Progress in Manufacturing and Alloying of AgCuZnSn Brazing Filler Metals
WANG Xingxing1, PENG Jin1, XUE Peng2, WANG Jiansheng1, LI Quancai1, TAN Qunyan1
1 School of Mechanical Engineering, North China University of Water Resources and Electric Power, Zhengzhou 450045; 2 School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094;
Abstract: Sn is used as a beneficial alloy element in silver based brazing filler metals. Obviously, the addition of Sn has a positive function on melting temperature, wettability, filling performance and mechanical property of the sliver based brazing filler me-tals. AgCuZnSn brazing alloys is used as a green and environment-friendly filler metals, which has been a hot topics in the brazing aca-demia at home and abroad. The research and development of the AgCuZnSn brazing alloys during the past two decades are reviewed synthetically. First, the properties of AgCuZnSn brazing alloys are outlined. Secondly, the preparation methods of AgCuZnSn brazing alloys are discussed. Thirdly, the research progress of alloying on the AgCuZnSn brazing filler metals, and the effect of In, Ga, Ni, P, La, Mn element and Ni-P, Ga-In, Ga-In-Ce alloy on AgCuZnSn brazing alloys are reviewed. Lastly, the current problems of the AgCuZnSn brazing alloys are presented, some suggestions are also given for solving these problems, and the future development direction of the AgCuZnSn brazing alloys is prospected, which can provide the theoretical guide and reference for the research of AgCuZnSn brazing alloys.
1 Wingert P C,Leung C H. The development of silver-based cadmium-free contact materials[J]. J Alloys Compd,2004,72(3):148. 2 Stobrawa J,Wierzbickił,Ciura L,et al. Podatnosc do przeróbki plastycznej stopów Ag-Cu-Zn-Sn[J]. Hutnik, Wiadomosci Hutnicze,2013,80(8):442. 3 Chung J W,Kim G S,Lee S Y, et al. Effects of alloying elements on the microstructure and mechanical properties of Cd-free brazing alloys[J]. J Korean Inst Met Mater,2001,39(9):1068. 4 Lai Zhongmin. Effects of Ga/In and rare earth Ce on microstructures and properties of brazed joint of Ag30Cu Zn Sn filler metal[D]. Nanjing:Nanjing University of Aeronautics & Astronautics,2010(in Chinese). 赖忠民. Ga/In与稀土Ce对Ag30CuZn钎料显微组织及钎焊接头性能影响的研究[D]. 南京: 南京航空航天大学,2010. 5 Gancarz T,Pstrus J. Formation and growth of intermetallic phases at the interface in the Cu/Sn-Zn-Ag-Cu/Cu joints [J]. J Alloys Compd,2015,647:844. 6 Winiowski A,Rózanski M. Impact of tin and nickel on the brazing properties of silver filler metals and on the strength of brazed joints made of stainless steels[J]. Arch Metall Mater,2013,58(4):1007. 7 Sun Bin,Gan Weiping,Shang Xiaoyun,et al. Study on processing technology and brazing performance of Ag55Cu21Zn17Sn5Ge2 solder[J].Hot Working Technol,2009,38(3):85(in Chinese). 孙斌,甘卫平,尚晓云,等. Ag55Cu21Zn17Sn5Ge2钎料加工工艺及其钎焊性能的研究[J]. 热加工工艺,2009,38(3):85. 8 Chen Hui. Study on silver-based intermediate temperature filler me-tals alloy for electronic packaging[D]. Changsha:Central South University,2007(in Chinese). 陈慧. 电子封装用银基中温钎料合金的研究[D]. 长沙:中南大学,2007. 9 Zhao Jianchang,Lv Dengfeng,Long Weimin,et al. Manufacturing technology and application prospect of flux cored silver filler metal[J]. Weld Joining,2016(5):9(in Chinese). 赵建昌,吕登峰,龙伟民,等. 新型药芯银钎料的制造技术及应用前景[J]. 焊接,2016(5):9. 10 李国赣. 银基药芯焊丝及制造方法:中国,201110435173.2[P]. 2012-06-27. 11 张冠星,龙伟民,裴夤崟,等. 一种高锡银基焊条及其制备方法:中国,201310443997.3[P]. 2015-08-19. 12 Hu Xiaohua,Hu Jianhua,Gao Ge,et al. Effects of sintering process on microstructure and properties of Ag-Cu-Zn-Sn filler metal formed by electromagnetic compaction[J]. Hot Work Technol,2017, 46(1):23(in Chinese). 胡晓华,胡建华,高歌,等. 烧结工艺对电磁压制成形Ag-Cu-Zn-Sn钎料组织与性能的影响[J]. 热加工工艺,2017,46(1):23. 13 Xu Zhikun.Technological study on low-voltage electromagnetic compaction and liquid phase sintering of cadmium-free silver-based intermediate temperature filler metals[D]. Wuhan: Wuhan University of Technology,2012(in Chinese). 徐志坤. 无镉中温银基钎料的低电压电磁压制及烧结工艺研究[D]. 武汉:武汉理工大学,2012. 14 Gao Ge,Hu Jianhua,Cheng Cheng,et al. Forming equation about multivariate mixed metal powder by electromagnetic compaction[J]. Chinese J Nonferrous Met,2015,25(7):1937(in Chinese). 高歌,胡建华,程呈,等. 电磁压制多元金属混合粉末的压型方程[J]. 中国有色金属学报,2015,25(7):1937. 15 Long W M,Zhang G X,Zhang Q K. In situ synthesis of high strength Ag brazing filler metals during induction brazing process[J]. Scripta Mater,2016,110:41. 16 Long Weimin,Lu Quanbin,He Peng,et al. In situ synthesis of Al-Si-Cu alloy during brazing process and mechanical property of brazing joint[J]. J Mater Eng,2016,44(6):17(in Chinese). 龙伟民,路全彬,何鹏,等. 钎焊过程原位合成Al-Si-Cu合金及接头性能[J]. 材料工程,2016,44(6):17. 17 Long Weimin,Zhang Guanxing,Zhang Qingke,et al. In-situ synthesis of high strength Ag brazing filler metals during brazing process[J]. Trans China Weld Inst,2015,36(11):1(in Chinese). 龙伟民,张冠星,张青科,等. 钎焊过程原位合成高强度银钎料[J]. 焊接学报,2015,36(11):1. 18 王星星,王博,韩林山,等. 一种过饱和钎料及其制备方法:中国,201510867587.0[P].2016-02-24. 19 Wang Xingxing,Zhang Guanxing,Long Weimin,et al. Experimental research of tin brush electro-plated on Ag45CuZn brazing filler me-tal[J].Rare Met Mater Eng,2013,42(11):2394(in Chinese). 王星星,张冠星,龙伟民,等. Ag45CuZn钎料表面刷镀锡的试验研究[J]. 稀有金属材料与工程,2013,42(11):2394. 20 Wang Xingxing,et al. Phase composition and formation mechanism of diffusion transition zone for silver-based brazing alloys with tin coatings[J]. Mater Rev:Res,2017,31(4):66(in Chinese). 王星星,等. 镀锡银钎料扩散过渡区的物相和形成机制[J]. 材料导报:研究篇,2017,31(4):66. 21 Wang Xingxing,Li Quancai,Long Weimin,et al. Effect of heat diffusion process on the interface microstructure and melting characteristic of brazing filler metals with tin coatings[J]. Trans China Weld Inst,2016,37(5):89(in Chinese). 王星星,李权才,龙伟民,等. 热扩散对镀锡银钎料界面组织及熔化特性的影响[J]. 焊接学报,2016,37(5):89. 22 Wang Xingxing,Du Quanbin,Long Weimin,et al. Effect of micro tin brush-electroplated coating on properties of AgCuZnSn brazing filler metals[J].Trans China Weld Inst,2015,36(3):47(in Chinese). 王星星,杜全斌,龙伟民,等. 微米锡刷镀层对AgCuZnSn钎料性能的影响[J].焊接学报,2015,36(3):47. 23 Timmins P F. The mechanism of tough-pitch copper embit-terment by silver brazing alloys[J]. Weld J,1990,69(10):378s. 24 Li M G,Sun D Q,Qiu X M,et al. Effect of tin on melting temperature and microstructure of Ag-Cu-Zn-Sn filler metals[J]. Mater Sci Technol,2005,21(11):1318. 25 Xue Songbai,Qian Yiyu,Hu Xiaoping. Effect of tin and indium in silver filler metal and its mechanisem[J]. Weld Joining,1998(11):28(in Chinese). 薛松柏,钱乙余,胡晓萍. 元素锡、铟在银基钎料中的作用及其机理[J]. 焊接,1998(11):28. 26 Li Minggao. Joining of TiNi shape memory alloy and stainless steel[D]. Changchun:Jilin University,2006(in Chinese). 李明高. TiNi形状记忆合金与不锈钢的连接[D]. 长春:吉林大学,2006. 27 Cao J,Zhang L X,Wang H Q,et al. Effect of silver content on microstructure and properties of brass/steel induction brazing joint using Ag-Cu-Zn-Sn filler metal[J]. J Mater Sci Technol,2011,27(4):377. 28 Wierzbicki L J,Malec W,Stobrawa J,et al. Studies into new,environmentally friendly Ag-Cu-Zn-Sn brazing alloys of low silver content[J]. Arch Metall Mater,2011,56(1):147. 29 Wu Qianqian. Influence of indium and stannum on microstructure and properties of BAg20CuZn filler metal[D]. Zhengzhou:Zhengzhou University,2014(in Chinese). 武倩倩. 铟和锡对BAg20CuZn钎料组织及性能的影响[D]. 郑州:郑州大学,2014. 30 Watanabe T,Yanagisawa A,Sasaki T. Development of Ag based brazing filler metal with low melting point[J]. Sci Technol Weld Joining,2011,16(6):502. 31 Han Xianpeng. Effects of Ga on properties of cadmium-free silver filler metal[D]. Nanjing:Nanjing University of Aeronautics & Astronautics,2008(in Chinese). 韩宪鹏.镓对无镉银钎料性能影响的研究[D]. 南京:南京航空航天大学,2008. 32 Ma Jia,Long Weimin,He Peng,et al. Effect of gallium addition on microstructure and properties of Ag-Cu-Zn-Sn alloys[J]. China Weld:English Ed,2015,24(3):6. 33 Zhang Tao,Xue Songbai,Ma Chaoli. Research status of AgCuZn brazing filler metals[J]. Weld Joining,2014(10):10(in Chinese). 张涛,薛松柏,马超力. Ag-Cu-Zn系钎料的研究现状[J]. 焊接,2014(10):10. 34 Ma Chaoli,Xue Songbai,Wang Bo. Study on novel Ag-Cu-Zn-Sn brazing filler metal bearing Ga[J]. J Alloys Compd,2016,688:854. 35 Li Zhuoran,Jiao Ning,Feng Jicai,et al. Effect of alloying elements on microstructure and property of AgCuZn brazing alloy[J]. Trans China Weld Inst,2008,29(3):65(in Chinese). 李卓然,矫宁,冯吉才,等. 合金元素对AgCuZn 系钎料合金组织与性能的影响[J]. 焊接学报,2008,29(3):65. 36 Li Zhuoran,Jiao Ning,Feng Jicai,et al. Effect of P and rare-earth La on microstructure and property of AgCuZnSn brazing alloy[J]. Trans China Weld Inst,2007,28(12):1(in Chinese). 李卓然,矫宁,冯吉才,等. P、稀土La对AgCuZnSn钎料合金组织与性能的影响[J]. 焊接学报,2007,28(12):1. 37 Wang Xiaorong,Yu Dingkun,He Yanming,et al. Effect of Sn content on brazing properties of Ag based filler alloy[J]. Mater Sci,2013,3:14. 38 Daniel S,Gunther W,Sebastian S. Development of Ag-Cu-Zn-Sn brazing filler metals with a 10weigh-% reduction of silver and liquids temperature[J]. China Weld:English Ed,2014,23(4):25. 39 Khorunov V F,Stefaniv B V,Maksymova S V. Effect of nickel and manganese on structure of Ag-Cu-Zn-Sn system alloys and strength of brazed joints[J]. Paton Weld J,2014,4:22. 40 Li Z R,Cao J,Liu B,et al. Effect of La content on microstructure evolution of 20Ag-Cu-Zn-Sn-P-La filler metals and properties of joints[J]. Sci Technol Weld Joining,2010,15(1):59. 41 Liu Bin. Investigation on microstructure and properties of cadmium-free silver-based intermediate temperature filler metals[D]. Harbin:Harbin Institute of Technology,2008(in Chinese). 刘彬. 新型银基无镉中温钎料组织性能的研究[D]. 哈尔滨:哈尔滨工业大学,2008. 42 Li Zhuoran,Liu Bin,Feng Jicai. Effect of Ni on wettability and shear strength of joints of Ag20CuZnSnP filler metal[J]. Trans China Weld Inst,2008,29(9):19(in Chinese). 李卓然,刘彬,冯吉才.镍对Ag20CuZnSnP钎料铺展润湿性和接头抗剪强度的影响[J].焊接学报,2008,29(9):19. 43 Qiao Ning. Investigation on microstructure and properties of low silver-containing cadmium-free intermediate temperature brazing filler metals[D]. Harbin:Harbin Institute of Technology,2007(in Chinese). 矫宁. 新型低温无镉中温钎料组织性能的研究[D]. 哈尔滨:哈尔滨工业大学,2007. 44 Liu Hongwei,Feng Xiaosong. Research on properties of cadmium-free silver-based intermediate temperature brazing filler metals[J]. Weld Joining,2011(9):30(in Chinese). 刘宏伟,封小松. 含镓和铟的无镉银基中温钎料性能研究[J]. 焊接,2011(9):30. 45 Lai Zhongmin,Xue Songbai,Han Xianpeng,et al. Study on microstructure and property of brazed joint of AgCuZn-X(Ga, Sn, In, Ni) brazing alloy[J]. Rare Met Mater Eng,2010,39(3):397. 46 Lai Zhongmin,Xue Songbai,Zhang Liang,et al. Investigation on properties and microstructures of Ag-Cu-Zn-Sn-xGa-yIn filler metal[J]. Trans China Weld Inst,2010,31(3):73(in Chinese). 赖忠民,薛松柏,张亮,等. Ag-Cu-Zn-Sn-xGa-yIn 钎料性能与显微组织研究[J]. 焊接学报,2010,31(3):73. 47 Zhang Guanxing,Long Weimin,Pan Jianjun,et al. Effect of oxygen content on wettability and mechanical property of brazing seam for silver based powdered brazing filler metal[J]. Trans China Weld Inst,2014,35(3):81(in Chinese). 张冠星,龙伟民,潘建军,等. 氧含量对银基粉状钎料润湿性及钎缝力学性能的影响[J]. 焊接学报,2014,35(3):81. 48 Fan Jianglei,Long Weimin,Wang Xingxing,et al. Effect of inclusions on microstructure and mechanical properties of Ag-Cu-Zn filler metal[J]. Trans China Weld Inst,2015,36(5):1(in Chinese). 樊江磊,龙伟民,王星星,等. 夹杂物对Ag-Cu-Zn钎料凝固组织和性能的影响[J]. 焊接学报,2015,36(5):1. 49 孙大千,邱小明,朱宪春. 口腔正畸复合矫齿丝及其制备方法:中国,01138750.5[P]. 2004-07-07. 50 Qiu Xiaoming,Li Minggao,Sun Daqian,et al. Microstucture and properties of brazing joint of TiNi shape memory alloy with stainless steel[J]. J Mechan Eng,2005,41(2):132(in Chinese). 邱小明,李明高,孙大千,等.TiNi形状记忆合金与不锈钢钎焊接头的微观组织与性能[J]. 机械工程学报,2005,41(2):132.
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2017, Vol. 31 
