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材料导报  2019, Vol. 33 Issue (6): 1070-1073    https://doi.org/10.11896/cldb.201906030
  高分子与聚合物基复合材料 |
EVA基纺织品用热熔胶的形成:组分含量和参数调控
武海良1, 杨倩1, 张希文1, 沈艳琴1, 姚一军2
1 西安工程大学纺织科学与工程学院,西安 710048
2 陕西科技大学轻工科学与工程学院,西安 710021
Fabrication of EVA Based Hot Melt Adhesive for Textiles via Adjusting Component Amount and Experimental Parameters
WU Hailiang1, YANG Qian1, ZHANG Xiwen1, SHEN Yanqin1, YAO Yijun2
1 School of Textile Science and Engineering, Xi’an Polytechnic University, Xi’an 710048
2 College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi’an 710021
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摘要 以乙烯-醋酸乙烯酯(EVA)为基体,采用熔融共混法设计合成了一种高强低黏的EVA基纺织品用热熔胶。利用红外光谱仪(FTIR)和差示扫描量热仪(DSC)对热熔胶的结构与热稳定性能进行表征,探讨了增黏树脂种类与热熔胶剥离强度的关系,考察了不同条件对热熔胶的熔体指数、熔融黏度、硬度及层压纺织品粘接效果等指标的影响。结果表明,松香作为增黏树脂且与EVA的质量比为16∶25,抗氧剂的投入量占EVA的0.8%时,热熔胶对涤纶布的剥离强力最好;石蜡的加入可以改善EVA基热熔胶的熔融黏度;当混炼温度达到140 ℃、混炼时间为25 min时,制备的EVA基热熔胶显示了较高的玻璃化转变温度(Tg=49.8 ℃)和熔体指数(MI=18.834 g/10 min),对层压涤纶布的剥离强力达到34.1 N,符合层压纺织品要求。
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武海良
杨倩
张希文
沈艳琴
姚一军
关键词:  EVA基热熔胶  剥离强力  增黏树脂  熔体指数    
Abstract: Ahot melt adhesive for textile products with high strength and low viscosity was synthesized via melt blending method and taking ethylene vinyl acetate (EVA) as matrix. The structure and thermal stability of the obtained EVA based hot melt adhesive were characterized by infrared spectrum (FTIR) and differential scanning calorimeter (DSC). The relationship between tackifying resin types and peel strength of hot melt adhesives was investigated. Furthermore, the impact of various conditions on the properties(such as melt index, melt viscosity, hardness and bonding effect to laminated textiles etc.) of EVA based hot melt adhesive was analyzed. The results indicated that the EVA based hot melt adhesive showed superior peeling strength on polyester fabric, under the colophony (as a tackifying resin) and EVA mass ratio of 16∶25, and the antioxidant input amount of 0.8% of EVA. The addition of paraffin wax could improve the viscosity of the EVA based hot melt adhesive. In addition, under the condition that the mixing temperature reached 140 ℃ and mixing time was 25 min, the prepared EVA based hot melt adhesive presented high glass transition temperature (Tg=49.8 ℃), favorable melt index (MI=18.834 g/10 min), and satisfactory peeling strength (34.1 N) for laminated polyester fabric, which met the demands of laminated textiles.
Key words:  EVA based hot melt adhesive    peel strength    tackifying resin    melt index
               出版日期:  2019-03-25      发布日期:  2019-04-03
ZTFLH:  TQ436.4  
基金资助: 陕西省重点研发计划项目(2017GY-132)
作者简介:  武海良,西安工程大学纺织科学与工程学院,教授,三秦学者。
引用本文:    
武海良, 杨倩, 张希文, 沈艳琴, 姚一军. EVA基纺织品用热熔胶的形成:组分含量和参数调控[J]. 材料导报, 2019, 33(6): 1070-1073.
WU Hailiang, YANG Qian, ZHANG Xiwen, SHEN Yanqin, YAO Yijun. Fabrication of EVA Based Hot Melt Adhesive for Textiles via Adjusting Component Amount and Experimental Parameters. Materials Reports, 2019, 33(6): 1070-1073.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.201906030  或          http://www.mater-rep.com/CN/Y2019/V33/I6/1070
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