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《材料导报》期刊社  2018, Vol. 32 Issue (3): 453-460    https://doi.org/10.11896/j.issn.1005-023X.2018.03.016
     材料综述 ｜ |
高强高导铜铬锆合金的最新研究进展
胡号旗1,2,许赪2,杨丽景2,张恒华1,宋振纶2
1 上海大学材料科学与工程学院,上海 200072
2 中国科学院海洋新材料与应用技术重点实验室,浙江省海洋材料与防护技术重点实验室,中国科学院宁波材料技术与工程研究所,宁波 315201
Recent Advances in the Research of High-strength and High-conductivity CuCrZr Alloy
Haoqi HU1,2,Cheng XU2,Lijing YANG2,Henghua ZHANG1,Zhenlun SONG2
1 School of Materials Science and Engineering, Shanghai University, Shanghai 200072
2 Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies,Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201
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摘要 

随着社会发展,对在电机制造、交通运输、电力、电子等领域应用的铜合金的导电性和强度提出了更高要求,铜铬锆合金是满足这些要求的理想材料之一。针对近年来铜铬锆合金的研究热点,综述了铜铬锆合金合金化设计以及加工工艺方面的研究进展,详细总结了目前对铜铬锆合金研究最多的几种加工工艺及其对合金组织和性能的影响,并在此基础上对高强高导铜铬锆合金的热点研究方向进行了分析和展望。
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胡号旗
许赪
杨丽景
张恒华
宋振纶
关键词:  铜铬锆合金  高强  高导    
Abstract: 

With the development of the transportation, electric power, electronics and other fields,higher requirements have been put forward for copper alloys in strength and conductivity. The CuCrZr alloy is one of the ideal materials to meet these requirements. This paper summarizes the progress of the research on the alloying, designing and processing of CuCrZr alloy with the focus on the recent hot topics of CuCrZr alloys, discusses the influence of the processing methods presently under investigation on the microstructure and properties of CuCrZr alloy. The prospective research topics of the CuCrZr alloy have been also proposed.
Key words:  CuCrZr alloy    high strength    high conductivity
出版日期:  2018-02-10      发布日期:  2018-02-10
ZTFLH:  TG146.1+1  
基金资助: 宁波市工业重大攻关项目(2017B10001)
作者简介:  胡号旗:男,1992年生,硕士研究生,主要从事铜合金材料的研究 E-mail: huhaoqi@nimte.ac.cn|宋振纶:通信作者,男,研究员,主要从事金属材料及其表面技术的研究 E-mail: songzhenlun@nimte.ac.cn
引用本文:    
胡号旗,许赪,杨丽景,张恒华,宋振纶. 高强高导铜铬锆合金的最新研究进展[J]. 《材料导报》期刊社, 2018, 32(3): 453-460.
Haoqi HU,Cheng XU,Lijing YANG,Henghua ZHANG,Zhenlun SONG. Recent Advances in the Research of High-strength and High-conductivity CuCrZr Alloy. Materials Reports, 2018, 32(3): 453-460.
链接本文:  
https://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.03.016  或          https://www.mater-rep.com/CN/Y2018/V32/I3/453
图1  不同系列的典型铜合金的极限抗拉强度与电导性能[1,2,3,4,5,6]
图2  CuCrZr合金、CuCr合金、CuZr合金和一些商业合金的强度与导电性的关系[12,13,14,15,16,17,18,19]
图3  Cu-1Cr-0.1Zr合金析出相的3D重建图像及相应延箭头方向的元素分布(厚度1 nm)[25]
图4  粉末冶金法制备的Cu-1Cr-0.65Zr合金在450 ℃时效处理4 h:(a)明场像和SAED照片;(b)析出相的高分辨照片;(c)析出相的EDX分析[28]
Processing
methods		 Alloys Condition σb/MPa Conductivity
%IACS
Vacuum
induction
melting		 Cu-(0.3—1)Cr-(0.03—0.2)Zr-X
(X=RE,Ti,Mg,etc.)		 Solution-deformation-aging [13-14,24,32] 425—590 75—83
Solution-aging[33,34] 350—450 61—85
Secondary aging[35,36,37,38] 480—1 120 67—90
Solution-SPD-aging[19,39-41] 700—1 750 26—85
Powder
metallurgy		 Cu-(0.5—1.5)Cr-(0.05—0.5)Zr-Ti Aging[42,43] 400—450 78—85
Deformation-aging[44] 600 62
Non-vacuum
melting		 Cu-(0.3—0.8)Cr-(0.15—0.45)Zr-X
(X=RE,Mg)		 Solution-deformation-aging[45,46,47] 450—540 78—85
Rapid
solidification		 Cu-0.3Cr-0.15Zr-0.05Mg Aging[48] 378 70
表1  不同工艺制备CuCrZr合金的性能
Defect Resistance increment
μΩ·cm
Vacancy (1%,atom fraction) 1.6
Solution atom (1%,atom fraction) 2.5
Grain boundary/(cm2/cm3) 31.2×10-7
Dislocation/(cm/cm3) 1.0×10-7
表2  不同晶格缺陷对Cu及Cu合金的电阻率的影响[49,50]
图5  Cu-0.81Cr-0.12Zr-0.05La-0.05Y合金60%冷轧773 K时效60 min的明场像与衍射花样[22]
图6  Cu-0.8Cr-0.09Zr合金硬度和导电率随时效时间的变化(时效温度:450 ℃)
图7  不同状态的Cu-0.8Cr-0.09Zr合金的组织和衍射花样照片:(a,b)固溶态;(c,d)固溶时效态
图8  Cu-0.8Cr-0.08Zr经8道次ECAP在425 ℃时效240 min的TEM照片[57]
图9  Cu-15Cr-0.24Zr原位复合材料的不同状态的微观形貌:(a)铸态;(b)ε=2.41轴向;(c)ε=2.41径向;(d)ε=6.44轴向[62]
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