铁基非晶涂层在不同介质溶液中的摩擦学性能研究

doi:10.11896/cldb.24040191

材料导报

2025, Vol. 39

Issue (11): 24040191-7 https://doi.org/10.11896/cldb.24040191

金属与金属基复合材料

铁基非晶涂层在不同介质溶液中的摩擦学性能研究

李春玲^1,*, 王荣福¹, 翟海民², 李文生³

1 兰州理工大学机电工程学院,兰州 730050
2 兰州理工大学材料科学与工程学院,兰州 730050
3 西北师范大学物理与电子工程学院,兰州 730070

Tribological Properties of Fe-based Amorphous Coatings in Different Media Solutions

LI Chunling^1,*, WANG Rongfu¹, ZHAI Haimin², LI Wensheng³

1 School of Mechanical and Electrical Engineering, Lanzhou University of Technology, Lanzhou 730050, China
2 School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China
3 College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070, China

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摘要采用爆炸喷涂技术在316L不锈钢上制备了铁基非晶涂层,研究了涂层在质量分数为3.5% 的NaCl、0.01 mol/L NaOH和0.01 mol/L H₂SO₄溶液中的摩擦学性能。结果表明:制备的涂层具有完整的非晶结构,硬度远高于316L不锈钢基体,且孔隙率较低。由于溶液的润滑作用,涂层在介质溶液中的摩擦系数和磨损率都明显低于干滑动摩擦,XPS分析表明涂层表面形成了由Cr和Mo氧化物组成的耐腐蚀性钝化膜。在NaCl溶液中形成的大量氧化物使得涂层的磨损率最小(4.36×10^-6 mm³·N^-1·m^-1),在H₂SO₄溶液中形成的SiO₂膜也可有效地降低涂层的磨损率(4.61×10^-6 mm³·N^-1·m^-1)。在NaOH溶液中,由于强碱对材料的腐蚀程度较高,涂层的磨损率最高(6.63×10^-6 mm³·N^-1·m^-1),涂层在介质溶液中的磨损机制受机械和腐蚀磨损的协同作用,机械磨损占据主导作用。

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关键词: 铁基非晶涂层爆炸喷涂湿摩擦磨损机制

Abstract: Fe-based amorphous coatings were prepared on 316L stainless steel substrates through detonation spraying. The tribological behavior of these coatings was investigated in various solutions, including 3.5% (mass fraction) NaCl, 0.01 mol/L NaOH, and 0.01 mol/L H₂SO₄. The findings reveal that the fabricated Fe-based amorphous coating possesses a homogenous amorphous structure and lower porosity, exhibiting significantly higher hardness than the 316L stainless steel substrate. Notably, the lubrication effect of the solutions results in a substantial reduction in the friction coefficient and wear rate of the coating compared to dry sliding conditions. By XPS, it’s found that a corrosion-resistant passive film composed primarily of Cr and Mo oxides is formed on the coating surface. In the NaCl solution, a large amount of oxides are generated to effectively minimize the wear rate to 4.36×10^-6 mm³·N^-1·m^-1. Similarly, the SiO₂ film formed in the H₂SO₄ solution also contributes to a reduced wear rate of 4.61×10^-6 mm³·N^-1·m^-1. However, in the NaOH solution, the high corrosion potential of the strong alkali leads to the highest wear rate of 6.63×10^-6 mm³·N^-1·m^-1 for the coating. The wear mechanism of the coating in these solutions is primarily influenced by the combined effects of mechanical and corrosive wear, with mechanical wear playing a dominant role.

Key words: Fe-based amorphous coating detonation spraying wet friction wear mechanism

发布日期: 2025-05-29

ZTFLH:

TH117.1

基金资助: 国家自然科学基金(52075234);甘肃省自然科学基金(23JRRA802)

通讯作者: *李春玲,兰州理工大学机电工程学院副教授、硕士研究生导师。主要从事激光加工技术、材料表面改性等领域的研究工作。yxplcl@lut.edu.cn

引用本文:

李春玲, 王荣福, 翟海民, 李文生. 铁基非晶涂层在不同介质溶液中的摩擦学性能研究[J]. 材料导报, 2025, 39(11): 24040191-7.
LI Chunling, WANG Rongfu, ZHAI Haimin, LI Wensheng. Tribological Properties of Fe-based Amorphous Coatings in Different Media Solutions. Materials Reports, 2025, 39(11): 24040191-7.

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https://www.mater-rep.com/CN/10.11896/cldb.24040191 或 https://www.mater-rep.com/CN/Y2025/V39/I11/24040191

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