金属卤化物钙钛矿材料自掺杂研究进展

doi:10.11896/cldb.24020097

材料导报

2025, Vol. 39

Issue (7): 24020097-9 https://doi.org/10.11896/cldb.24020097

无机非金属及其复合材料

金属卤化物钙钛矿材料自掺杂研究进展

陈旭, 廖静, 谭理, 李海进^*

西南石油大学新能源与材料学院, 成都 610500

Research Progress of Self-doping in Metal Halide Perovskite Materials

CHEN Xu, LIAO Jing, TAN Li, LI Haijin^*

School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China

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摘要近年来大量研究表明,自掺杂可定向调控有机-无机金属卤化物钙钛矿材料导电类型(P型或N型),优化其光吸收与载流子传输性能,进而提升器件光电转换效率。连续沉积自掺杂类型相反的两种钙钛矿,可制得新型双钙钛矿层异(同)质结(P-P结)太阳能电池。与传统钙钛矿太阳能电池相比,自掺杂P-P结太阳能电池的光活性层存在额外内建电场,可促进载流子的传输,从而减少非辐射复合。同时,钙钛矿双极性电荷传输的特性使其可充当电子传输层和空穴传输层。这允许P-P结太阳能电池摒弃传输层结构,简化器件结构、优化制备流程,为钙钛矿太阳能电池的进一步发展提供新方向。本文围绕有机-无机金属卤化物钙钛矿材料,详细阐述了调控其自掺杂类型的方法,讨论了自掺杂P-P结太阳能电池的物理机制及影响因素,梳理并总结了自掺杂钙钛矿在制备太阳能电池方面的应用,最后对其当前的技术难点和未来发展进行了总结与展望。

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	陈旭
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关键词: 钙钛矿自掺杂 P(N)型钙钛矿 P-P异(同)质结

Abstract: In recent years, numerous research has demonstrated that self-doping enables precise modulation of the conductivity type (p-type or n-type) in organic-inorganic metal halide perovskite materials, leading to improved light absorption and charge carrier transport, ultimately resulting in enhanced power conversion efficiency of solar cells. Furthermore, the sequential deposition of perovskite layers with different doping types has facilitated the development of novel bilayer perovskite homojunction/heterojunction (P-P junction) solar cells. When compared to conventional pe-rovskite solar cells, P-P junction solar cells exhibit an additional built-in electric field within the photoactive layer, which efficiently promotes the transmission of carrier, effectively reducing non-radiative recombination. Additionally, the inherent bipolar charge transport characteristics of perovskite materials allow them to function as both electron and hole transport layers. Consequently, the introduction of P-P junctions obviates the need for separate transport layers, thereby optimizing device architecture and simplifying fabrication processes. These advancements provide a promising direction for the further development of perovskite solar cells. This paper focuses on organic-inorganic metal halide perovskite materials, providing detailed insights into the methods employed to regulate self-doping types. It also comprehensively reviews the applications of self-doped perovskites in solar cells, elucidates the physical mechanisms and influencing factors associated with self-doped P-P junction solar cells, and concludes with a summary and outlook on the current technological challenges and future prospects in this field.

Key words: perovskite self-doping P(N)-type perovskite P-P heterostructure (homojunction)

出版日期: 2025-04-10 发布日期: 2025-04-10

ZTFLH:

TK514

基金资助: 四川省科技计划项目(2022NSFSC1963);四川省产教融合示范项目(川财教[2022]106号)

通讯作者: *李海进,博士,西南石油大学讲师、硕士研究生导师。从事光伏新能源相关领域的研究。haijinli@swpu.edu.cn

作者简介: 陈旭,西南石油大学新能源与材料学院硕士研究生,在李海进讲师的指导下进行研究。目前主要研究方向为金属卤化物钙钛矿半导体太阳能电池。

引用本文:

陈旭, 廖静, 谭理, 李海进. 金属卤化物钙钛矿材料自掺杂研究进展[J]. 材料导报, 2025, 39(7): 24020097-9.
CHEN Xu, LIAO Jing, TAN Li, LI Haijin. Research Progress of Self-doping in Metal Halide Perovskite Materials. Materials Reports, 2025, 39(7): 24020097-9.

链接本文:

https://www.mater-rep.com/CN/10.11896/cldb.24020097 或 https://www.mater-rep.com/CN/Y2025/V39/I7/24020097

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