苯磺酸甜菜碱表面改性阳离子交换膜

doi:10.11896/j.issn.1005-023X.2018.02.009

《材料导报》期刊社

2018, Vol. 32

Issue (2): 203-206 https://doi.org/10.11896/j.issn.1005-023X.2018.02.009

物理材料研究｜材料

苯磺酸甜菜碱表面改性阳离子交换膜

黄全江^1,²,南君^1,²,王三反^1,²,李欣怡^1,²,邹信^1,²,张学敏^1,²

1 寒旱地区水资源综合利用教育部工程中心, 兰州 730070
2 兰州交通大学环境与市政工程学院, 兰州 730070

Benzenesulfonic Acid Betaine Surface Modified Cation Exchange Membrane

Quanjiang HUANG^1,²,Jun NAN^1,²,Sanfan WANG^1,²,Xinyi LI^1,²,Xin ZOU^1,²,Xuemin ZHANG^1,²

1 Engineering Research Center for Cold and Arid Regions Water Resource Comprehensive Utilization, Ministry of Education, Lanzhou 730070
2 School of Environmental and Municipal Engineering, Lanzhou Jiaotong University, Lanzhou 730070

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摘要

采用等离子体辉光放电技术,在以聚苯乙烯为基膜的阳离子交换膜表面接枝苯磺酸甜菜碱(SBMA)单体,制备出具有高选择透过性的阳离子交换膜。对改性前后的膜进行扫描电镜(SEM)、傅里叶红外光谱分析(FTIR)及氯离子泄漏率测试,表征膜的改性效果。结果表明:在SBMA浓度为60 g/L,等离子照射强度为0.7 W/cm ²,照射时间为7 min,照射气体氛围为氩气的条件下,改性效果最佳。改性膜含有的活性基团明显增多,表面致密均匀,氯离子泄漏率由原膜的14%降低至2%以下。

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	黄全江
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关键词: 苯磺酸甜菜碱等离子体辉光放电离子交换膜表面改性氯离子泄漏率

Abstract:

The cation exchange membrane with high selectivity was prepared by grafting benzenesulfonic acid betaine (SBMA) on the polystyrene-based cation exchange membrane by plasma glow discharge.In order to characterize the modification of the membrane, the SEM, FTIR and chloride ion leakage rates were measured before and after the modification. The results showed that the modified effect was the best when SBMA concentration was 60 g/L, the intensity of plasma irradiation was 0.7 W/cm ², the irradiation time was 7 min, and the irradiation gas atmosphere was argon. After modification, the active groups contained in the membrane were obviously increased and the surface density was uniform. The ion chloride leakage rate of the modified membrane decreased from 14% to 2%.

Key words: benzenesulfonic acid betaine plasma glow discharge ion-exchange membrane surface modification chloride ion leakage rate

出版日期: 2018-01-25 发布日期: 2018-01-25

ZTFLH:

TB332

基金资助: 国家科技支撑计划项目(2015BAE04B01);国家自然科学基金(21466019)

引用本文:

黄全江,南君,王三反,李欣怡,邹信,张学敏. 苯磺酸甜菜碱表面改性阳离子交换膜[J]. 《材料导报》期刊社, 2018, 32(2): 203-206.
Quanjiang HUANG,Jun NAN,Sanfan WANG,Xinyi LI,Xin ZOU,Xuemin ZHANG. Benzenesulfonic Acid Betaine Surface Modified Cation Exchange Membrane. Materials Reports, 2018, 32(2): 203-206.

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https://www.mater-rep.com/CN/10.11896/j.issn.1005-023X.2018.02.009 或 https://www.mater-rep.com/CN/Y2018/V32/I2/203

图1 SBMA的分子结构

图2 等离子接枝反应过程

表1 改性前后膜性能参数比较

图3 SBMA单体浓度对改性膜氯离子泄漏率的影响

图4 等离子体放电时间对改性膜氯离子泄漏率的影响

表2 辉光放电气体氛围对改性膜选择透过性的影响

图5 (a)原膜及(b)60 g/L,0.7 W/cm2,7 min;(c)60 g/L, 0.7 W/cm2,10 min;(d)60 g/L,1.2 W/cm2,7 min不同条件下改性膜的SEM图

图6 改性前后膜的FTIR分析

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