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材料导报  2025, Vol. 39 Issue (17): 24040050-9    https://doi.org/10.11896/cldb.24040050
  金属与金属基复合材料 |
V含量对S30403奥氏体不锈钢高温抗氧化性能的影响
沈彬1,2, 顾尚军3, 王劼3, 魏福龙3, 谢祥3, 黎志英1,2, 张钧祥1,2, 李长荣1,2,*
1 贵州大学材料与冶金学院,贵阳 550025
2 贵州省冶金工程与过程节能重点实验室,贵阳 550025
3 首钢水城钢铁有限公司,贵州 六盘水 553000
Effect of V Content on High-temperature Oxidation Resistance of S30403 Austenitic Stainless Steel
SHEN Bin1,2, GU Shangjun3, WANG Jie3, WEI Fulong3, XIE Xiang3, LI Zhiying1,2, ZHANG Junxiang1,2, LI Changrong1,2,*
1 College of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
2 Guizhou Province Key Laboratory of Metallurgical and Process Energy Saving, Guiyang 550025, China
3 Shougang Shuicheng Iron and Steel (Group)Co., Ltd., Liupanshui 553000, Guizhou, China
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摘要 奥氏体不锈钢作为核电常用的结构材料,在高温服役时,材料表面氧化物的增厚可能导致过热和故障,造成重大安全事故。本工作采用静态不连续氧化增重法研究了六种不同V含量的S30403奥氏体不锈钢在900 ℃空气环境下的高温抗氧化性能。结果显示,1#钢在氧化100 h后的平均氧化速率为0.056 9 g·m-2·h-1,符合完全抗氧化级别,当钢中V含量增加至0.49%(质量分数)时,6#钢的平均氧化速率达到最大值,为0.693 1 g·m-2·h-1,符合抗氧化级别。实验钢中的V元素促进了Cr和Si元素的内氧化,含V钢表面Cr2O3和SiO2氧化物含量减少,Mn和Fe元素通过氧化膜向外扩散形成尖晶石结构的MnCr2O4。随着钢中V含量的增加,2#—6#钢表面氧化膜的连续性和致密性逐渐降低,高温抗氧化性能下降。
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沈彬
顾尚军
王劼
魏福龙
谢祥
黎志英
张钧祥
李长荣
关键词:  奥氏体不锈钢  高温抗氧化性能  扩散控制  氧化膜    
Abstract: Austenitic stainless steel, commonly used as a structural material in nuclear power plants, may experience overheating and failures due to the thickening of surface oxides at high temperatures, leading to significant safety accidents. This study utilized the static discontinuous oxidation weight gain method to investigate the high-temperature oxidation resistance of six different V-content S30403 austenitic stainless steels in a 900 ℃ air environment. The results show that Steel 1# exhibited an average oxidation rate of 0.056 9 g·m-2·h-1 after 100 hours of oxidation, meeting the complete oxidation resistance level. As the V content in the steel increased to 0.49%, Steel 6# demonstrated the highest average oxidation rate of 0.693 1 g·m-2·h-1, corresponding to the oxidation resistance level. The V element in the experimental steels facilitated the internal oxidation of Cr and Si elements, leading to a reduction in the surface oxide content of Cr2O3 and SiO2 in V-containing steels. Mn and Fe elements diffused outward through the oxide film to form a spinel structure of MnCr2O4. With the increase of V content in the steels, the continuity and density of the surface oxide film on Steels 2# to 6# gradually decrease, resulting in a decline in high-temperature oxidation resistance performance.
Key words:  austenitic stainless steel    high-temperature oxidation resistance    diffusion control    oxide film
发布日期:  2025-08-28
ZTFLH:  TG144  
基金资助: 国家自然科学基金(52074095);贵州省科技成果转化项目(黔科合成果[2023]一般100);贵州省基础研究计划项目(黔科合基础-ZK[2023]一般072);贵州省科技支撑计划项目(黔科合支撑[2023]一般404)
通讯作者:  *李长荣,博士,贵州大学教授、博士研究生导师。主要从事金属熔体纯净化理论与工艺等相关领域的研究。crli@gzu.edu.cn   
作者简介:  沈彬,硕士。主要从事奥氏体不锈钢组织和高温性能方面的研究。
引用本文:    
沈彬, 顾尚军, 王劼, 魏福龙, 谢祥, 黎志英, 张钧祥, 李长荣. V含量对S30403奥氏体不锈钢高温抗氧化性能的影响[J]. 材料导报, 2025, 39(17): 24040050-9.
SHEN Bin, GU Shangjun, WANG Jie, WEI Fulong, XIE Xiang, LI Zhiying, ZHANG Junxiang, LI Changrong. Effect of V Content on High-temperature Oxidation Resistance of S30403 Austenitic Stainless Steel. Materials Reports, 2025, 39(17): 24040050-9.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24040050  或          https://www.mater-rep.com/CN/Y2025/V39/I17/24040050
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