Ma Y, Hao J, et al. Materials Science and Engineering A, 2018, A737, 286.
65 Liang Y J, Wang L, Wen Y, et al. Nature Communications, 2018, 9, 4063.
66 Liu W H, Yang T, Liu C T. Materials Chemistry and Physics, 2018, 210, 2.
67 Yang T, Zhao Y L, Luan J H, et al. Scripta Materialia, 2019, 164, 30.
68 Zhang L, Zhou Y, Jin X, et al. Materials Science and Engineering A, 2018, A732, 186.
69 Zheng T, Hu X, He F, et al. Journal of Materials Science & Technology, 2020, 69, 156.
70 Tong Y, Chen D, Han B, et al. Acta Materialia, 2019, 165, 228.
71 Sathiyamoorthi P, Kim H S. Progress in Materials Science,DOI:10.1016/j.pmatsci.2020.100709.
72 Shukla S, Choudhuri D, Wang T, et al. Materials Research Letters, 2018, 6, 676.
73 Zhu Y, Wu X. Materials Research Letters, 2019, 7, 393.
74 Wu S W, Wang G, Wang Q, et al. Acta Materialia, 2019, 165, 444.
75 Du X H, Li W P, Chang H T, et al. Nature Communications, 2020, 11, 2390.
76 Fu Z, Jiang L, Wardini J L, et al. Science Advances, DOI:10.1126/sciadv.aat8712.
77 Lu Y, Gao X, Jiang L, et al. Acta Materialia, 2017, 124, 143.
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