VO2智能调温涂层的研究进展

doi:10.11896/cldb.24030036

材料导报

2025, Vol. 39

Issue (7): 24030036-7 https://doi.org/10.11896/cldb.24030036

无机非金属及其复合材料

VO₂智能调温涂层的研究进展

鲍艳^1,*, 谢梦爽¹, 郭茹月¹, 张婧²

1 陕西科技大学轻工科学与工程学院, 西安 710021
2 咸阳职业技术学院医药化工学院, 陕西咸阳 712000

Research Progress of VO₂ Intelligent Temperature Control Coating

BAO Yan^1,*, XIE Mengshuang¹, GUO Ruyue¹, ZHANG Jing²

1 College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China
2 College of Medicine and Chemical Engineering, Xianyang Polytechnic Institute, Xianyang 712000, Shaanxi, China

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摘要二氧化钒(VO₂)是一种典型的二元过渡金属氧化物,具有金属-绝缘体相变特性,在约68 ℃时可实现单斜绝缘相和稳定金红石金属相的可逆转变,因而在建筑领域具有良好的应用前景。近年来,VO₂的制备工艺已相对成熟,但其热致变色性能的提升仍是研究的重点。基于此,本文从VO₂的热致变色性能调控出发,旨在概述VO₂智能调温涂层的研究进展。首先,总结了VO₂相变前后的晶体结构和能带结构变化,并详细讨论了基于Mott理论、Peierls理论以及Mott与Peierls协同理论的三种相变机理;其次,总结了元素掺杂对VO₂相变温度的影响规律,进一步阐明了核壳结构和多层膜结构等结构设计对VO₂光学性能、抗氧化性以及环境稳定性等综合性能的增强原理,分析比较了各自的特点和优势;最后,指出了VO₂现阶段存在的问题,并对其未来发展进行了展望,以期为相关领域的研究人员提供借鉴。

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	鲍艳
	谢梦爽
	郭茹月
	张婧

关键词: 相变离子掺杂核壳结构多层膜结构

Abstract: Vanadium dioxide (VO₂) , a typical binary transition metal oxide, has the characteristics of metal-insulator phase transformation, which can achieve the reversible transformation of monoclinic insulating phase and stable rutile metal phase at about 68 ℃, and it has a good application prospect in the construction field for it. In recent years, the preparation technology for VO₂ has been relatively mature, but the improvement of its thermochromic performance is still the focus of research. Based on it, with the thermochromic performance control of VO₂ as the center, this paper summarized the research progress of VO₂ intelligent temperature control coatings. Firstly, the crystal structure and band structure changes of VO₂ before and after the phase transition are summarized, and the three phase transition mechanisms based on the Mott theory, the Peierls theory and the Mott-Peierls synergy theory are discussed in detail. Secondly, the influence of elemental doping on the phase transition temperature of VO₂ is clarified, and the enhancement principle of the structural design of core-shell structure and multilayer film structure on the comprehensive properties of VO₂ such as optical properties, oxidation resistance and environmental stability is further clarified. Moreover, the characteristics and advantages of each strategy are analyzed and compared. Finally, the existing problems of VO₂ at the present stage are pointed out, and its future development is prospected. It is helpful to provide reference for researchers in related fields.

Key words: phase transitions ion doping core-shell structure multilayer membrane structure

出版日期: 2025-04-10 发布日期: 2025-04-10

ZTFLH:

TQ135.11

基金资助: 国家自然科学基金(22378253;22078188);咸阳市科技计划项目(2021ZDZX-GY-0007);陕西省科技厅项目(2022GY-170)

通讯作者: *鲍艳,二级教授,博士研究生导师,享受国务院政府特殊津贴。长期从事有机/无机纳米复合功能化学品的研究。baoyan@sust.edu.cn

引用本文:

鲍艳, 谢梦爽, 郭茹月, 张婧. VO₂智能调温涂层的研究进展[J]. 材料导报, 2025, 39(7): 24030036-7.
BAO Yan, XIE Mengshuang, GUO Ruyue, ZHANG Jing. Research Progress of VO₂ Intelligent Temperature Control Coating. Materials Reports, 2025, 39(7): 24030036-7.

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https://www.mater-rep.com/CN/10.11896/cldb.24030036 或 https://www.mater-rep.com/CN/Y2025/V39/I7/24030036

1 Santamouris M. Minimizing energy consumption, energy poverty and global and local climate change in the built environment:innovating to zero:causalities and impacts in a zero concept world, Elsevier, UK, 2018, pp.167.
2 Enríquez E, Fuertes V, Solar Energy, 2017, 149, 114.
3 Shi R, Shen N, Wang J, et al. Applied Physics Reviews, 2019, 6(1), 011312.
4 Coşkun M, Altınöz S, Coşkun Ö D. Photonics and Nanostructures-Fundamentals and Applications, 2022, 49, 100993.
5 Günther A, Lohringer H, Müller D, et al. Journal of Physics and Che-mistry of Solids, 2022, 170, 110897.
6 Fukawa A, Nakazawa T, Tamura J, et al. Applied Physics Letters, 2023, 122, 052403.
7 Rana A, Li C, Koster G, et al. Scientific Reports, 2020, 10(1), 3293.
8 Lu Y C, Hsueh C H. ACS Applied Nano Materials, 2022, 5(2), 2923.
9 Thangappan R, Kumar R D, Jayavel R. Diamond and Related Materials, 2023, 137, 110102.
10 Wang S, Liu M, Kong L, et al. Progress in Materials Science, 2016, 81, 1.
11 Morin F J. Physical review letters, 1959, 3(1), 34.
12 Fillingham P J. Journal of Applied Physics, 1967, 38(12), 4823.
13 Eyert V. Annalen der Physik, 2002, 514(9), 650.
14 Liu H, Lu J, Wang X R. Nanotechnology, 2017, 29(2), 024002.
15 Guo Y, Zhang Y, Zhang L, et al. Materials Research Express, 2018, 6(2), 026409.
16 Jana A, Sahoo S, Chowdhury S, et al. Physical Review B, 2022, 106(20), 205123.
17 Ergün Y, Jeckelmann E. Physical Review B, 2020, 101(8), 085403.
18 Quackenbush N F, Paik H, Holtz M E, et al. Physical Review B, 2017, 96(8), 081103.
19 Xue Y, Yin S. Nanoscale, 2022, 14(31), 11054.
20 Qin S, Fan Y, Qiu X, et al. ACS Applied Electronic Materials, 2022, 4(12), 6067.
21 Zhao Z, Liu Y, Wang D, et al. Solar Energy Materials and Solar Cells, 2020, 209, 110443.
22 Li Z, Liu X, Li W, et al. Vacuum, 2021, 184, 109903.
23 Krammer A, Matilainen A, Pischow K, et al. Solar Energy Materials and Solar Cells, 2022, 240, 111680.
24 Victor J L, Gaudon M, Salvatori G, et al. The Journal of Physical Che-mistry Letters, 2021, 12(32), 7792.
25 Hunt G M, Miragliotta J A, Ginn J, et al. Applied Physics Letters, 2023, 123(7), 071103.
26 Verma D, Chandran Y, Uniyal P, et al. Journal of the American Ceramic Society, 2023, 106(7), 4321.
27 Bao Y, Guo R, Ge X, et al. Progress in Organic Coatings, 2023, 180, 107574.
28 Chen F, Yuan L, Wu X, et al. Ceramics International, 2023, 49(15), 25585.
29 Zhao C, Li Z, Sun S, et al. Vacuum, 2022, 203, 111309.
30 Zhang Y, Tan X, Huang C, et al. Materials Research Innovations, 2015, 19(4), 295.
31 Zhao Z, Li D, Yang J, et al. Applied Surface Science, 2023, 635, 157705.
32 Outón J, Casas-Acuña A, Domínguez M, et al. Applied Surface Science, 2023, 608, 155180.
33 Suleiman A O, Mansouri S, Margot J, et al. Applied Surface Science, 2022, 571, 151267.
34 Kurajica S, Mandić V, Panžić I, et al. Nanomaterials, 2020, 10(12), 2537.
35 Huang T, Kang T, Li Y, et al. Optical Materials Express, 2018, 8(8), 2300.
36 Bleu Y, Bourquard F, Barnier V, et al. Materials, 2023, 16(1), 461.
37 Ding X, Li Y, Zhang Y. Molecules, 2023, 28(9), 3778.
38 Pei R, Ma X, Han C, et al. Zeitschrift für Anorganische und Allgemeine Chemie, 2022, 648(14), e202200132.
39 Zou Z, Zhang Z, Xu J, et al. Journal of Alloys and Compounds, 2019, 806, 310.
40 Wang L, Hao Y Q, Ma W, et al. Rare Metals, 2021, 40, 1337.
41 Wang S, Wei W, Huang T, et al. Advanced Engineering Materials, 2019, 21(12), 1900947.
42 Cui Y, Cao C, Chen Z, et al. Computational Materials Science, 2017, 130, 103.
43 Liu Y, Jiang T, Lv Y, et al. Materials Research Express, 2023, 10(3), 035008.
44 Haji H F, Numan N, Madiba I G, et al. Journal of Electronic Materials, 2023, 52(6), 4020.
45 Xie D, Li Y, Liu Y, et al. Catalysis Letters, 2023, 154, 1847.
46 Baqir M A, Choudhury P K, Naqvi Q A, et al. IEEE Access, 2020, 8, 84850.
47 Li D, Deng S, Zhao Z, et al. Applied Surface Science, 2022, 598, 153741.
48 Sun X, Qu Z, Yuan J, et al. Ceramics International, 2021, 47(20), 29011.
49 Wen Z, Ke Y, Feng C, et al. Advanced Materials Interfaces, 2021, 8(1), 2001606.
50 Saini M, Dehiya B S, Umar A. Ceramics International, 2020, 46(1), 986.
51 Pi J, Li C B, Sun R Y, et al. Composites Communications, 2022, 32, 101167.
52 Lu Y, Cao Z, Chen C, et al. Ceramics International, 2023, 49(11), 19541.
53 Qu Z, Yao L, Ma S, et al. Solar Energy Materials and Solar Cells, 2019, 200, 109920.
54 Liu Y, Sun R, Jin B, et al. ACS Applied Nano Materials, 2022, 5(4), 5599.
55 Liu Y, Xu W Z, Charpentier P A. Progress in Organic Coatings, 2020, 142, 105589.
56 Bleu Y, Bourquard F, Poulet A, et al. Ceramics International, 2023, 49(9), 13542.
57 Xu F, Cao X, Shao Z, et al. ACS Applied Materials & Interfaces, 2019, 11(5), 4712.

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