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材料导报  2025, Vol. 39 Issue (17): 24100145-10    https://doi.org/10.11896/cldb.24100145
  金属与金属基复合材料 |
铜铈催化剂在催化氧化中的研究进展:作用机制及结构性能调控
张明虎1,2,3, 朱文杰1,2,3,*, 陆继长1,2,3, 刘江平1,2,3, 罗永明2,3,4
1 昆明理工大学环境科学与工程学院,昆明 650500
2 昆明理工大学挥发性有机物污染防治与资源化省创新团队,昆明 650500
3 云南省高校恶臭挥发性有机物控制重点实验室,昆明 650500
4 昆明理工大学化学工程学院,昆明 650500
Research Progress of Copper-Cerium Catalysts in Catalytic Oxidation: Mechanism and Regulation of Structural Properties
ZHANG Minghu1,2,3, ZHU Wenjie1,2,3,*, LU Jichang1,2,3, LIU Jiangping1,2,3, LUO Yongming2,3,4
1 Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China
2 The Innovation Team for Volatile Organic Compounds Pollutants Control and Resource Utilization of Yunnan Province, Kunming University of Science and Technology, Kunming 650500, China
3 The Higher Educational Key Laboratory for Odorous Volatile Organic Compounds Pollutants Control of Yunnan Province, Kunming 650500, China
4 Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming 650500, China
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摘要 铜铈催化剂因来源广泛、催化性能优异,在催化氧化领域具有广阔的应用前景。近年来,研究人员对铜铈催化剂在催化氧化中的作用机制进行了深入的研究,对铜铈催化剂的结构性能调控进行了多方面的探索。本文综述了目前有关铜铈催化剂催化氧化VOCs和CO的研究进展,探讨了铜铈催化剂的电子金属-载体相互作用和非对称氧空位在催化氧化中的作用机制,总结了载体形貌、制备方法以及金属掺杂等因素对铜铈催化剂结构性能的影响,并对未来研究中可能遇到的挑战进行了展望。
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张明虎
朱文杰
陆继长
刘江平
罗永明
关键词:  铜铈催化剂  催化氧化  非对称氧空位  电子金属-载体相互作用  载体形貌    
Abstract: Copper-cerium catalysts have a broad application prospect in the field of catalytic oxidation due to their wide source and excellent catalytic performance. In recent years, researchers have conducted in-depth research on the mechanism of copper-cerium catalysts in catalytic oxidation, and explored the structural property regulation of copper-cerium catalyst. In this paper, the current research progresson the catalytic oxidation of VOCs and CO with copper-cerium catalysts was reviewed, the mechanism of electronic metal-support interactions and asymmetric oxygen vacancy in the catalytic oxidation of copper-cerium catalysts was discussed, and the effects of support morphologies, preparation methods and metal doping on the structural properties of copper-cerium catalysts were summarized. At last, the possible challenges in future research were prospected.
Key words:  copper-cerium catalyst    catalytic oxidation    asymmetric oxygen vacancy    electronic metal-support interaction    support morphology
发布日期:  2025-08-28
ZTFLH:  O643.36  
基金资助: 国家自然科学基金(22166021);云南省科技厅科技计划项目(202302AG050002-1);云南省中青年学术与技术带头人后备人才项目(202405AC350026)
通讯作者:  *朱文杰,昆明理工大学环境科学与工程学院教授、硕士研究生导师。目前主要从事微-介孔环境纳米材料研发、水体重金属污染防治、挥发性有机物催化降解等方面的研究工作。zhuwenjie17@163.com   
作者简介:  张明虎,昆明理工大学环境科学与工程学院硕士研究生,主要研究领域为铜铈催化剂催化氧化苯乙烯。
引用本文:    
张明虎, 朱文杰, 陆继长, 刘江平, 罗永明. 铜铈催化剂在催化氧化中的研究进展:作用机制及结构性能调控[J]. 材料导报, 2025, 39(17): 24100145-10.
ZHANG Minghu, ZHU Wenjie, LU Jichang, LIU Jiangping, LUO Yongming. Research Progress of Copper-Cerium Catalysts in Catalytic Oxidation: Mechanism and Regulation of Structural Properties. Materials Reports, 2025, 39(17): 24100145-10.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.24100145  或          https://www.mater-rep.com/CN/Y2025/V39/I17/24100145
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