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材料导报  2023, Vol. 37 Issue (9): 22090082-9    https://doi.org/10.11896/cldb.22090082
  无机非金属及其复合材料 |
硅异质结太阳能电池用透明导电氧化物薄膜的研究现状及发展趋势
夏鹏1,2, 傅萍1,2, 黄金华2, 李佳2,*, 宋伟杰2
1 宁波大学材料科学与化学工程学院,浙江 宁波 315211
2 中国科学院宁波材料技术与工程研究所,浙江 宁波 315201
Current Situation and Development Trend of Transparent Conductive Oxide Films on Silicon Heterojunction Solar Cells
XIA Peng1,2, FU Ping1,2, HUANG Jinhua2, LI Jia2,*, SONG Weijie2
1 School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, China
2 Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang, China
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摘要 硅异质结(SHJ)太阳能电池是目前光伏产业中的重要组成部分,其由于具有高开路电压(Voc)等优点而引起了广泛的关注。在硅异质结太阳能电池中,透明导电氧化物(TCO)薄膜层的光学性能和电学性能分别影响着电池的短路电流(Jsc)、填充因子(FF),进而影响电池的转换效率。近年来,SHJ电池中TCO层的研究主要集中于掺杂的In2O3和ZnO体系。本文从硅异质结太阳能电池的不同结构出发,概述了TCO薄膜的光电性能(透过率、禁带宽度、方块电阻、载流子浓度、迁移率和功函数)以及与相邻层的接触对电池性能的影响,介绍了不同体系的透明导电氧化物薄膜在硅异质结太阳能电池中的应用及研究现状,并展望其未来的发展趋势。
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夏鹏
傅萍
黄金华
李佳
宋伟杰
关键词:  硅异质结太阳能电池  背发射极结构  透明导电氧化物薄膜  迁移率    
Abstract: Silicon heterojunction (SHJ) solar cells are an important part of the current photovoltaic industry, and they have attracted wide spread attention because of their high open-circuit voltage (Voc). The optical and electrical properties of transparent conductive oxide (TCO) films in SHJ solar cells affect the short-circuit current (Jsc) and filling factor (FF), respectively, and the variation of Jsc and FF will further affect the conversion efficiency of the cells. Therefore, the performance of the TCO film layer limits the long-term development of SHJ solar cells. In recent years, the development of TCO films in SHJ cells has mainly focused on improving the performance of doped In2O3 systems and doped ZnO systems. In this paper, we firstly describe the different structures of SHJ solar cells, followed by the optoelectronic properties, namely, transmittance, band gap, sheet resistance, carrier concentration, mobility, and work function, of transparent conductive oxide films. The effect of contact properties with each layer on the performance of the cell is then summarized, the application and research status of various transparent conductive oxide films in SHJ solar cells are introduced, and the prospects for their future development trends are reviewed.
Key words:  silicon heterojunction solar cell    rear emitter structure    transparent conductive oxide film    mobility
出版日期:  2023-05-10      发布日期:  2023-05-04
ZTFLH:  TB321  
基金资助: 企业合作项目
通讯作者:  *李佳,中国科学院宁波材料技术与工程研究所项目研究员、博士研究生导师。2007年获得华中科技大学电子系博士学位,2008年加入中科院宁波材料所。目前从事柔性光电功能薄膜及应用方面的研究工作。已完成多项国家级和省部级项目及企业合作项目。发表SCI学术论文40余篇,授权中国发明专利10余项。lijia@nimte.ac.cn   
作者简介:  夏鹏,2020年6月于南昌航空大学获得工学学士学位。现为宁波大学与宁波材料技术与工程研究所联合培养的硕士研究生,主要在宁波材料技术与工程研究所工作。目前主要研究领域为透明导电氧化物薄膜。
引用本文:    
夏鹏, 傅萍, 黄金华, 李佳, 宋伟杰. 硅异质结太阳能电池用透明导电氧化物薄膜的研究现状及发展趋势[J]. 材料导报, 2023, 37(9): 22090082-9.
XIA Peng, FU Ping, HUANG Jinhua, LI Jia, SONG Weijie. Current Situation and Development Trend of Transparent Conductive Oxide Films on Silicon Heterojunction Solar Cells. Materials Reports, 2023, 37(9): 22090082-9.
链接本文:  
http://www.mater-rep.com/CN/10.11896/cldb.22090082  或          http://www.mater-rep.com/CN/Y2023/V37/I9/22090082
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