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材料导报编辑部  2017, Vol. 31 Issue (10): 121-126    https://doi.org/10.11896/j.issn.1005-023X.2017.010.025
  材料研究 |
铝合金表面蓝色微弧氧化陶瓷膜的制备及性能研究*
陈超,张玉平,陈为为,程焕武,王鲁
北京理工大学材料学院, 北京 100083
Preparation and Properties of Blue Ceramic Coating by Micro-arc Oxidation on Aluminum Alloy
CHEN Chao, ZHANG Yuping, CHEN Weiwei, CHENG Huanwu, WANG Lu
School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100083
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摘要 采用微弧氧化技术在5052铝合金表面制备蓝色陶瓷膜,研究Co(OH)2着色剂浓度和微弧氧化电压对蓝色陶瓷膜组织结构和腐蚀性能的影响规律。采用光学显微镜、扫描电镜和X射线衍射研究蓝色陶瓷膜层的宏观形貌、微观组织和相结构,采用电化学工作站测试陶瓷层在3.5%(质量分数)NaCl溶液中的电化学腐蚀性能。研究结果表明,蓝色微弧氧化陶瓷层主要由γ-Al2O3组成,提高Co(OH)2浓度或者氧化电压,膜层颜色由浅向深演变,当浓度增至3.0 g/L后膜层蓝色不再加深,同时膜层表面逐渐封闭,致密性提高。在140 V氧化电压下,添加1.0 g/L Co(OH)2所制备的蓝色膜层具有最好的耐腐蚀性能。蓝色膜具有颜色艳丽、装饰性好等优势,相信该蓝色微弧氧化膜技术在建筑材料和仪器仪表行业将会有广阔的应用前景。
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陈超
张玉平
陈为为
程焕武
王鲁
关键词:  铝合金  微弧氧化  蓝色陶瓷膜  微观结构  电化学腐蚀    
Abstract: A blue ceramic coating was prepared on 5052 aluminum alloy by micro-arc oxidation in the manuscript. We syste-matically investigated the effects of the Co(OH)2 concentration and the applied voltage on the microstructure and the corrosion resis-tance. The OM, SEM and XRD were employed to characterize the macrostructure, microstructure and phase structure, respectively. The electrochemical corrosion resistance of coatings was measured by an electrochemical workstation in 3.5 wt% NaCl solution. The results show that the phase structure is mainly compose of γ-Al2O3. As the Co(OH)2 concentration and voltage increased, the blueness degree of coatings gradually deepen, and the color is the darkest when added 3.0 g/L Co(OH)2. Meanwhile, the surface tended to close and became denser. The results show that the corrosion resistance of ceramic coating is best with 1.0 g/L Co(OH)2 when the voltage was 140 V. We believe that the micro-arc oxidation technology of blue ceramic coating will have a wide range of applications in building materials and instrumentation industries as its gorgeous color and decorative function.
Key words:  aluminum alloy    micro-arc oxidation    blue ceramic coating    microstructure    electrochemical corrosion
发布日期:  2018-05-08
ZTFLH:  TG174.453  
基金资助: *国家自然科学基金(51401024);北京理工大学基础研究项目(20150942006)
通讯作者:  陈为为,男,1982年生,副教授,主要从事材料表面改性和涂层研究Tel:010-68912709E-mail:wwchen@bit.edu.cn   
作者简介:  陈超:男,1992年生,硕士研究生,主要研究方向为涂层制备E-mail:645097223@bit.edu.cn
引用本文:    
陈超,张玉平,陈为为,程焕武,王鲁. 铝合金表面蓝色微弧氧化陶瓷膜的制备及性能研究*[J]. 材料导报编辑部, 2017, 31(10): 121-126.
CHEN Chao, ZHANG Yuping, CHEN Weiwei, CHENG Huanwu, WANG Lu. Preparation and Properties of Blue Ceramic Coating by Micro-arc Oxidation on Aluminum Alloy. Materials Reports, 2017, 31(10): 121-126.
链接本文:  
https://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2017.010.025  或          https://www.mater-rep.com/CN/Y2017/V31/I10/121
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