弛豫时间分布技术在固体氧化物燃料电池中的应用

doi:10.11896/cldb.24090247

材料导报

2025, Vol. 39

Issue (19): 24090247-8 https://doi.org/10.11896/cldb.24090247

无机非金属及其复合材料

弛豫时间分布技术在固体氧化物燃料电池中的应用

谭婷^1,*, 李春生², 王冠旭², 刘彩玲², 王嘉蓉², 杨征^1,*

1 中石油深圳新能源研究院有限公司,广东深圳 518000
2 中国石油集团济柴动力有限公司,济南 250000

Application of Distribution of Relaxation Times Technique in Solid Oxide Fuel Cells

TAN Ting^1,*, LI Chunsheng², WANG Guanxu², LIU Cailing², WANG Jiarong², YANG Zheng^1,*

1 PetroChina Shenzhen New Energy Research Institute Company Limited, Shenzhen 518000, Guangdong, China
2 CNPC Jichai Power Company Limited, Jinan 250000, China

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摘要固体氧化物燃料电池(SOFC)作为高效的能量存储和转换系统,将逐步改变传统能源利用方式。然而,SOFC电极反应复杂,深度理解和分析电化学反应过程及其衰减机理较为困难,需要更先进的分析手段来解决这一问题。弛豫时间分布(DRT)技术是近年来备受瞩目的一种电化学分析方法,可以精确地评估SOFC系统中的电化学反应特性。DRT技术是通过回归DRT模型,对电化学阻抗谱(EIS)数据进行解卷积,然后提取电化学系统的时间尺度特性,确定合适的等效电路并量化关键物理参数,从而为选择和优化电极材料和微观结构提供指导的一种分析与研究手段。本文介绍了DRT技术的原理和分析过程,并通过介绍其在SOFC领域中的具体应用实例,展示了DRT方法在电极极化分离和归属方面以及电池衰减分析中的应用和优势。

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	谭婷
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	杨征

关键词: 弛豫时间分布技术固体氧化物燃料电池阳极阴极衰减机理

Abstract: Solid oxide fuel cells (SOFCs), as efficient energy storage and conversion systems, are poised to gradually change traditional energy utilization methods. However, due to the complexity of electrochemical reactions in SOFC electrodes, gaining a deep understanding of the reaction processes and analyzing degradation mechanisms remain challenging. Advanced analysis techniques are required to address this issue. The distribution of relaxation times (DRT) has recently garnered significant attention as a precise analysis tool for the electrochemical characteristics of SOFC systems. By deconvoluting electrochemical impedance spectroscopy (EIS) data, the DRT technique extracts time-scale characteristics of the electrochemical system, identifies appropriate equivalent circuits, and quantifies key physical parameters. This provides valuable guidance for selecting and optimizing electrode materials and microstructures. This review outlines the principles and analytical process of the DRT technique, while showcasing its practical applications and advantages in the separation and attribution of electrode polarization, as well as in the analysis of cell degradation in the SOFC field.

Key words: distribution of relaxation time solid oxide fuel cell anode cathode degradation mechanism

发布日期: 2025-09-24

ZTFLH:

TM911.4

基金资助: 中国石油集团济柴动力有限公司科技项目(F-G60024L0);中国石油天然气集团有限公司基础性前瞻性科技专项(2023ZZ1204)

通讯作者: *谭婷,博士,2024年入职中石油深圳新能源研究院有限公司。目前主要研究领域为固体氧化物燃料电池/电解池。tanting0817@163.com
杨征,博士,中石油深圳新能源研究院有限公司研究员。目前主要从事固体氧化物燃料电池/电解池方面的研究工作。zheng.yang@petrochina.com.cn

引用本文:

谭婷, 李春生, 王冠旭, 刘彩玲, 王嘉蓉, 杨征. 弛豫时间分布技术在固体氧化物燃料电池中的应用[J]. 材料导报, 2025, 39(19): 24090247-8.
TAN Ting, LI Chunsheng, WANG Guanxu, LIU Cailing, WANG Jiarong, YANG Zheng. Application of Distribution of Relaxation Times Technique in Solid Oxide Fuel Cells. Materials Reports, 2025, 39(19): 24090247-8.

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https://www.mater-rep.com/CN/10.11896/cldb.24090247 或 https://www.mater-rep.com/CN/Y2025/V39/I19/24090247

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